Interplay of hemilability and redox activity in models of hydrogenase active sites

Direct Observation of an Iron-Bound Terminal Hydride in [FeFe]-Hydrogenase by Nuclear Resonance Vibrational Spectroscopy

(2017) Edward J. Reijerse et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A matrix of heterobimetallic complexes for interrogation of hydrogen evolution reaction electrocatalysts

(2017) Pokhraj Ghosh et al.   Chemical Science

Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides

(2016) David Schilter et al.   CHEMICAL REVIEWS

Approaches to quantifying the electronic and steric properties of metallodithiolates as ligands in coordination chemistry

(2016) Jason A. Denny et al.   COORDINATION CHEMISTRY REVIEWS

Identification of a Catalytic Iron-Hydride at the H-Cluster of [FeFe]-Hydrogenase

(2016) David W. Mulder et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hemilabile Bridging Thiolates as Proton Shuttles in Bioinspired H2 Production Electrocatalysts

(2016) Shengda Ding et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible Photoinduced Reductive Elimination of H2 from the Nitrogenase Dihydride State, the E4(4H) Janus Intermediate

(2016) Dmitriy Lukoyanov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reductive Elimination of H2 Activates Nitrogenase to Reduce the N≡N Triple Bond: Characterization of the E4(4H) Janus Intermediate in Wild-Type Enzyme

(2016) Dmitriy Lukoyanov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-centred proton reduction catalysis in a model of [NiFe] hydrogenase

(2016) Deborah Brazzolotto et al.   Nature Chemistry

Synthetic Advances Inspired by the Bioactive Dinitrosyl Iron Unit

(2015) Randara Pulukkody et al.   ACCOUNTS OF CHEMICAL RESEARCH

Metallodithiolates as Ligands in Coordination, Bioinorganic, and Organometallic Chemistry

(2015) Jason A. Denny et al.   CHEMICAL REVIEWS

Identification of a Key Catalytic Intermediate Demonstrates That Nitrogenase Is Activated by the Reversible Exchange of N2 for H2

(2015) Dmitriy Lukoyanov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogens detected by subatomic resolution protein crystallography in a [NiFe] hydrogenase

(2015) Hideaki Ogata et al.   NATURE

Mechanism of hydrogen activation by [NiFe] hydrogenases

(2015) Rhiannon M Evans et al.   Nature Chemical Biology

Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage

(2014) Brian M. Hoffman et al.   CHEMICAL REVIEWS

Hydrogenases

(2014) Wolfgang Lubitz et al.   CHEMICAL REVIEWS

New Reactions of Terminal Hydrides on a Diiron Dithiolate

(2014) Wenguang Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox active iron nitrosyl units in proton reduction electrocatalysis

(2014) Chung-Hung Hsieh et al.   Nature Communications

Nitrogenase: A Draft Mechanism

(2013) Brian M. Hoffman et al.   ACCOUNTS OF CHEMICAL RESEARCH

A Functional [NiFe]Hydrogenase Mimic That Catalyzes Electron and Hydride Transfer from H2

(2013) S. Ogo et al.   SCIENCE

Identification and Characterization of the “Super-Reduced” State of the H-Cluster in [FeFe] Hydrogenase: A New Building Block for the Catalytic Cycle?

(2012) Agnieszka Adamska et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox-active ligands in catalysis

(2012) Oana R. Luca et al.   CHEMICAL SOCIETY REVIEWS

Dinitrosyl iron adducts of (N2S2)M(NO) complexes (M=Fe, Co) as metallodithiolate ligands

(2012) Chung-Hung Hsieh et al.   POLYHEDRON

Redox Non-Innocent Ligands: Versatile New Tools to Control Catalytic Reactions

(2012) Volodymyr Lyaskovskyy et al.   ACS Catalysis

Insights into [FeFe]-Hydrogenase Structure, Mechanism, and Maturation

(2011) David W. Mulder et al.   STRUCTURE

Solar Energy Supply and Storage for the Legacy and Nonlegacy Worlds

(2010) Timothy R. Cook et al.   CHEMICAL REVIEWS

Mechanism of electrocatalytic hydrogen production by a di-iron model of iron–iron hydrogenase: A density functional theory study of proton dissociation constants and electrode reduction potentials

(2010) Panida Surawatanawong et al.   DALTON TRANSACTIONS

Hydride-Containing Models for the Active Site of the Nickel−Iron Hydrogenases

(2010) Bryan E. Barton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A {Fe(NO)3}10Trinitrosyliron Complex Stabilized by an N-Heterocyclic Carbene and the Cationic and Neutral {Fe(NO)2}9/10Products of Its NO Release

(2010) Chung-Hung Hsieh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structural and Functional Analogues of the Active Sites of the [Fe]-, [NiFe]-, and [FeFe]-Hydrogenases†

(2009) Cédric Tard et al.   CHEMICAL REVIEWS

Nickel−Iron Dithiolato Hydrides Relevant to the [NiFe]-Hydrogenase Active Site

(2009) Bryan E. Barton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

[FeFe]-Hydrogenase Models and Hydrogen: Oxidative Addition of Dihydrogen and Silanes

(2008) Zachariah M. Heiden et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Terminal Hydride in [FeFe]-Hydrogenase Model Has Lower Potential for H2Production Than the Isomeric Bridging Hydride

(2008) Bryan E. Barton et al.   INORGANIC CHEMISTRY