Journal
RSC ADVANCES
Volume 7, Issue 52, Pages 32581-32590Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ra04742h
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Funding
- Russian Science Foundation [RSF-DST No. 16-43-02010]
- Russian Science Foundation [16-43-02010] Funding Source: Russian Science Foundation
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In this paper a new approach to the creation of a micro-meso-macroporous structure of Y zeolite was proposed. It was based on the selective crystallization into the integral cluster crystals of the preliminarily molded granules containing crystals of the zeolite in question and a porous binder matrix. The synthesized material was characterized by the high crystallinity degree of 95% and the volume of micro-, meso-, and macro-pores of 0.30, 0.15 and 0.15 cm(3) g(-1), respectively. It was shown that the Y zeolite with the hierarchical structure in H-form had the total acidity of about 830 mu mol g(-1) and revealed the high activity and selectivity in the synthesis of pyridines.
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