High-valent organometallic copper and palladium in catalysis

Copper-Catalyzed Aerobic Oxidative CH Functionalizations: Trends and Mechanistic Insights

(2011) Alison E. Wendlandt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed trifluoromethylation of aryl boronic acids using a CF3+ reagent

(2011) Jun Xu et al.   CHEMICAL COMMUNICATIONS

Large-Scale Applications of Transition Metal-Catalyzed Couplings for the Synthesis of Pharmaceuticals

(2011) Javier Magano et al.   CHEMICAL REVIEWS

Synthesis, Isolation, and Characterization of an Organometallic Triiodopalladium(IV) Complex. Quantitative and Regioselective Synthesis of Two C–I Reductive Elimination Products

(2011) José Vicente et al.   INORGANIC CHEMISTRY

Mechanistic and Computational Studies of Oxidatively-Induced Aryl−CF3Bond-Formation at Pd: Rational Design of Room Temperature Aryl Trifluoromethylation

(2011) Nicholas D. Ball et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H Bond Activation at Palladium(IV) Centers

(2011) Joy M. Racowski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Understanding of the Unexpected Meta Selectivity in Copper-Catalyzed Anilide C–H Bond Arylation

(2011) Bo Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nucleophilic Aryl Fluorination and Aryl Halide Exchange Mediated by a CuI/CuIIICatalytic Cycle

(2011) Alicia Casitas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalyst Control of Site Selectivity in the PdII/IV-Catalyzed Direct Arylation of Naphthalene

(2011) Amanda J. Hickman et al.   ACS Catalysis

Emergence of Palladium(IV) Chemistry in Synthesis and Catalysis

(2010) Petr Sehnal et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Copper Promoted C-N and C-O Type Cross-Coupling Reactions

(2010) Pralay Das et al.   CURRENT ORGANIC CHEMISTRY

The mechanism of the modified Ullmann reaction

(2010) Elena Sperotto et al.   DALTON TRANSACTIONS

Copper(II)-Catalyzed Ortho-Acyloxylation of the 2-Arylpyridines sp2C−H Bonds with Anhydrides, Using O2as Terminal Oxidant

(2010) Wenhui Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Computational Explorations of Mechanisms and Ligand-Directed Selectivities of Copper-Catalyzed Ullmann-Type Reactions

(2010) Gavin O. Jones et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alternative Mechanistic Explanation for Ligand-Dependent Selectivities in Copper-CatalyzedN- andO-Arylation Reactions

(2010) Hai-Zhu Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of C−F Reductive Elimination from Palladium(IV) Fluorides

(2010) Takeru Furuya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

On the Mechanism of Palladium-Catalyzed Aromatic C−H Oxidation

(2010) David C. Powers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzedortho-Trifluoromethylation of Arenes Using TFA as a Promoter

(2010) Xisheng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidation of a Cyclometalated Pd(II) Dimer with “CF3+”: Formation and Reactivity of a Catalytically Competent Monomeric Pd(IV) Aquo Complex

(2010) Yingda Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Oxidative Arylhalogenation of Alkenes: Synthetic Scope and Mechanistic Insights

(2010) Dipannita Kalyani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Aerobic Oxidative Functionalization of an Arene C−H Bond: Evidence for an Aryl-Copper(III) Intermediate

(2010) Amanda E. King et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Catalyzed Late-Stage Fluorination

(2010) Pingping Tang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Palladium-Catalyzed Trifluoromethylation of Aryl Chlorides

(2010) E. J. Cho et al.   SCIENCE

Direct observation of CuI/CuIII redox steps relevant to Ullmann-type coupling reactions

(2010) Alicia Casitas et al.   Chemical Science

The Organometallic Fluorine Chemistry of Palladium and Rhodium: Studies toward Aromatic Fluorination

(2009) Vladimir V. Grushin   ACCOUNTS OF CHEMICAL RESEARCH

Recent Applications of Palladium-Catalyzed Coupling Reactions in the Pharmaceutical, Agrochemical, and Fine Chemical Industries

(2009) Christian Torborg et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic CC, CN, and CO Ullmann-Type Coupling Reactions

(2009) Florian Monnier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

High-Oxidation-State Palladium Catalysis: New Reactivity for Organic Synthesis

(2009) Kilian Muñiz   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organopalladium(iv) chemistry

(2009) Ling-Min Xu et al.   CHEMICAL SOCIETY REVIEWS

Organopalladium and platinum chemistry in oxidising milieu as models for organic synthesis involving the higher oxidation states of palladium

(2009) Allan J. Canty   DALTON TRANSACTIONS

Copper-Catalyzed Synthesis of Benzoxazoles via a Regioselective C−H Functionalization/C−O Bond Formation under an Air Atmosphere

(2009) Satoshi Ueda et al.   JOURNAL OF ORGANIC CHEMISTRY

Chelating N-Heterocyclic Carbene Alkoxide as a Supporting Ligand for PdII/IVC−H Bond Functionalization Catalysis

(2009) Polly L. Arnold et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Intramolecular Aminofluorination of Unactivated Alkenes

(2009) Tao Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Carboamination of Alkenes Promoted byN-Fluorobenzenesulfonimide via C−H Activation of Arenes

(2009) Carolyn F. Rosewall et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed Hydroxylation of Arenes with 1 atm of O2or Air

(2009) Yang-Hui Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Reactivity of a Mono-σ-Aryl Palladium(IV) Fluoride Complex

(2009) Nicholas D. Ball et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthetic and Mechanistic Studies of Pd-Catalyzed C−H Arylation with Diaryliodonium Salts: Evidence for a Bimetallic High Oxidation State Pd Intermediate

(2009) Nicholas R. Deprez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bimetallic Palladium Catalysis: Direct Observation of Pd(III)−Pd(III) Intermediates

(2009) David C. Powers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Aerobic Oxidative Coupling of Terminal Alkynes withH-Phosphonates Leading to Alkynylphosphonates

(2009) Yuxing Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidatively Induced Carbon−Halogen Bond-Forming Reactions at Nickel

(2009) Andrew T. Higgs et al.   ORGANOMETALLICS

A Meta-Selective Copper-Catalyzed C-H Bond Arylation

(2009) R. J. Phipps et al.   SCIENCE

Synthesis of 2-Arylbenzoxazoles by Copper-Catalyzed Intramolecular Oxidative CO Coupling of Benzanilides

(2008) Satoshi Ueda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CH Functionalization/CN Bond Formation: Copper-Catalyzed Synthesis of Benzimidazoles from Amidines

(2008) Gordon Brasche et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Mediated Coupling Reactions and Their Applications in Natural Products and Designed Biomolecules Synthesis

(2008) Gwilherm Evano et al.   CHEMICAL REVIEWS

Copper-Catalyzed Aerobic Oxidative Amidation of Terminal Alkynes:  Efficient Synthesis of Ynamides

(2008) Tetsuya Hamada et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Preparation of σ- and π-Allylcopper(III) Intermediates in SN2 and SN2′ Reactions of Organocuprate(I) Reagents with Allylic Substrates

(2008) Erika R. Bartholomew et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper Complexes of Anionic Nitrogen Ligands in the Amidation and Imidation of Aryl Halides

(2008) Jesse W. Tye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu(II)-Catalyzed Direct and Site-Selective Arylation of Indoles Under Mild Conditions

(2008) Robert J. Phipps et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbon−Nitrogen Bond Formation Involving Well-Defined Aryl−Copper(III) Complexes

(2008) Lauren M. Huffman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Intramolecular Chloroamination of Alkenes

(2008) Forrest E. Michael et al.   ORGANIC LETTERS