Journal
RSC ADVANCES
Volume 7, Issue 13, Pages 7619-7622Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra27921j
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Funding
- Persian Gulf University Research Council
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Solvent-free room temperature synthesis of tert-butyl peresters was achieved via copper-catalyzed oxidative-coupling of benzyl cyanides with tert-butyl hydroperoxide in short reaction times. Various derivatives of tert-butyl peresters were synthesized by this pathway in good to excellent yields. Further investigation revealed that the above-mentioned protocol is effective for the synthesis of benzoic acid derivatives when the reaction is conducted at 80 degrees C, under the same reaction conditions.
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