To branch or not to branch: C–H selectivity of thiophene-based donor–acceptor–donor monomers in direct arylation polycondensation exemplified by PCDTBT

Direct heteroarylation polymerization: guidelines for defect-free conjugated polymers

(2017) Thomas Bura et al.   Chemical Science

Effects of the Terminal Structure, Purity, and Molecular Weight of an Amorphous Conjugated Polymer on Its Photovoltaic Characteristics

(2016) Junpei Kuwabara et al.   ACS Applied Materials & Interfaces

Direct (Hetero)arylation Polymerization: Simplicity for Conjugated Polymer Synthesis

(2016) Jean-Rémi Pouliot et al.   CHEMICAL REVIEWS

Tin-Free Direct C–H Arylation Polymerization for High Photovoltaic Efficiency Conjugated Copolymers

(2016) Alexander S. Dudnik et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

PCDTBT: From Polymer Photovoltaics to Light-Emitting Diodes by Side-Chain-Controlled Luminescence

(2016) Florian Lombeck et al.   MACROMOLECULES

An Indacenodithiophene–Quinoxaline Polymer Prepared by Direct Arylation Polymerization for Organic Photovoltaics

(2016) Shanshan Chen et al.   MACROMOLECULES

Suppression of Homocoupling Side Reactions in Direct Arylation Polycondensation for Producing High Performance OPV Materials

(2016) Junpei Kuwabara et al.   MACROMOLECULES

Mixed-Ligand Approach to Palladium-Catalyzed Direct Arylation Polymerization: Effective Prevention of Structural Defects Using Diamines

(2016) Eisuke Iizuka et al.   MACROMOLECULES

Structural effects of dibromocarbazoles on direct arylation polycondensation with 3,4-ethylenedioxythiophene

(2016) Wei Li et al.   Polymer Chemistry

C–H Arylation in the Synthesis of π-Conjugated Polymers

(2016) Sabin-Lucian Suraru et al.   ACS Macro Letters

PCDTBT based solar cells: one year of operation under real-world conditions

(2016) Yiwei Zhang et al.   Scientific Reports

High Mobility Ambipolar Diketopyrrolopyrrole-Based Conjugated Polymer Synthesized Via Direct Arylation Polycondensation

(2015) Yao Gao et al.   ADVANCED MATERIALS

Exciton Diffusion in Conjugated Polymers: From Fundamental Understanding to Improvement in Photovoltaic Conversion Efficiency

(2015) Yasunari Tamai et al.   Journal of Physical Chemistry Letters

Defect-free Naphthalene Diimide Bithiophene Copolymers with Controlled Molar Mass and High Performance via Direct Arylation Polycondensation

(2015) Rukiya Matsidik et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Balanced Ambipolar Poly(diketopyrrolopyrrole-alt-tetrafluorobenzene) Semiconducting Polymers Synthesized via Direct Arylation Polymerization

(2015) Kai Wang et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Defect Analysis of High Electron Mobility Diketopyrrolopyrrole Copolymers Made by Direct Arylation Polycondensation

(2015) Sebastian Broll et al.   MACROMOLECULES

Direct Arylation Polycondensation: A Promising Method for the Synthesis of Highly Pure, High-Molecular-Weight Conjugated Polymers Needed for Improving the Performance of Organic Photovoltaics

(2014) Junpei Kuwabara et al.   ADVANCED FUNCTIONAL MATERIALS

Structure–Function Relationships of High-Electron Mobility Naphthalene Diimide Copolymers Prepared Via Direct Arylation

(2014) Alessandro Luzio et al.   CHEMISTRY OF MATERIALS

Optimization of direct arylation polymerization (DArP) through the identification and control of defects in polymer structure

(2014) Andrey E. Rudenko et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Simple Synthesis of P(Cbz-alt-TBT) and PCDTBT by Combining Direct Arylation with Suzuki Polycondensation of Heteroaryl Chlorides

(2014) Florian Lombeck et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Scope and Limitations of a Direct Arylation Polycondensation Scheme in the Synthesis of PCPDTBT-Type Copolymers

(2014) Sebastian Kowalski et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Effects of PAr3 Ligands on Direct Arylation of Heteroarenes with Isolated [Pd(2,6-Me2C6H3)(μ-O2CMe)(PAr3)]4 Complexes

(2014) Masayuki Wakioka et al.   ORGANOMETALLICS

Remarkable Ligand Effect of P(2-MeOC6H4)3 on Palladium-Catalyzed Direct Arylation

(2014) Masayuki Wakioka et al.   ORGANOMETALLICS

Molecular weight dependent vertical composition profiles of PCDTBT:PC71BM blends for organic photovoltaics

(2014) James W. Kingsley et al.   Scientific Reports

Identifying Homocouplings as Critical Side Reactions in Direct Arylation Polycondensation

(2014) Florian Lombeck et al.   ACS Macro Letters

Conjugated Polymers à la Carte from Time-Controlled Direct (Hetero)Arylation Polymerization

(2014) Pierre-Olivier Morin et al.   ACS Macro Letters

Influence of β-linkages on the morphology and performance of DArP P3HT–PC61BM solar cells

(2013) Andrey E Rudenko et al.   NANOTECHNOLOGY

Thiophene based hyperbranched polymers with tunable branching using direct arylation methods

(2013) Ken Okamoto et al.   Polymer Chemistry

Direct heteroarylation of β-protected dithienosilole and dithienogermole monomers with thieno[3,4-c]pyrrole-4,6-dione and furo[3,4-c]pyrrole-4,6-dione

(2013) Lauren G. Mercier et al.   Polymer Chemistry

Direct arylation polycondensation as simplified alternative for the synthesis of conjugated (co)polymers

(2013) S. Kowalski et al.   PROGRESS IN POLYMER SCIENCE

Direct (Hetero)arylation Polymerization: An Effective Route to 3,4-Propylenedioxythiophene-Based Polymers with Low Residual Metal Content

(2013) Leandro A. Estrada et al.   ACS Macro Letters

PCDTBT: en route for low cost plastic solar cells

(2013) Serge Beaupré et al.   Journal of Materials Chemistry A

Origins of regioselectivity of the palladium-catalyzed (aromatic)CH bond metalation–deprotonation

(2012) Serge I. Gorelsky   COORDINATION CHEMISTRY REVIEWS

Direct arylation polycondensation for the synthesis of bithiophene-based alternating copolymers

(2012) Junpei Kuwabara et al.   Polymer Chemistry

Synthesis of Poly(4,4-dialkyl-cyclopenta[2,1-b:3,4-b′]dithiophene-alt-2,1,3-benzothiadiazole) (PCPDTBT) in a Direct Arylation Scheme

(2012) Sebastian Kowalski et al.   ACS Macro Letters

Synthesis of 5-Alkyl[3,4-c]thienopyrrole-4,6-dione-Based Polymers by Direct Heteroarylation

(2011) Philippe Berrouard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Polycondensation of Dibromofluorene Analogues with Tetrafluorobenzene via Direct Arylation

(2011) Wei Lu et al.   MACROMOLECULES

High Efficiency Polymer Solar Cells with Long Operating Lifetimes

(2011) Craig H. Peters et al.   Advanced Energy Materials

Synthesis of Thiophene- and Bithiophene-Based Alternating Copolymers via Pd-Catalyzed Direct C–H Arylation

(2011) Yohei Fujinami et al.   ACS Macro Letters

Synthesis and characterization of low bandgap conjugated donor–acceptor polymers for polymer:PCBM solar cells

(2010) Guoli Tu et al.   JOURNAL OF MATERIALS CHEMISTRY

Palladium-Catalyzed Dehydrohalogenative Polycondensation of 2-Bromo-3-hexylthiophene: An Efficient Approach to Head-to-Tail Poly(3-hexylthiophene)

(2010) Qifeng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY