4.6 Article

Synthesis of aryl triflones by insertion of arynes into C-SO2CF3 bonds

Journal

RSC ADVANCES
Volume 7, Issue 1, Pages 47-50

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra26429h

Keywords

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Funding

  1. National Natural Science Foundation of China [21502215, 21421002, 21332010, 21272036]
  2. Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20020000]
  3. Youth Innovation Promotion Association CAS [2016234]
  4. Shanghai Pujiang Program [15PJ1410300]

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A new approach toward the synthesis of aryl triflones was achieved by the formal insertion of arynes into C-SO2CF3 bonds. This reaction proceeds through addition of CF3SO2-containing nucleophiles to the in situ generated arynes and subsequent intramolecular rearrangement.

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