Tuning of electronic properties via labile N→B-coordination in conjugated organoboranes

Recent developments in and perspectives on three-coordinate boron materials: a bright future

(2017) Lei Ji et al.   Chemical Science

Synthesis by free radical polymerization and properties of BN-polystyrene and BN-poly(vinylbiphenyl)

(2016) Wen-Ming Wan et al.   CHEMICAL COMMUNICATIONS

Generation of an N→B Ladder-type Structure by Regioselective Hydroboration of an Alkenyl-Functionalized Quaterpyridine

(2016) Markus Grandl et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hydroboration as an Efficient Tool for the Preparation of Electronically and Structurally Diverse N→B-Heterocycles

(2016) Markus Grandl et al.   CHEMISTRY-A EUROPEAN JOURNAL

Efficient synthetic methods for the installation of boron–nitrogen bonds in conjugated organic molecules

(2016) Matthew M. Morgan et al.   DALTON TRANSACTIONS

Merging thiophene with boron: new building blocks for conjugated materials

(2016) Yi Ren et al.   DALTON TRANSACTIONS

Low Band Gap Coplanar Conjugated Molecules Featuring Dynamic Intramolecular Lewis Acid–Base Coordination

(2016) Congzhi Zhu et al.   JOURNAL OF ORGANIC CHEMISTRY

Luminescent Main-Chain Organoborane Polymers: Highly Robust, Electron-Deficient Poly(oligothiophene borane)s via Stille Coupling Polymerization

(2016) Xiaodong Yin et al.   MACROMOLECULES

Pyridyl Directed Catalyst-Free trans-Hydroboration of Internal Alkynes

(2016) Kang Yuan et al.   ORGANIC LETTERS

1,1-Hydroboration of Fused Azole–Isoindole Analogues as an Approach for Construction of B,N-Heterocycles and Azole-Fused B,N-Naphthalenes

(2016) Yong-gang Shi et al.   ORGANIC LETTERS

Steric Shielding vs Structural Constraint in a Boron-Containing Polycyclic Aromatic Hydrocarbon

(2016) Valentin M. Hertz et al.   ORGANOMETALLICS

Novel Dimeric o-Carboranyl Triarylborane: Intriguing Ratiometric Color-Tunable Sensor via Aggregation-Induced Emission by Fluoride Anions

(2016) Byung Hoon Choi et al.   ORGANOMETALLICS

Click-chemistry approaches to π-conjugated polymers for organic electronics applications

(2016) Assunta Marrocchi et al.   Chemical Science

Stepwise Reduction of 9,10-Bis(dimesitylboryl)anthracene

(2015) Yang Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly emissive organic solids with remarkably broad color tunability based on N,C-chelate, four-coordinate organoborons

(2015) Aslam C. Shaikh et al.   CHEMICAL COMMUNICATIONS

Thermal and Photolytic Transformation of NHC-B,N-Heterocycles: Controlled Generation of Blue Fluorescent 1,3-Azaborinine Derivatives and 1H-Imidazo[1,2-a]indoles by External Stimuli

(2015) Sean M. McDonald et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Luminescent Microporous Organic Polymer with Lewis Acidic Boron Sites on the Pore Surface: Ratiometric Sensing and Capture of F−Ions

(2015) Venkata M. Suresh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Strongly Emissive and Photostable Four-Coordinate Organoboron N,C Chelates and Their Use in Fluorescence Microscopy

(2015) Vânia F. Pais et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Preorganized Ditopic Borane as Highly Efficient One- or Two-Electron Trap

(2015) Alexander Hübner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electron Delocalization in Reduced Forms of 2-(BMes2)pyrene and 2,7-Bis(BMes2)pyrene

(2015) Lei Ji et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

B2N2-Dibenzo[a,e]pentalenes: Effect of the BN Orientation Pattern on Antiaromaticity and Optoelectronic Properties

(2015) Xiao-Ye Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enamine/butadienylborane cycloaddition in the frustrated Lewis pair regime

(2015) Guo-Qiang Chen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

One-Pot Synthesis of Brightly Fluorescent Mes2B-Functionalized Indolizine Derivatives via Cycloaddition Reactions

(2015) Deng-Tao Yang et al.   ORGANIC LETTERS

Facile Arylation of Four-Coordinate Boron Halides by Borenium Cation Mediated Boro-desilylation and -destannylation

(2015) Daniel L. Crossley et al.   ORGANOMETALLICS

Triarylborane conjugated dicyanovinyl chromophores: intriguing optical properties and colorimetric anion discrimination

(2015) George Rajendra Kumar et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Development of a donor polymer using a B ← N unit for suitable LUMO/HOMO energy levels and improved photovoltaic performance

(2015) Zijian Zhang et al.   Polymer Chemistry

Optical and electronic properties of air-stable organoboron compounds with strongly electron-accepting bis(fluoromesityl)boryl groups

(2015) Zuolun Zhang et al.   Chemical Science

Enhancing electron affinity and tuning band gap in donor–acceptor organic semiconductors by benzothiadiazole directed C–H borylation

(2015) D. L. Crossley et al.   Chemical Science

Role of Steric Attraction and Bite-Angle Flexibility in Metal-Mediated C–H Bond Activation

(2015) Lando P. Wolters et al.   ACS Catalysis

Confirmed by X-ray Crystallography: The B⋅B One-Electron σ Bond

(2014) Alexander Hübner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Luminescent Materials: Locking π-Conjugated and Heterocyclic Ligands with Boron(III)

(2014) Denis Frath et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

BN Heterosuperbenzenes: Synthesis and Properties

(2014) Xiao-Ye Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Triarylboranes with a 2-Dimesitylboryl-2’-(N,N-dimethylamino)biphenyl Core Unit: Structure-Property Correlations and Sensing Abilities to Discriminate Between F−and CN−Ions

(2014) Chen Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis and characterisation of the complete series of B–N analogues of triptycene

(2014) Ömer Seven et al.   DALTON TRANSACTIONS

Unusual Doping of Donor–Acceptor-Type Conjugated Polymers Using Lewis Acids

(2014) Elena Poverenov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bis-BN Cyclohexane: A Remarkably Kinetically Stable Chemical Hydrogen Storage Material

(2014) Gang Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photodissociation of B–N Lewis Adducts: A Partially Fused Trinaphthylborane with Dual Fluorescence

(2014) Kyohei Matsuo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Internal Adduct Formation of Active Intramolecular C4-bridged Frustrated Phosphane/Borane Lewis Pairs

(2014) Xiaowu Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Two BN Isosteres of Anthracene: Synthesis and Characterization

(2014) Jacob S. A. Ishibashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Straightforward Strategy toward Large BN-Embedded π-Systems: Synthesis, Structure, and Optoelectronic Properties of Extended BN Heterosuperbenzenes

(2014) Xiao-Ye Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactivity and Electronic Properties of a Ferrocene Molecule Bearing an N,C-Chelated BMes2 Unit

(2014) Ying-Li Rao et al.   ORGANOMETALLICS

Multiple Reduction of 2,5-Bis(borolyl)thiophene: Isolation of a Negative Bipolaron by Comproportionation

(2013) Holger Braunschweig et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Study of boron–nitrogen dative bonds using azetidine inversion dynamics

(2013) Cam Thuy Hoang et al.   CHEMICAL COMMUNICATIONS

Four-coordinate organoboron compounds for organic light-emitting diodes (OLEDs)

(2013) Di Li et al.   CHEMICAL SOCIETY REVIEWS

Aggregation-Induced Emission and Efficient Solid-State Fluorescence from Tetraphenylethene-Based N,C-Chelate Four-Coordinate Organoborons

(2013) Zujin Zhao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Triarylborane conjugated acacH ligands and their BF2 complexes: facile synthesis and intriguing optical properties

(2013) George Rajendra Kumar et al.   DALTON TRANSACTIONS

Photo- and Thermal-Induced Multistructural Transformation of 2-Phenylazolyl Chelate Boron Compounds

(2013) Ying-Li Rao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C-Functionalized, Air- and Water-Stable 9,10-Dihydro-9,10-diboraanthracenes: Efficient Blue to Red Emitting Luminophores

(2013) Christian Reus et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Radical Anion of Structurally Constrained Triphenylborane

(2013) Tomokatsu Kushida et al.   ORGANOMETALLICS

Highly Congested Donor–Acceptor P–B Compound: Synthesis and Properties of a BMes2- and a PPh2-Functionalized 1,8-Naphthalene

(2013) Yu-Fei Li et al.   ORGANOMETALLICS

Color Tuning in Polymer Light-Emitting Diodes with Lewis Acids

(2012) Peter Zalar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Advances in Azaborine Chemistry

(2012) Patrick G. Campbell et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stepwise Intramolecular Photoisomerization of NHC-Chelate Dimesitylboron Compounds with C–C Bond Formation and C–H Bond Insertion

(2012) Ying-Li Rao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Planarized Triarylboranes: Stabilization by Structural Constraint and Their Plane-to-Bowl Conversion

(2012) Zhiguo Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Advanced Luminescent Materials Based on Organoboron Polymers

(2012) Kazuo Tanaka et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Decorating BODIPY with Three- and Four-Coordinate Boron Groups

(2012) Jia-sheng Lu et al.   ORGANIC LETTERS

Metal-Free Ortho C–H Borylation of 2-Phenoxypyridines under Mild Conditions

(2012) Liting Niu et al.   ORGANIC LETTERS

Photochromic Thienylpyridine–Bis(alkynyl)borane Complexes: Toward Readily Tunable Fluorescence Dyes and Photoswitchable Materials

(2012) Hok-Lai Wong et al.   ORGANIC LETTERS

3-Vinylborane-functionalized oligothiophenes: isomer-dependent electronic structure and fluorescence enhancement upon anion binding

(2012) Frank Pammer et al.   Chemical Science

Electrochemical Considerations for Determining Absolute Frontier Orbital Energy Levels of Conjugated Polymers for Solar Cell Applications

(2011) Claudia M. Cardona et al.   ADVANCED MATERIALS

Turn-on fluorescence response upon anion binding to dimesitylboryl-functionalized quaterthiophene

(2011) Haiyan Li et al.   CHEMICAL COMMUNICATIONS

Metallopolymers Featuring Boratabenzene Iron Complexes

(2011) Frank Pammer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metal-containing triarylboron compounds for optoelectronic applications

(2011) Zachary M. Hudson et al.   DALTON TRANSACTIONS

1,2-BN Cyclohexane: Synthesis, Structure, Dynamics, and Reactivity

(2011) Wei Luo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lewis Acid Adducts of Narrow Band Gap Conjugated Polymers

(2011) Gregory C. Welch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Polyboryl-Functionalized Triazine as an Electron Transport Material for OLEDs

(2011) Christina Sun et al.   ORGANOMETALLICS

Impact of Cyclometalation and π-Conjugation on Photoisomerization of an N,C-Chelate Organoboron Compound

(2011) Ying-Li Rao et al.   ORGANOMETALLICS

Modification of pyridine-based conjugated polymer films via Lewis acid: halochromism, characterization and macroscopic gradation patterning

(2011) Shotaro Hayashi et al.   Polymer Chemistry

Intramolecular frustrated N/B lewis pairs by enamine hydroboration

(2011) Sina Schwendemann et al.   Chemical Science

Lewis-base adducts of 9,10-dihydro-9,10-diboraanthracene: ditopic hydroboration reagents and a B–N analogue of triptycene

(2010) Andreas Lorbach et al.   CHEMICAL COMMUNICATIONS

Advances in the Synthesis of Organoborane Polymers for Optical, Electronic, and Sensory Applications

(2010) Frieder Jäkle   CHEMICAL REVIEWS

Fluoride Ion Complexation and Sensing Using Organoboron Compounds

(2010) Casey R. Wade et al.   CHEMICAL REVIEWS

Click polymerization

(2010) Anjun Qin et al.   CHEMICAL SOCIETY REVIEWS

Steric and Electronic Influence on Photochromic Switching of N,C-Chelate Four-Coordinate Organoboron Compounds

(2010) Hazem Amarne et al.   CHEMISTRY-A EUROPEAN JOURNAL

Structure and Dynamic Features of an Intramolecular Frustrated Lewis Pair

(2010) Kirill V. Axenov et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Pyridine−Borane Complexes via Electrophilic Aromatic Borylation

(2010) Naoki Ishida et al.   JOURNAL OF ORGANIC CHEMISTRY

Organoboron Polymers for Photovoltaic Bulk Heterojunctions

(2010) Sebastiano Cataldo et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Click Polymerization: Progresses, Challenges, and Opportunities

(2010) Anjun Qin et al.   MACROMOLECULES

Synthesis and Electronic Structure of Ferrocenylborane-Modified Quaterthiophenes and Polythiophenes

(2010) Haiyan Li et al.   MACROMOLECULES

Electronic Tuning of Thiazolyl-Capped π-Conjugated Compounds via a Coordination/Cyclization Protocol with B(C6F5)3

(2010) Andre Job et al.   ORGANIC LETTERS

Single Boryl Isomerization in Silyl-Bridged Photochromic Diboryl Dyes

(2010) Stephen K. Murphy et al.   ORGANIC LETTERS

Conjugated alternating copolymers with 4,4′-dimesitylboryl-2,2′-bithiophene as a building block

(2010) Haiyan Li et al.   Polymer Chemistry

Impact of Donor−Acceptor Geometry and Metal Chelation on Photophysical Properties and Applications of Triarylboranes

(2009) Zachary M. Hudson et al.   ACCOUNTS OF CHEMICAL RESEARCH

Acetylenic Polymers: Syntheses, Structures, and Functions

(2009) Jianzhao Liu et al.   CHEMICAL REVIEWS

Cu(I)-Catalyzed Huisgen Azide−Alkyne 1,3-Dipolar Cycloaddition Reaction in Nucleoside, Nucleotide, and Oligonucleotide Chemistry

(2009) Franck Amblard et al.   CHEMICAL REVIEWS

Marrying click chemistry with polymerization: expanding the scope of polymeric materials

(2009) Patricia L. Golas et al.   CHEMICAL SOCIETY REVIEWS

How stable are 1,2-dihydro-1,2-azaborines toward water and oxygen?

(2009) Ashley N. Lamm et al.   Molecular BioSystems

Synthesis and electrochemical properties of a new class of boron-containing n-type conjugated polymers

(2009) Jianfang Chai et al.   SYNTHETIC METALS

A Hybrid Organic/Inorganic Benzene

(2008) Adam J. V. Marwitz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

B-N as a C-C substitute in aromatic systems

(2008) Michael J.D Bosdet et al.   CANADIAN JOURNAL OF CHEMISTRY

Cu-Catalyzed Azide−Alkyne Cycloaddition

(2008) Morten Meldal et al.   CHEMICAL REVIEWS

Reversible Intramolecular C−C Bond Formation/Breaking and Color Switching Mediated by a N,C-Chelate in (2-ph-py)BMes2and (5-BMes2-2-ph-py)BMes2

(2008) Ying-Li Rao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

BN versus CC: How Similar Are They?

(2007) Zhiqiang Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION