4.6 Article

Controlled synthesis of perovskite lanthanum ferrite nanotubes with excellent electrochemical properties

Journal

RSC ADVANCES
Volume 7, Issue 21, Pages 12931-12937

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra27423d

Keywords

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Funding

  1. Henan Provincial Department of Education [17A140013]
  2. National Natural Science Foundation of China [51472102, 21503194]
  3. Graduates' Scientific Research Foundation of Zhengzhou University of Light Industry

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In this work, we have fabricated a series of perovskite-type oxide LaFeO3 samples using a simple sol-gel method and further calcination treatment. We investigated the morphologies, structures and electrochemical performances of the fabricated samples in detail by controlling the calcination temperature and time. The morphology characterization indicates that when the calcination temperature and time are 700 degrees C and 3 h, respectively, LaFeO3 presents as a large number of nanotubes with a diameter of 25 nm. Electrochemical performance testing indicates that the tubular LaFeO3 shows excellent electrochemical performance. When 2 M KOH is used as the electrolyte, the LaFeO3 nanotubes exhibit a high specific capacitance of 313.21 F g(-1) at a current density of 0.8 A g(-1). In addition, the electrode maintains 86.1% of the initial specific capacitance after 5000 cycles at a scan rate of 100 mV s(-1), indicating good long-cycle stability. These results indicate that LaFeO3 nanotubes are a novel pseudocapacitance electrode material for application in energy storage devices.

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