Evaluating the role of acidic, basic, and polar amino acids and dipeptides on a molecular electrocatalyst for H2 oxidation

Controlling Proton Delivery through Catalyst Structural Dynamics

(2016) Allan Jay P. Cardenas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Design and engineering of artificial oxygen-activating metalloenzymes

(2016) Flavia Nastri et al.   CHEMICAL SOCIETY REVIEWS

Optimizing conditions for utilization of an H2 oxidation catalyst with outer coordination sphere functionalities

(2016) Arnab Dutta et al.   DALTON TRANSACTIONS

Investigating the role of chain and linker length on the catalytic activity of an H2production catalyst containing a β-hairpin peptide

(2016) Matthew L. Reback et al.   JOURNAL OF COORDINATION CHEMISTRY

Achieving Reversible H2/H+ Interconversion at Room Temperature with Enzyme-Inspired Molecular Complexes: A Mechanistic Study

(2016) Nilusha Priyadarshani et al.   ACS Catalysis

Homogenous Electrocatalytic Oxygen Reduction Rates Correlate with Reaction Overpotential in Acidic Organic Solutions

(2016) Michael L. Pegis et al.   ACS Central Science

Photoswitching a molecular catalyst to regulate CO2 hydrogenation

(2015) Nilusha Priyadarshani et al.   DALTON TRANSACTIONS

The Role of Solvent and the Outer Coordination Sphere on H2Oxidation Using [Ni(PCy2NPyz2)2]2+

(2015) Arnab Dutta et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Nickel-Substituted Rubredoxin as a Minimal Enzyme Model for Hydrogenase

(2015) Jeffrey W. Slater et al.   Journal of Physical Chemistry Letters

Ab Initio-Based Kinetic Modeling for the Design of Molecular Catalysts: The Case of H2 Production Electrocatalysts

(2015) Ming-Hsun Ho et al.   ACS Catalysis

Beyond the Active Site: The Impact of the Outer Coordination Sphere on Electrocatalysts for Hydrogen Production and Oxidation

(2014) Bojana Ginovska-Pangovska et al.   ACCOUNTS OF CHEMICAL RESEARCH

Arginine-Containing Ligands Enhance H2Oxidation Catalyst Performance

(2014) Arnab Dutta et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Protein Design: Toward Functional Metalloenzymes

(2014) Fangting Yu et al.   CHEMICAL REVIEWS

Enzyme Design from the Bottom Up: An Active Nickel Electrocatalyst with a Structured Peptide Outer Coordination Sphere

(2014) Matthew L. Reback et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent achievments in the design and engineering of artificial metalloenzymes

(2014) Marc Dürrenberger et al.   CURRENT OPINION IN CHEMICAL BIOLOGY

Development of Molecular Electrocatalysts for Energy Storage

(2014) Daniel L. DuBois   INORGANIC CHEMISTRY

Amino acid modified Ni catalyst exhibits reversible H2oxidation/production over a broad pH range at elevated temperatures

(2014) Arnab Dutta et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

The Influence of the Second and Outer Coordination Spheres on Rh(diphosphine)2 CO2 Hydrogenation Catalysts

(2014) J. Timothy Bays et al.   ACS Catalysis

A modular, energy-based approach to the development of nickel containing molecular electrocatalysts for hydrogen production and oxidation

(2013) Wendy J. Shaw et al.   BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS

A proton channel allows a hydrogen oxidation catalyst to operate at a moderate overpotential with water acting as a base

(2013) Sheri Lense et al.   CHEMICAL COMMUNICATIONS

The Stabilization Effect of Dielectric Constant and Acidic Amino Acids on Arginine–Arginine (Arg–Arg) Pairings: Database Survey and Computational Studies

(2013) Zhengyan Zhang et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Minimal Proton Channel Enables H2 Oxidation and Production with a Water-Soluble Nickel-Based Catalyst

(2013) Arnab Dutta et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enhanced Photochemical Hydrogen Production by a Molecular Diiron Catalyst Incorporated into a Metal–Organic Framework

(2013) Sonja Pullen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Spontaneous activation of [FeFe]-hydrogenases by an inorganic [2Fe] active site mimic

(2013) Julian Esselborn et al.   Nature Chemical Biology

Conformational Dynamics and Proton Relay Positioning in Nickel Catalysts for Hydrogen Production and Oxidation

(2013) James A. Franz et al.   ORGANOMETALLICS

A Designed Functional Metalloenzyme that Reduces O2 to H2O with Over One Thousand Turnovers

(2012) Kyle D. Miner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Outer-Coordination Sphere: Incorporating Amino Acids and Peptides as Ligands for Homogeneous Catalysts to Mimic Enzyme Function

(2012) Wendy J. Shaw   CATALYSIS REVIEWS-SCIENCE AND ENGINEERING

Solar fuels generation and molecular systems: is it homogeneous or heterogeneous catalysis?

(2012) Vincent Artero et al.   CHEMICAL SOCIETY REVIEWS

The Role of a Dipeptide Outer-Coordination Sphere on H2-Production Catalysts: Influence on Catalytic Rates and Electron Transfer

(2012) Matthew L. Reback et al.   CHEMISTRY-A EUROPEAN JOURNAL

Investigating the Role of the Outer-Coordination Sphere in [Ni(PPh2NPh-R2)2]2+ Hydrogenase Mimics

(2012) Avijita Jain et al.   INORGANIC CHEMISTRY

Alteration of the oxygen-dependent reactivity of de novo Due Ferri proteins

(2012) Amanda J. Reig et al.   Nature Chemistry

Incorporating Amino Acid Esters into Catalysts for Hydrogen Oxidation: Steric and Electronic Effects and the Role of Water as a Base

(2012) Sheri Lense et al.   ORGANOMETALLICS

Active Hydrogenation Catalyst with a Structured, Peptide-Based Outer-Coordination Sphere

(2012) Avijita Jain et al.   ACS Catalysis

A hydrogenase model system based on the sequence of cytochrome c: photochemical hydrogen evolution in aqueous media

(2011) Yohei Sano et al.   CHEMICAL COMMUNICATIONS

Incorporating Peptides in the Outer-Coordination Sphere of Bioinspired Electrocatalysts for Hydrogen Production

(2011) Avijita Jain et al.   INORGANIC CHEMISTRY

Photocatalytic hydrogen evolution by a diiron hydrogenase model based on a peptide fragment of cytochrome c556 with an attached diiron carbonyl cluster and an attached ruthenium photosensitizer

(2011) Yohei Sano et al.   JOURNAL OF INORGANIC BIOCHEMISTRY

Hydrolytic catalysis and structural stabilization in a designed metalloprotein

(2011) Melissa L. Zastrow et al.   Nature Chemistry

[Ni(PPh2NBn2)2(CH3CN)]2+ as an Electrocatalyst for H2 Production: Dependence on Acid Strength and Isomer Distribution

(2011) Aaron M. Appel et al.   ACS Catalysis

Metal-Directed Protein Self-Assembly

(2010) Eric N. Salgado et al.   ACCOUNTS OF CHEMICAL RESEARCH

Protein-based hybrid catalysts—design and evolution

(2010) Valentin Köhler et al.   CURRENT OPINION IN BIOTECHNOLOGY

Artificial [FeFe]-Hydrogenase: On Resin Modification of an Amino Acid to Anchor a Hexacarbonyldiiron Cluster in a Peptide Framework

(2010) Souvik Roy et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

A Cyclodextrin Host/Guest Approach to a Hydrogenase Active Site Biomimetic Cavity

(2010) Michael L. Singleton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cooperative Effect of a Classical and a Weak Hydrogen Bond for the Metal-Induced Construction of a Self-Assembled β-Turn Mimic

(2009) Andy C. Laungani et al.   CHEMISTRY-A EUROPEAN JOURNAL

Resin-bound models of the [FeFe]-hydrogenase enzyme active site and studies of their reactivity

(2009) Kayla N. Green et al.   DALTON TRANSACTIONS

The Molecular Origin of Like-Charge Arginine−Arginine Pairing in Water

(2009) Jiří Vondrášek et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Rationally tuning the reduction potential of a single cupredoxin beyond the natural range

(2009) Nicholas M. Marshall et al.   NATURE

Designing artificial enzymes by intuition and computation

(2009) Vikas Nanda et al.   Nature Chemistry

The roles of the first and second coordination spheres in the design of molecular catalysts for H2production and oxidation

(2008) M. Rakowski DuBois et al.   CHEMICAL SOCIETY REVIEWS

Supramolecular Bidentate Ligands by Metal-Directed in situ Formation of Antiparallel β-Sheet Structures and Application in Asymmetric Catalysis

(2008) Andy C. Laungani et al.   CHEMISTRY-A EUROPEAN JOURNAL

Structural evolution of a recoverable rhodium hydrogenation catalyst

(2008) Wendy J. Shaw et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY