Deep Eutectic Mixtures: Promising Sustainable Solvents for Metal-Catalysed and Metal-Mediated Organic Reactions

Unexpected lateral-lithiation-induced alkylative ring opening of tetrahydrofurans in deep eutectic solvents: synthesis of functionalised primary alcohols

(2015) Francesca C. Sassone et al.   CHEMICAL COMMUNICATIONS

Deep eutectic solvents: biorenewable reaction media for Au(i)-catalysed cycloisomerisations and one-pot tandem cycloisomerisation/Diels–Alder reactions

(2015) C. Vidal et al.   GREEN CHEMISTRY

Deep Eutectic Solvents: Sustainable Media for Nanoscale and Functional Materials

(2014) Durgesh V. Wagle et al.   ACCOUNTS OF CHEMICAL RESEARCH

Introducing Deep Eutectic Solvents to Polar Organometallic Chemistry: Chemoselective Addition of Organolithium and Grignard Reagents to Ketones in Air

(2014) Cristian Vidal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterogeneous catalyst preparation in ionic liquids: Titania supported gold nanoparticles

(2014) Camella Oumahi et al.   CATALYSIS TODAY

Superparamagnetic CuFeO2Nanoparticles in Deep Eutectic Solvent: an Efficient and Recyclable Catalytic System for the Synthesis of Imidazo[1,2-a]pyridines

(2014) Jun Lu et al.   ChemCatChem

Introducing deep eutectic solvents as biorenewable media for Au(i)-catalysed cycloisomerisation of γ-alkynoic acids: an unprecedented catalytic system

(2014) María J. Rodríguez-Álvarez et al.   CHEMICAL COMMUNICATIONS

Regioselective desymmetrization of diaryltetrahydrofurans via directed ortho-lithiation: an unexpected help from green chemistry

(2014) Valentina Mallardo et al.   CHEMICAL COMMUNICATIONS

Deep Eutectic Solvents (DESs) and Their Applications

(2014) Emma L. Smith et al.   CHEMICAL REVIEWS

Ionic Liquids and Deep Eutectic Mixtures: Sustainable Solvents for Extraction Processes

(2014) Francisco Pena-Pereira et al.   ChemSusChem

Toxicity of Ionic Liquids: Eco(cyto)activity as Complicated, but Unavoidable Parameter for Task-Specific Optimization

(2014) Ksenia S. Egorova et al.   ChemSusChem

Low melting mixtures based on β-cyclodextrin derivatives and N,N′-dimethylurea as solvents for sustainable catalytic processes

(2014) François Jérôme et al.   GREEN CHEMISTRY

Glycerol: a biorenewable solvent for base-free Cu(i)-catalyzed 1,3-dipolar cycloaddition of azides with terminal and 1-iodoalkynes. Highly efficient transformations and catalyst recycling

(2014) Cristian Vidal et al.   GREEN CHEMISTRY

A facile one-pot synthesis of tetrasubstituted imidazoles catalyzed by eutectic mixture stabilized ferrofluid

(2014) Najmoddin Aziizi et al.   JOURNAL OF MOLECULAR LIQUIDS

Natural Deep Eutectic Solvents – Solvents for the 21st Century

(2014) Alexandre Paiva et al.   ACS Sustainable Chemistry & Engineering

Catalysis at room temperature: perspectives for future green chemical processes

(2014) Frank Leung-Yuk Lam et al.   Wiley Interdisciplinary Reviews-Energy and Environment

Natural deep eutectic solvents as new potential media for green technology

(2013) Yuntao Dai et al.   ANALYTICA CHIMICA ACTA

Low-Transition-Temperature Mixtures (LTTMs): A New Generation of Designer Solvents

(2013) María Francisco et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Deep eutectic solvents (DES) as green reaction media for the redox isomerization of allylic alcohols into carbonyl compounds catalyzed by the ruthenium complex [Ru(η3:η3-C10H16)Cl2(benzimidazole)]

(2013) Cristian Vidal et al.   CATALYSIS COMMUNICATIONS

Bio-based solvents: an emerging generation of fluids for the design of eco-efficient processes in catalysis and organic chemistry

(2013) Yanlong Gu et al.   CHEMICAL SOCIETY REVIEWS

Deep Eutectic Solvents in Polymerizations: A Greener Alternative to Conventional Syntheses

(2013) Francisco del Monte et al.   ChemSusChem

Comparative performance evaluation and systematic screening of solvents in a range of Grignard reactions

(2013) Asha Kadam et al.   GREEN CHEMISTRY

Gamma-valerolactone, a sustainable platform molecule derived from lignocellulosic biomass

(2013) David Martin Alonso et al.   GREEN CHEMISTRY

New Ag(I)–Iminophosphorane Coordination Polymers as Efficient Catalysts Precursors for the MW-Assisted Meyer–Schuster Rearrangement of Propargylic Alcohols in Water

(2013) Joaquín García-Álvarez et al.   INORGANIC CHEMISTRY

Synthesis and Reactivity of New Rhenium(I) Complexes Containing Iminophosphorane-Phosphine Ligands: Application to the Catalytic Isomerization of Propargylic Alcohols in Ionic Liquids

(2013) Joaquín García-Álvarez et al.   INORGANIC CHEMISTRY

One-pot synthesis of tri- and tetrasubstituted imidazoles using eutectic salts as ionic liquid catalyst

(2013) Akbar Mobinikhaledi et al.   RESEARCH ON CHEMICAL INTERMEDIATES

Choline chloride/CuCl as an effective homogeneous catalyst for palladium-free Sonogashira cross-coupling reactions

(2013) Abdol R. Hajipour et al.   TETRAHEDRON LETTERS

Water-Soluble Gold(I) and Gold(III) Complexes with Sulfonated N-Heterocyclic Carbene Ligands: Synthesis, Characterization, and Application in the Catalytic Cycloisomerization of γ-Alkynoic Acids into Enol-Lactones

(2013) Eder Tomás-Mendivil et al.   ACS Catalysis

Choline chloride based eutectic solvent: an efficient and reusable solvent system for the synthesis of primary amides from aldehydes and from nitriles

(2013) Umakant B. Patil et al.   RSC Advances

Exploiting the Lithiation-Directing Ability of Oxetane for the Regioselective Preparation of Functionalized 2-Aryloxetane Scaffolds under Mild Conditions

(2012) Donato Ivan Coppi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Continuous reactions in supercritical carbon dioxide: problems, solutions and possible ways forward

(2012) Xue Han et al.   CHEMICAL SOCIETY REVIEWS

Deep-eutectic solvents playing multiple roles in the synthesis of polymers and related materials

(2012) Daniel Carriazo et al.   CHEMICAL SOCIETY REVIEWS

Deep eutectic solvents: syntheses, properties and applications

(2012) Qinghua Zhang et al.   CHEMICAL SOCIETY REVIEWS

Highly Efficient Redox Isomerisation of Allylic Alcohols Catalysed by Pyrazole-Based Ruthenium(IV) Complexes in Water: Mechanisms of Bifunctional Catalysis in Water

(2012) Luca Bellarosa et al.   CHEMISTRY-A EUROPEAN JOURNAL

Directed Remote Aromatic Metalations: Mechanisms and Driving Forces

(2012) David Tilly et al.   CHEMISTRY-A EUROPEAN JOURNAL

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

(2012) Vittorio Pace et al.   ChemSusChem

Allylic alcohols as synthetic enolate equivalents: Isomerisation and tandem reactions catalysed by transition metal complexes

(2012) Nanna Ahlsten et al.   DALTON TRANSACTIONS

(Iminophosphorane)copper(I) Complexes as Highly Efficient Catalysts for 1,3-Dipolar Cycloaddition of Azides with Terminal and 1-Iodoalkynes in Water: One-Pot Multi-Component Reaction from Alkynes and in situ Generated Azides

(2012) Joaquín García-Álvarez et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Lactic acid as an invaluable bio-based solvent for organic reactions

(2012) Jie Yang et al.   GREEN CHEMISTRY

Pd(ii)-catalyzed cycloisomerisation of γ-alkynoic acids and one-pot tandem cycloisomerisation/CuAAC reactions in water

(2012) Joaquín García-Álvarez et al.   GREEN CHEMISTRY

Low melting mixtures in organic synthesis – an alternative to ionic liquids?

(2012) Carolin Ruß et al.   GREEN CHEMISTRY

Cycloisomerization versus Hydration Reactions in Aqueous Media: A Au(III)-NHC Catalyst That Makes the Difference

(2012) Eder Tomás-Mendivil et al.   ORGANIC LETTERS

Green Chemistry is Good Process Chemistry

(2012) Trevor Laird   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Transition metal-catalyzed addition of C-, N- and O-nucleophiles to unactivated C–C multiple bonds

(2012) Nitin T. Patil et al.   TETRAHEDRON

Catalytic Isomerization of Allylic Alcohols in Water

(2012) Pablo Lorenzo-Luis et al.   ACS Catalysis

Imidazole Based Ruthenium(IV) Complexes as Highly Efficient Bifunctional Catalysts for the Redox Isomerization of Allylic Alcohols in Aqueous Medium: Water as Cooperating Ligand

(2012) Josefina Díez et al.   ACS Catalysis

Novel rhenium(i) catalysts for the isomerization of propargylic alcohols into α,β-unsaturated carbonyl compounds: an unprecedented recyclable catalytic system in ionic liquids

(2011) Joaquín García-Álvarez et al.   CHEMICAL COMMUNICATIONS

Glycerol and derived solvents: new sustainable reaction media for organic synthesis

(2011) Alba E. Díaz-Álvarez et al.   CHEMICAL COMMUNICATIONS

Room-Temperature Ionic Liquids: Solvents for Synthesis and Catalysis. 2

(2011) Jason P. Hallett et al.   CHEMICAL REVIEWS

Platinum Metals in the Catalytic Asymmetric Isomerization of Allylic Alcohols

(2011) Luca Mantilli et al.   CHEMISTRY LETTERS

Searching for green solvents

(2011) Philip G. Jessop   GREEN CHEMISTRY

A one-pot catalysis: the strategic classification with some recent examples

(2011) Nitin T. Patil et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Organozinc Chemistry Enabled by Micellar Catalysis. Palladium-Catalyzed Cross-Couplings between Alkyl and ArylBromidesin Water at Room Temperature

(2011) Christophe Duplais et al.   ORGANOMETALLICS

Redox Isomerization of Allylic Alcohols into Carbonyl Compounds Catalyzed by the Ruthenium(IV) Complex [Ru(η3:η3-C10H16)Cl(κ2O,O-CH3CO2)] in Water and Ionic Liquids: Highly Efficient Transformations and Catalyst Recycling

(2011) Joaquín García-Álvarez et al.   ORGANOMETALLICS

Are Natural Deep Eutectic Solvents the Missing Link in Understanding Cellular Metabolism and Physiology?

(2011) Y. H. Choi et al.   PLANT PHYSIOLOGY

Iridium(I)-Catalyzed Coupling of (Z)-2-En-4-yn-1-ols with Activated Alkynes: A New Synthetic Route to 7-Oxanorbornadienes

(2010) Alba E. Díaz-Álvarez et al.   ADVANCED SYNTHESIS & CATALYSIS

Synthesis of Aryl Fluorides on a Solid Support and in Solution by Utilizing a Fluorinated Solvent

(2010) Marion Döbele et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Toxicity of imidazolium- and pyridinium-based ionic liquids and the co-metabolic degradation of N-ethylpyridinium tetrafluoroborate

(2010) C. Zhang et al.   CHEMOSPHERE

Chemistry by Nanocatalysis: First Example of a Solid-Supported RAPTA Complex for Organic Reactions in Aqueous Medium

(2010) Sergio E. García-Garrido et al.   ChemSusChem

Grignard Reactions in Pyridinium and Phosphonium Ionic Liquids

(2010) Leigh Ford et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Palladium-catalyzed cycloisomerization of (Z)-enynols into furans using green solvents: glycerol vs. water

(2010) Javier Francos et al.   GREEN CHEMISTRY

A highly efficient copper(i) catalyst for the 1,3-dipolar cycloaddition of azides with terminal and 1-iodoalkynes in water: regioselective synthesis of 1,4-disubstituted and 1,4,5-trisubstituted 1,2,3-triazoles

(2010) Joaquín García-Álvarez et al.   GREEN CHEMISTRY

Glycerol as a sustainable solvent for green chemistry

(2010) Yanlong Gu et al.   GREEN CHEMISTRY

Glycerol eutectics as sustainable solvent systems

(2010) Andrew P. Abbott et al.   GREEN CHEMISTRY

Ultrafast Grignard addition reactions in the presence of water

(2010) Gyorgyi Osztrovszky et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Stereoselective Negishi-like Couplings Between Alkenyl and Alkyl Halides in Water at Room Temperature

(2010) Arkady Krasovskiy et al.   ORGANIC LETTERS

Click chemistry under non-classical reaction conditions

(2009) C. Oliver Kappe et al.   CHEMICAL SOCIETY REVIEWS

Organic reactions in low melting mixtures based on carbohydrates and l-carnitine—a comparison

(2009) Florian Ilgen et al.   GREEN CHEMISTRY

Zn-Mediated, Pd-Catalyzed Cross-Couplings in Water at Room TemperatureWithoutPrior Formation of Organozinc Reagents

(2009) Arkady Krasovskiy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

E factors, green chemistry and catalysis: an odyssey

(2008) Roger A. Sheldon   CHEMICAL COMMUNICATIONS

Development of Highly Chemoselective Bulky Zincate Complex,tBu4ZnLi2: Design, Structure, and Practical Applications in Small-/Macromolecular Synthesis

(2008) Taniyuki Furuyama et al.   CHEMISTRY-A EUROPEAN JOURNAL

Solvents from nature

(2008) István T. Horváth   GREEN CHEMISTRY

Carbon-Centered Strong Bases in Phosphonium Ionic Liquids

(2008) Taramatee Ramnial et al.   JOURNAL OF ORGANIC CHEMISTRY