Journal
CATALYSIS SCIENCE & TECHNOLOGY
Volume 7, Issue 9, Pages 1921-1927Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cy00076f
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- Ministere de l'Education Nationale de l'Enseignement Superieur et de la Recherche (MNESR)
- Centre National de la Recherche Scientifique (CNRS)
- Chimie ParisTech
- Ecole Normale Superieure (ENS)
- Agence Nationale de la Recherche (ANR)
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We report the first copper-catalyzed olefinic ethoxy carbonyl difluoromethylation of alkenyl thioethers via direct C-H bond functionalization using BrCF2COOEt. The developed methodology allows the preparation of trisubstituted olefins with a controlled stereochemistry. A mechanistic study is reported and a radical mechanism is revealed.
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