Article
Biochemistry & Molecular Biology
Wei Wang, Zihao Peng, Min Ji, Junqing Chen, Peng Wang
Summary: In this study, a fluorescent probe SQM-NBD was synthesized for selective detection of Cys/Hcy. The probe showed superior sensitivity to Cys/Hcy and was able to achieve fluorescence imaging of Cys/Hcy in HeLa cells, demonstrating its potential for Cys/Hcy identification under physiological and pathological conditions.
BIOORGANIC CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Hongmin Hao, Chao Xu, Haiyuan Luo, Jinglian Yang, Cong Liu, Bingjia Xu, Guang Shi, Xiaobo Xing, Zhenguo Chi
Summary: A highly emissive photofunctional porous organic polymer film (polyPhTPECz) was constructed using an in situ electropolymerization method. The film showed excellent multifunctional and reusable luminescent sensor abilities for 2,4,6-trinitrophenol (TNP) and Fe3+ in aqueous media, with low detection limits and sensitive detection for TNP vapor. The fluorescence-quenching mechanism for TNP was a combination of electron transfer and resonance energy transfer due to the high fluorescence property and cross-linked porous texture of the polyPhTPECz films.
MATERIALS CHEMISTRY FRONTIERS
(2021)
Article
Engineering, Environmental
Bo Situ, Bairong He, Xu Chen, Xiaojing He, Weiwei Feng, Xinyi Ye, Yifang Huang, Xiaolei Xue, Shan Liu, Qiong Xia, Jianjun Zou, Ben Zhong Tang, Lei Zheng
Summary: MASPB is a density-responsive bioprobe for fluorescent sensing of cell nucleus density, capable of distinguishing between tumor cells and normal cells based on nuclear condensation and cellular distribution, providing a rapid tool for nucleus density mapping with potential applications in cancer diagnosis.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Analytical
Wenjie Liang, Gang Nie, Jinjin Che, Zhengjiang Zhang, Dugang Chen, Wenbo Wu
Summary: There is a lack of effective and friendly diagnostic technique for alcoholic liver disease (ALD). Fluorescence imaging, which has been widely applied in disease diagnostic ascribed to the merits of high sensitivity, excellent temporal resolution and minimal invasiveness, is probably a good candidate for ALD studying.
SENSORS AND ACTUATORS B-CHEMICAL
(2023)
Article
Chemistry, Analytical
Ting Chen, Min Zhang, Huili Ma, Caizhi Liao, Qiguo Zhong, Yao-Jen Tu, Yongming Zhang, Ran Cao, Xiaofeng Chen
Summary: In this study, a ratiometric fluorescence sensor MOF-808-TPY was successfully constructed for quantitative analysis of the fluoroquinolone antibacterial agent fleroxacin. The sensor exhibited decreased fluorescence intensity at 370 nm and enhanced fluorescence intensity at 440 nm in the presence of fleroxacin, allowing for selective analysis of fleroxacin.
MICROCHEMICAL JOURNAL
(2023)
Article
Chemistry, Analytical
An-Min Song, Yuan-Jun Tong, Ru-Ping Liang, Jian-Ding Qiu
Summary: The novel ThT@luminol-Eu-GMP CPNPs were synthesized for sensitive detection of ALP and arsenate, with boosted fluorescent performance of ThT achieved through a dual-path design involving molecular rotation restriction and FRET effect.
MICROCHEMICAL JOURNAL
(2021)
Article
Chemistry, Applied
Xiaodan Zeng, Xin Chen, Jie Chen, Mingshuo Ma, Hua Jin, Shihua Yu, Zhigang Liu
Summary: This article describes the successful design and synthesis of a novel ratiometric fluorescent probe for monitoring peroxynitrite in macrophage cells and zebrafish. The probe exhibited high selectivity and sensitivity, making it a reliable tool for tracking peroxynitrite in physiological systems.
Article
Chemistry, Applied
Ling Dai, Weilin Mao, Lianzhe Hu, Jiaxing Song, Yan Zhang, Ting Huang, Min Wang
Summary: This study proposes a bifunctional material with aggregation induced emission (AIE) character and catalytic activity by integrating Zr(IV) ions and tetraphenyl ethylene (TPE) derivatives. The TPE-Zr4+ aggregates exhibit typical AIE effect and retain the phosphatase-like catalytic activity of Zr4+ ions, with high sensitivity to pH values. This material shows promise for ratiometric pH sensing and intracellular imaging.
Article
Chemistry, Analytical
Mengting Xia, Chunbin Li, Lingxiu Liu, Yumao He, Yongdong Li, Guoyu Jiang, Jianguo Wang
Summary: In this study, a novel fluorescent probe with AIE characteristics was developed for the rapid and reliable detection of carboxylesterase (CaE) associated with hepatocellular carcinoma (HCC). The probe exhibited high sensitivity and selectivity towards CaE, and showed potential for application in complex biological samples and live cells, tissues, and animals.
Article
Chemistry, Multidisciplinary
Li Da-xue, Li Dan, Zong Liang, Xiao Yan-hua, Sui Shao-hui, Zhuang Bo, Li Rui, Zhen Hong-ling, Li Jian, Huang Zhi-ping, Jiang Zhi-gang, Wu Wei-hui
Summary: In this study, a sensor based on aggregation-induced emission (AIE), named 4-(1,2,2-triphenylvinyl)benzoxime (TPE-phos), was designed for phosgene detection. The sensor undergoes nitrile formation after reacting with phosgene, leading to significant fluorescence emission within seconds due to the AIE effect.
CHEMICAL COMMUNICATIONS
(2022)
Article
Chemistry, Multidisciplinary
Chinna Ayya Swamy Pothulapadu, Anjitha Jayaraj, N. Swathi, Ragam N. Priyanka, Gandhi Sivaraman
Summary: Metal ions play a crucial role in environmental and biological applications, with a focus on detecting specific ions at minute levels. Benzothiazole-based chemosensors have been designed and synthesized for highly selective and sensitive detection of biologically important metal ions like Zn2+, Cu2+, and Ni2+. The sensors exhibit ratiometric and colorimetric responses to the target ions, making them valuable tools for bioimaging and environmental monitoring.
Article
Spectroscopy
Feng Li, Wen Yao, Chang-He Tian, Ya-Fei Du, Jun-Zheng Wang, Tian-Yang Zhang, Jun-Ying Miao, Bao-Xiang Zhao
Summary: A novel ratiometric fluorescent probe was developed for the detection of thiophenol derivatives, showing high fluorescence signal change ratio and low detection limit, suitable for environmental monitoring and biological research.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2022)
Article
Biochemistry & Molecular Biology
Huan Xiang, Tianqing Ye, Yanbo Li, Yanfei Lin, Dan Liu, Hongwei Zhou, Jianbo Wang, Lei Li
Summary: A ratiometric fluorescent probe BH based on an asymmetric BODIPY dye was designed and synthesized for the detection of intracellular hydrogen sulfide. The probe exhibits colorimetric and ratiometric fluorescence response, with enhanced molecular conjugation after ring formation of the BODIPY skeleton. The probe shows excellent detection selectivity and low cytotoxicity, and can be used for monitoring hydrogen sulfide in living cells.
Article
Chemistry, Analytical
Qi Song, Ning Wang, Fangkun Wang, Kaizhuo Guo, Jiwei Cui, Jingcheng Hao, Yong-Qiang Zhang, Jie Jiang
Summary: In this study, a hydrogen bonding-anchored sensing strategy was used to develop a NIR fluorescent probe CDM-1, which can detect N2H4 with ratiometric and colorimetric responses. The probe showed high selectivity and reactivity with a low limit of detection value and demonstrated its potential in monitoring N2H4 in living cells.
SENSORS AND ACTUATORS B-CHEMICAL
(2023)
Article
Chemistry, Analytical
Qi Wu, LiHeng Feng, Jian Bin Chao, Yu Wang, Shaomin Shuang
Summary: A new fluorescent probe, BTT, was reported for ratiometric sensing of Zn2+ ions in methanol/HEPES buffer solution, showing a clear emission change and color change in the presence of Zn2+. The probe has a limit of detection for Zn2+ quantitation down to 37.7 nM and can image both exogenous and endogenous Zn2+ ions in cells.
Article
Chemistry, Multidisciplinary
Shaoxiong Yang, Tianci Li, Yi Cheng, Wenwen Fan, Longjie Wang, Yanxiong Liu, Longchun Bian, Chuan-Hua Zhou, Li-Yan Zheng, Qiu-E Cao
Summary: This study employed three covalent organic framework (COF) isomers to adsorb gold from electronic waste (e-waste), and found that the adsorption rates and uptake amount of these COF isomers were significantly improved under visible light irradiation. Among them, Tp-BTD-AA showed the highest gold capacity and exhibited high adsorption selectivity and good recyclability.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2022)
Article
Chemistry, Inorganic & Nuclear
Wenwen Fan, Yi Cheng, Baoru Wang, Longjie Wang, Qian Zhou, Yanxiong Liu, Chunqiong Wang, Liyan Zheng, Qiu'e Cao
Summary: In this study, a switch-on near-infrared (NIR) luminescence sensing assay for flavonoids was developed using a metal-organic framework (MOF) called IQBA-Yb. The probe showed excellent sensing capability for kaempferol (Kae) and quercetin (Que), with a wide linear range, low detection limit, and short response time. The presence of hydrogen bonds between the analytes and the MOF skeleton promoted energy transfer and fluorescence enhancement.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Physical
Shiwen Yue, Huangting Ding, Yitong Sun, Meng Tang, Jingyi Wen, Ye Peng, Liyan Zheng, Feng Wang, Yonggang Shi, Qiue Cao
Summary: The introduction of a methoxy group at the ortho position of triphenylphosphine can promote the generation of triplet excitons and increase phosphorescence emission efficiency, while stabilizing excited triplet excitons and enabling a good response to protonic acids, expanding the application of pure organic room-temperature phosphorescent materials.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2022)
Article
Chemistry, Inorganic & Nuclear
Baoru Wang, Peng Liu, Yixiao Hu, Haili Zhao, Liyan Zheng, Qiue Cao
Summary: A copper-based metal-organic framework (Cu-SM MOF) was prepared and found to exhibit superior aqueous stability and laccase-like activity, making it suitable for applications such as phenol oxidation and industrial wastewater treatment.
DALTON TRANSACTIONS
(2023)
Article
Nanoscience & Nanotechnology
Wenwen Fan, Xiaolan Liu, Yi Cheng, Shasha Chang, Longjie Wang, Yanxiong Liu, Peng Liu, Li-Yan Zheng, Qiu-E Cao
Summary: In this study, a novel double ratiometric detection method for vanillymandelic acid (VMA) was developed using Ln3+-based metal-organic frameworks. The method exhibited fast response, low detection limits, and wide linear ranges, making it suitable for pheochromocytoma diagnosis.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Analytical
Yitong Sun, Huangting Ding, Meng Tang, Jingyi Wen, Shiwen Yue, Ye Peng, Liyan Zheng, Yonggang Shi, Qiue Cao
Summary: This paper introduces a novel strategy based on the instability of the Lewis acid-base pair (boron (B) and nitrogen (N)) to design and synthesize molecular switches with multicolor fluorescence switching capability. The compound BN-HDZ-N shows unprecedented visual identification for butanol isomers and can be used for simple and rapid visual identification. This provides a new strategy for the design and fabrication of novel multicolor-tunable molecular switches with visual identification of isomers.
ANALYTICAL CHEMISTRY
(2023)
Article
Nanoscience & Nanotechnology
Wenwen Fan, Yi Cheng, Mingxia Feng, Peng Liu, Longjie Wang, Yanxiong Liu, Qiu-E. Cao, Li-Yan Zheng
Summary: Lanthanidemetal-organic frameworks (Ln-MOFs) with exceptional optical performance and structural diversity offer a unique platform for the development of luminescent materials. However, Ln-MOFs often suffer from luminescence quenching by high-vibrating oscillators, especially in aqueous solution. Thus, multiple strategies have been adopted to improve the luminescence of Ln(3+).
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Multidisciplinary
Fenqiang Luo, Meng Guo, Liyan Zheng, Zhixiong Cai
Summary: An efficient fluorescence-enhanced probe, named CIT-Z, was developed for the detection of cyanide ions (CN-) based on a tetraphenylethene coordinated copper-iodide complex. The prepared coordination polymers exhibited a 3-fold-interpenetrating network structure with excellent optical properties and chemical stability. The probe showed high selectivity and sensitivity towards CN- with a detection limit of 0.1 μM in real water samples.
Article
Materials Science, Multidisciplinary
Longjie Wang, Yuchen Zhang, Xiangdi Huang, Yanxiong Liu, Yi Cheng, Wenwen Fan, Liyan Zheng, Qiue Cao
Summary: Since the discovery of aggregation-induced emission (AIE), the development of new AIE fluorogens (AIEgens) has become a significant field. This study focuses on altering the substituents of quinoline derivatives to achieve the conversion from aggregation-caused quenching (ACQ) to AIE. The experimental results reveal that the behavior of the derivatives can be converted by changing the electron-donating and electron-withdrawing groups (EDG and EWG).
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Article
Chemistry, Multidisciplinary
Huangting Ding, Yitong Sun, Meng Tang, Jingyi Wen, Shiwen Yue, Ye Peng, Fei Li, Liyan Zheng, Suning Wang, Yonggang Shi, Qiue Cao
Summary: This study reports organic room-temperature phosphorescence (RTP) materials based on triarylboranes. The photo-activated RTP materials have long lifetimes and high quantum yields, and show potential applications in information encryption, anti-counterfeiting, and water resistance.
Article
Chemistry, Analytical
Qian Zhou, Haili Zhao, Dan Chen, Haowei Sun, Ke Zhang, Chunqiong Wang, Qiue Cao, Liyan Zheng
Summary: In this study, three copper iodide coordination polymer isomers were prepared, and their fluorescence response to thiophanate-methyl pesticide residue was investigated. The results showed that the spatial structures of the coordination polymers played a crucial role in fluorescence enhancement, providing a new method for rapid and sensitive detection of pesticide residue.
Article
Chemistry, Multidisciplinary
Linlin Chen, Jing Cheng, Longjie Wang, Wenwen Fan, Zhixiang Lu, Liyan Zheng
Summary: In this study, a metal-organic cage named Ag-TBI-TPE with excellent antibacterial activity was prepared and used for wound healing. The cage displayed high antibacterial activity, particularly under UV irradiation, due to its photosensitivity and positive charge. The application of the Ag-TBI-TPE cage significantly accelerated the healing process of infected wounds, demonstrating satisfactory biocompatibility and bio-safety.
Article
Materials Science, Multidisciplinary
Yi Cheng, Wenwen Fan, Longjie Wang, Yanxiong Liu, Shaoxiong Yang, Yonggang Shi, Shixi Liu, Liyan Zheng, Qiue Cao
Summary: Researchers have developed a series of materials with ultralong room-temperature phosphorescence and photostimulus-responsive behavior through a simple doping process. These materials show fast activation and deactivation speeds, as well as excellent fatigue resistance. They can be used for anti-counterfeiting pattern applications, and the raw materials are easily accessible and low-cost.
JOURNAL OF MATERIALS CHEMISTRY C
(2022)
Article
Materials Science, Multidisciplinary
Longjie Wang, Yu Qin, Yi Cheng, Wenwen Fan, Shaoxiong Yang, Liyan Zheng, Qiue Cao
Summary: Aggregation-induced emission (AIE) is a novel phenomenon that has attracted significant attention. Existing research on AIE has mainly focused on the impact of molecular structures and solvents on AIE behavior, with limited exploration of the interaction between solvents and AIE aggregates. In this study, a series of AIE molecules were designed and synthesized, and the impact of solvents on their fluorescence properties was investigated. It was found that water molecules not only induce aggregation and inhibit nonradiative transitions, but also trigger fluorescence through hydrogen bond donation. These findings provide new insights for the design of AIE molecules.
JOURNAL OF MATERIALS CHEMISTRY C
(2022)
Article
Chemistry, Inorganic & Nuclear
Wenwen Fan, Yi Cheng, Baoru Wang, Longjie Wang, Qian Zhou, Yanxiong Liu, Chunqiong Wang, Liyan Zheng, Qiu'e Cao
Summary: A switch-on near-infrared luminescence sensing assay for kaempferol and quercetin was developed based on a metal-organic framework, showing efficient fluorescence enhancement mechanism and excellent sensing capability. The probe had a wide linear range, low detection limit, and short response time, and was successfully applied in determining the content of kaempferol and quercetin in samples with satisfactory results.
INORGANIC CHEMISTRY
(2022)