Journal
SCIENCE OF ADVANCED MATERIALS
Volume 9, Issue 9, Pages 1616-1625Publisher
AMER SCIENTIFIC PUBLISHERS
DOI: 10.1166/sam.2017.3181
Keywords
Graphene Quantum Dots; Polymer Solar Cell; S and N Co-Doped GQDs; FeTSPP; PEDOT:PSS
Funding
- National Research Foundation of Korea (NRF) by the Korean government (MSIP) [2014R1A2A1A11051098]
- Chung-Ang University
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We report the use of composite layers of solution-processable poly(3,4 ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) and various graphene quantum dots (GQDs) as hole transport layers (HTLs) in high-performance polymer solar cells (PSCs). Three types of GQDs N-doped GQDs, S and N co-doped GQDs (S, N: GQDs), and Fe(III)tetra(4-sulfonatophenyl) porphyrin (FeTSPP) supported on S, N: GQDs and their composites with PEDOT:PSS were tested in PSCs. The PEDOT:PSS/FeTSPP@S, N: GQD composite HTL showed increased charge carrier transport due to enhanced conductivity resulting from the benzoid-quinoid transition and the well-matched work function between the FeTSPP@S, N: GQDs and PEDOT:PSS. Indeed, the PEDOT:PSS/FeTSPP@S, N: GQD composite HTL yielded an outstandingly improved power conversion efficiency (PCE) of 4.68% in PSCs, with a much more reproducible performance and longer lifetime than a reference PSC with a PEDOT:PSS HTL (PCE = 3.17%).
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