Complete diastereodivergence in asymmetric 1,6-addition reactions enabled by minimal modification of a chiral catalyst

Stereodivergent Coupling of Aldehydes and Alkynes via Synergistic Catalysis Using Rh and Jacobsen’s Amine

(2017) Faben A. Cruz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diastereodivergent Catalysis Using Modularly Designed Organocatalysts: Synthesis of both cis - and trans -Fused Pyrano[2,3-b ]pyrans

(2016) Huicai Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalyst-Controlled Switch in Chemo- and Diastereoselectivities: Annulations of Morita-Baylis-Hillman Carbonates from Isatins

(2016) Gu Zhan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diastereodivergent Reverse Prenylation of Indole and Tryptophan Derivatives: Total Synthesis of Amauromine, Novoamauromine, and epi -Amauromine

(2016) Jonas M. Müller et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Catalyst-Enabled Diastereodivergent Aza-Diels-Alder Reaction: Complementarity ofN-Heterocyclic Carbenes and Chiral Amines

(2016) Zi-Qiang Rong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Origin of High Regio-, Diastereo-, and Enantioselectivities in 1,6-Addition of Azlactones to Dienyl N-Acylpyrroles: A Computational Study

(2016) Masahiro Yamanaka et al.   JOURNAL OF ORGANIC CHEMISTRY

Diastereodivergent Construction of Bicyclic γ-Lactones via Enantioselective Ketone Hydroacylation

(2016) Xuesong Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Ir/Zn Dual Catalysis for Enantio- and Diastereodivergent α-Allylation of α-Hydroxyketones

(2016) Xiaohong Huo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereodivergent Allylic Substitutions with Aryl Acetic Acid Esters by Synergistic Iridium and Lewis Base Catalysis

(2016) Xingyu Jiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-catalysed enantioselective stereodivergent synthesis of amino alcohols

(2016) Shi-Liang Shi et al.   NATURE

Diastereodivergent Asymmetric 1,4-Addition of Oxindoles to Nitroolefins by Using Polyfunctional Nickel-Hydrogen-Bond-Azolium Catalysts

(2015) Melanie Mechler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Catalytic Asymmetric Doubly Vinylogous Michael Addition of α,β-Unsaturated γ-Butyrolactams to Dienones

(2015) Xiaodong Gu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

HighlyE-Selective and Enantioselective Michael Addition to Electron-Deficient Internal Alkynes Under Chiral Iminophosphorane Catalysis

(2015) Daisuke Uraguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric γ-Allylation of α,β-Unsaturated Aldehydes by Combined Organocatalysis and Transition-Metal Catalysis

(2015) Line Naesborg et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phosphoric Acid Catalyzed Asymmetric 1,6-Conjugate Addition of Thioacetic Acid to para -Quinone Methides

(2015) Nan Dong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Remote Construction of Chiral Vicinal Tertiary and Quaternary Centers by Catalytic Asymmetric 1,6-Conjugate Addition of Prochiral Carbon Nucleophiles to Cyclic Dienones

(2015) Yuan Wei et al.   CHEMISTRY-A EUROPEAN JOURNAL

Scandium-Catalyzed Asymmetric 1,6-Addition of 3-Substituted Oxindoles to Linear Dienyl Ketones

(2015) Zhen Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Origins of Asymmetric Phosphazene Organocatalysis: Computations Reveal a Common Mechanism for Nitro- and Phospho-Aldol Additions

(2015) Luis Simón et al.   JOURNAL OF ORGANIC CHEMISTRY

Diastereodivergent Catalytic Asymmetric Michael Addition of 2-Oxindoles to α,β-Unsaturated Ketones by Chiral Diamine Catalysts

(2015) Yuan Wei et al.   ORGANIC LETTERS

Diastereodivergent organocatalysis for the asymmetric synthesis of chiral annulated furans

(2015) Charlie Verrier et al.   Chemical Science

Asymmetric Organocatalytic Synthesis of 3-Diarylmethine-Substituted Oxindoles Bearing a Quaternary Stereocenter via 1,6-Conjugate Addition to para-Quinone Methides

(2015) Kun Zhao et al.   ACS Catalysis

Bifunctional Squaramide Catalysts with the Same Absolute Chirality for the Diastereodivergent Access to Densely Functionalised Cyclohexanes through Enantioselective Domino Reactions. Synthesis and Mechanistic Studies

(2014) Jose I. Martínez et al.   ADVANCED SYNTHESIS & CATALYSIS

Highly Diastereodivergent Synthesis of Tetrasubstituted Cyclohexanes Catalyzed by Modularly Designed Organocatalysts

(2014) Nirmal K. Rana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

1,6-Addition Reaction of 5H-Oxazol-4-ones to Conjugated Dienones Catalyzed by Chiral Guanidines

(2014) Akane Morita et al.   CHEMISTRY LETTERS

Enantioselective Direct Bisvinylogous 1,6-Additions of β-Allyl-2-cyclohexenone to α,α-Dicyanodienes through Trienamine Catalysis

(2014) Xin Feng et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Remote Ester Groups Switch Selectivity: Diastereodivergent Synthesis of Tetracyclic Spiroindolines

(2014) Jun Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereodivergent α-Allylation of Linear Aldehydes with Dual Iridium and Amine Catalysis

(2014) Simon Krautwald et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of Quaternary α-Amino Acids and Their Phosphonate Analogues

(2014) Kalisankar Bera et al.   Asian Journal of Organic Chemistry

Enantio- and Diastereodivergent Dual Catalysis:  -Allylation of Branched Aldehydes

(2013) S. Krautwald et al.   SCIENCE

Asymmetric Michael additions of α-cyanoacetates by soft Lewis acid/hard Brønsted acid catalysis: stereodivergency with bi- vs. monometallic catalysts

(2013) Simon H. Eitel et al.   Chemical Science

Highly stereoselective Michael addition of azlactones to electron-deficient triple bonds under P-spiro chiral iminophosphorane catalysis: importance of protonation pathway

(2013) Daisuke Uraguchi et al.   Chemical Science

Diastereodivergent De-epimerization in Catalytic Asymmetric Allylic Alkylation

(2012) Davide Audisio et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral-Anion-Dependent Inversion of Diastereo- and Enantioselectivity in Carbonyl Crotylation via Ruthenium-Catalyzed Butadiene Hydrohydroxyalkylation

(2012) Emma L. McInturff et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Regio-, Diastereo-, and Enantioselective 1,6- and 1,8-Additions of Azlactones to Di- and Trienyl N-Acylpyrroles

(2012) Daisuke Uraguchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

1,6-Conjugate Addition of Nucleophiles to α,β,γ,δ-Diunsaturated Systems

(2012) Artur Silva et al.   SYNTHESIS-STUTTGART

Controlled Assembly of Chiral Tetraaminophosphonium Aryloxide-Arylhydroxide(s) in Solution

(2011) Daisuke Uraguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Diastereodivergent Deracemization

(2011) Marco Luparia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereodivergent Direct Catalytic Asymmetric Mannich-Type Reactions of α-Isothiocyanato Ester with Ketimines

(2011) Gang Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Asymmetric 1,6-Addition Reactions

(2011) Akkattu T. Biju   ChemCatChem

N-Acylpyrroles: More Than Amides

(2011) Anna M. Goldys et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Diastereodivergent Asymmetric Sulfa-Michael Additions of α-Branched Enones using a Single Chiral Organic Catalyst

(2011) Xu Tian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly stereoselective catalytic conjugate addition of acyl anion equivalent to nitroolefins

(2011) Daisuke Uraguchi et al.   Chemical Science

Conjugate addition reactions of carbon nucleophiles to electron-deficient dienes

(2010) Aurelio G. Csákÿ et al.   CHEMICAL SOCIETY REVIEWS

Linking Structural Dynamics and Functional Diversity in Asymmetric Catalysis

(2009) Akihiro Nojiri et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Organic Ion Pair Catalysts Assembled Through a Hydrogen-Bonding Network

(2009) D. Uraguchi et al.   SCIENCE

Stereoselective syntheses of quaternary substituted α-amino acids using oxazol-5-(4H)-ones

(2009) Robert A. Mosey et al.   TETRAHEDRON-ASYMMETRY

Highly Diastereoselective Switchable Enantioselective Mannich Reaction of Glycine Derivatives with Imines

(2008) Xiao-Xia Yan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY