Journal
RSC ADVANCES
Volume 7, Issue 69, Pages 43655-43659Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ra09248b
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Funding
- European Union's Seventh Framework Programme [316955]
- EPSRC [EP/G007802/1]
- EPSRC [EP/G007802/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/G007802/1] Funding Source: researchfish
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A novel alpha-alkylation of N-diphenylphosphinoyl ketimines with alpha-bromocarbonyl compounds has been accomplished using visible light photoredox catalysis. The reaction proceeds under remarkably mild conditions: at 35 degrees C, in 20 hours, under blue light irradiation (1 W), in the presence of a tertiary amine and catalytic amounts of Ru- and Ni-based complexes. Chemoselective transformation of the products provides access to 1,4-dicarbonyl compounds, protected GABA analogues and gamma-lactams.
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