Mechanistic insights on the Pd-catalyzed addition of C–X bonds across alkynes – a combined experimental and computational study

An Exclusivelytrans-Selective Chlorocarbamoylation of Alkynes Enabled by a Palladium/Phosphaadamantane Catalyst

(2015) Christine M. Le et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Computational Studies of Synthetically Relevant Homogeneous Organometallic Catalysis Involving Ni, Pd, Ir, and Rh: An Overview of Commonly Employed DFT Methods and Mechanistic Insights

(2015) Theresa Sperger et al.   CHEMICAL REVIEWS

Highly Regio- and Diastereoselective Formation of Tetrasubstituted (Z)-1,2-Dihaloalkenes from the Halogenation of Trimethylsilyl Alkynes with ICl

(2015) Kyle C. Sproul et al.   ORGANIC LETTERS

The β-Silyl Effect on the Memory of Chirality in Friedel–Crafts Alkylation Using Chiral α-Aryl Alcohols

(2015) Toshiki Nokami et al.   ORGANIC LETTERS

Additive Effects in the Palladium-Catalyzed Carboiodination of ChiralN-Allyl Carboxamides

(2014) David A. Petrone et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synergistic Steric Effects in the Development of a Palladium-Catalyzed Alkyne Carbohalogenation: Stereodivergent Synthesis of Vinyl Halides

(2014) Christine M. Le et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Computed ligand effects on the oxidative addition of phenyl halides to phosphine supported palladium(0) catalysts

(2014) Claire L. McMullin et al.   DALTON TRANSACTIONS

Oxidative Additions of Aryl Halides to Palladium Proceed through the Monoligated Complex

(2013) Krista Vikse et al.   ChemCatChem

Improved definition of bond orders for correlated wave functions

(2012) I. Mayer   CHEMICAL PHYSICS LETTERS

The 1-Phenyl-1-(trimethylsilyl)ethyl Cation: An NMR Spectroscopic and Computational Study of the α-Silyl Effect in Benzyl Cations

(2012) Arseni Kostenko et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Connecting Binuclear Pd(III) and Mononuclear Pd(IV) Chemistry by Pd–Pd Bond Cleavage

(2012) David C. Powers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

High-valent organometallic copper and palladium in catalysis

(2012) Amanda J. Hickman et al.   NATURE

Theoretical study of Pd(0)-catalyzed carbohalogenation of alkenes: mechanism and origins of reactivities and selectivities in alkyl halide reductive elimination from Pd(ii) species

(2012) Yu Lan et al.   Chemical Science

Carbon-Halogen Bond Formation by the Reductive Elimination of PdII Species

(2012) Xuefeng Jiang et al.   Asian Journal of Organic Chemistry

Bystanding F+ Oxidants Enable Selective Reductive Elimination from High-Valent Metal Centers in Catalysis

(2011) Keary M. Engle et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Solvent Effect on Palladium-Catalyzed Cross-Coupling Reactions and Implications on the Active Catalytic Species

(2011) Fabien Proutiere et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phosphine and solvent effects on oxidative addition of CH3Br to Pd(PR3) and Pd(PR3)2 complexes

(2011) Maria Besora et al.   DALTON TRANSACTIONS

Palladium-Catalyzed Carboiodination of Alkenes: Carbon−Carbon Bond Formation with Retention of Reactive Functionality

(2011) Stephen G. Newman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

How to Conceptualize Catalytic Cycles? The Energetic Span Model

(2010) Sebastian Kozuch et al.   ACCOUNTS OF CHEMICAL RESEARCH

Accurate modelling of Pd(0) + PhX oxidative addition kinetics

(2010) Claire L. McMullin et al.   DALTON TRANSACTIONS

Palladium-Catalyzed Conversion of Aryl and Vinyl Triflates to Bromides and Chlorides

(2010) Xiaoqiang Shen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bimetallic Reductive Elimination from Dinuclear Pd(III) Complexes

(2010) David C. Powers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

γ-Silyl Cyclobutyl Carbocations

(2009) Xavier Creary et al.   JOURNAL OF ORGANIC CHEMISTRY

Effect of Ligand Steric Properties and Halide Identity on the Mechanism for Oxidative Addition of Haloarenes to Trialkylphosphine Pd(0) Complexes

(2009) Fabiola Barrios-Landeros et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chelating N-Heterocyclic Carbene Alkoxide as a Supporting Ligand for PdII/IVC−H Bond Functionalization Catalysis

(2009) Polly L. Arnold et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bimetallic Pd(III) complexes in palladium-catalysed carbon–heteroatom bond formation

(2009) David C. Powers et al.   Nature Chemistry

Iron Trichloride-Promoted Cyclization ofo-Alkynylaryl Isocyanates: Synthesis of 3-(Chloromethylene)oxindoles

(2009) Guillaume Cantagrel et al.   ORGANIC LETTERS

Mechanistic Comparison between Pd-Catalyzed Ligand-Directed C−H Chlorination and C−H Acetoxylation

(2009) Kara J. Stowers et al.   ORGANIC LETTERS

Formation of ArF from LPdAr(F): Catalytic Conversion of Aryl Triflates to Aryl Fluorides

(2009) D. A. Watson et al.   SCIENCE

BIBF 1120: Triple Angiokinase Inhibitor with Sustained Receptor Blockade and Good Antitumor Efficacy

(2008) F. Hilberg et al.   CANCER RESEARCH