Optimization of direct arylation polymerization (DArP) through the identification and control of defects in polymer structure

Two-Step direct arylation for synthesis of naphthalenediimide-based conjugated polymer

(2014) Yuta Nohara et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

One-Step Simple Preparation of Catalytic Initiators for Catalyst-Transfer Kumada Polymerization: Synthesis of Defect-Free Polythiophenes

(2014) Carlos A. Chavez et al.   MACROMOLECULES

A Highly Efficient Catalyst for the Synthesis of Alternating Copolymers with Thieno[3,4-c]pyrrole-4,6-dione Units via Direct Arylation Polymerization

(2014) Masayuki Wakioka et al.   MACROMOLECULES

Synthesis of diketopyrrolopyrrole based copolymers via the direct arylation method for p-channel and ambipolar OFETs

(2014) Prashant Sonar et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Light absorption of poly(3-hexylthiophene) single crystals

(2014) Khosrow Rahimi et al.   RSC Advances

Random Poly(3-hexylthiophene-co-3-cyanothiophene) Copolymers via Direct Arylation Polymerization (DArP) for Organic Solar Cells with High Open-Circuit Voltage

(2014) Andrey E. Rudenko et al.   ACS Macro Letters

Direct (Hetero)Arylation: A New Tool for Polymer Chemists

(2013) Lauren G. Mercier et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-catalyzed Direct Arylation Approach to Synthesize Naphthalene Bisimide-based Low-band-gap Polymers

(2013) Kazuhiro Nakabayashi et al.   CHEMISTRY LETTERS

Direct Arylation Polymerization: A Green, Streamlining Synthetic Approach to π -conjugated Polymers

(2013) Kai Wang et al.   CURRENT ORGANIC CHEMISTRY

Detection and role of trace impurities in high-performance organic solar cells

(2013) Maxim P. Nikiforov et al.   Energy & Environmental Science

Optimization of direct arylation polymerization conditions for the synthesis of poly(3-hexylthiophene)

(2013) Andrey E. Rudenko et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Synthesis and Photovoltaic Characterization of Dithieno[3,2-b:2′,3′-d]thiophene-Derived Narrow-Bandgap Polymers

(2013) Enwei Zhu et al.   MACROMOLECULAR CHEMISTRY AND PHYSICS

Synthesis of π-Conjugated Polymer Consisting of Pyrrole and Fluorene Units by Ru-Catalyzed Site-Selective Direct Arylation Polycondensation

(2013) Wei Lu et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Modular Establishment of a Diketopyrrolopyrrole-Based Polymer Library via Pd-Catalyzed Direct C-H (Hetero)arylation: a Highly Efficient Approach to Discover Low-Bandgap Polymers

(2013) Qiang Guo et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Effect of Polymorphism, Regioregularity and Paracrystallinity on Charge Transport in Poly(3-hexylthiophene) [P3HT] Nanofibers

(2013) Carl Poelking et al.   MACROMOLECULES

Tetrathiafulvalene (TTF)-Functionalized Thiophene Copolymerized with 3,3‴-Didodecylquaterthiophene: Synthesis, TTF Trapping Activity, and Response to Trinitrotoluene

(2013) Jasmine Sinha et al.   MACROMOLECULES

Novel Thiophene–Phenylene–Thiophene Fused Bislactam-Based Donor–Acceptor Type Conjugate Polymers: Synthesis by Direct Arylation and Properties

(2013) Mithrabinda K. Poduval et al.   MACROMOLECULES

C–H Arylation Reaction: Atom Efficient and Greener Syntheses of π-Conjugated Small Molecules and Macromolecules for Organic Electronic Materials

(2013) Ken Okamoto et al.   MACROMOLECULES

Langmuir–Blodgett Films of Amphiphilic Thieno[3,4-c]pyrrole-4,6-dione-Based Alternating Copolymers

(2013) Mariane Perpethue Ouattara et al.   MACROMOLECULES

A Highly Efficient Catalytic System for Polycondensation of 2,7-Dibromo-9,9-dioctylfluorene and 1,2,4,5-Tetrafluorobenzene via Direct Arylation

(2013) Masayuki Wakioka et al.   MACROMOLECULES

Influence of β-linkages on the morphology and performance of DArP P3HT–PC61BM solar cells

(2013) Andrey E Rudenko et al.   NANOTECHNOLOGY

Thiophene based hyperbranched polymers with tunable branching using direct arylation methods

(2013) Ken Okamoto et al.   Polymer Chemistry

Direct heteroarylation of β-protected dithienosilole and dithienogermole monomers with thieno[3,4-c]pyrrole-4,6-dione and furo[3,4-c]pyrrole-4,6-dione

(2013) Lauren G. Mercier et al.   Polymer Chemistry

Direct arylation polycondensation as simplified alternative for the synthesis of conjugated (co)polymers

(2013) S. Kowalski et al.   PROGRESS IN POLYMER SCIENCE

Direct (Hetero)arylation Polymerization: An Effective Route to 3,4-Propylenedioxythiophene-Based Polymers with Low Residual Metal Content

(2013) Leandro A. Estrada et al.   ACS Macro Letters

Fluorinated Porous Organic Polymers via Direct C–H Arylation Polycondensation

(2013) De-Peng Liu et al.   ACS Macro Letters

Microwave-Assisted Polycondensation via Direct Arylation of 3,4-Ethylenedioxythiophene with 9,9-Dioctyl-2,7-dibromofluorene

(2013) Seong Jib Choi et al.   ACS Sustainable Chemistry & Engineering

Additive-Free Bulk-Heterojuction Solar Cells with Enhanced Power Conversion Efficiency, Comprising a Newly Designed Selenophene-Thienopyrrolodione Copolymer

(2012) Dong Hwan Wang et al.   ADVANCED FUNCTIONAL MATERIALS

Semiconducting Polymers Prepared by Direct Arylation Polycondensation

(2012) Antonio Facchetti et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Origins of regioselectivity of the palladium-catalyzed (aromatic)CH bond metalation–deprotonation

(2012) Serge I. Gorelsky   COORDINATION CHEMISTRY REVIEWS

Effect of regioregularity on specific capacitance of poly(3-hexylthiophene)

(2012) P. Sivaraman et al.   ELECTROCHIMICA ACTA

Poly(3-hexylthiophene): synthetic methodologies and properties in bulk heterojunction solar cells

(2012) Assunta Marrocchi et al.   Energy & Environmental Science

Low-Cost Synthesis and Physical Characterization of Thieno[3,4-c]pyrrole-4,6-dione-Based Polymers

(2012) Philippe Berrouard et al.   JOURNAL OF ORGANIC CHEMISTRY

Effect of End Groups on Optoelectronic Properties of Poly(9,9-dioctylfluorene): A Study with Hexadecylfluorenes as Model Polymers

(2012) Qilin Wang et al.   Journal of Physical Chemistry C

Semi-random P3HT analogs via direct arylation polymerization

(2012) Andrey E. Rudenko et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

On the Role of Single Regiodefects and Polydispersity in Regioregular Poly(3-hexylthiophene): Defect Distribution, Synthesis of Defect-Free Chains, and a Simple Model for the Determination of Crystallinity

(2012) Peter Kohn et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Accessing New DPP-Based Copolymers by Direct Heteroarylation Polymerization

(2012) Jean-Rémi Pouliot et al.   MACROMOLECULAR CHEMISTRY AND PHYSICS

Detailed Optimization of Polycondensation Reaction via Direct C-H Arylation of Ethylenedioxythiophene

(2012) Koutarou Yamazaki et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Pd-Catalysed Direct Arylation Polymerisation for Synthesis of Low-Bandgap Conjugated Polymers and Photovoltaic Performance

(2012) Shu-Wei Chang et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Synthesis of End-capped Regioregular Poly(3-hexylthiophene)s via Direct Arylation

(2012) Qifeng Wang et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Facile Syntheses of Dioxythiophene-Based Conjugated Polymers by Direct C–H Arylation

(2012) Haichao Zhao et al.   MACROMOLECULES

Synthesis of Perfluoroalkyl End-Functionalized Poly(3-hexylthiophene) and the Effect of Fluorinated End Groups on Solar Cell Performance

(2012) Zhenghao Mao et al.   MACROMOLECULES

High Open-Circuit Voltage Solar Cells Based on New Thieno[3,4-c]pyrrole-4,6-dione and 2,7-Carbazole Copolymers

(2012) Ahmed Najari et al.   MACROMOLECULES

Thieno-, Furo-, and Selenopheno[3,4-c]pyrrole-4,6-dione Copolymers: Effect of the Heteroatom on the Electrooptical Properties

(2012) Serge Beaupré et al.   MACROMOLECULES

Synthesis of π-Conjugated Polymers Containing Fluorinated Arylene Units via Direct Arylation: Efficient Synthetic Method of Materials for OLEDs

(2012) Wei Lu et al.   MACROMOLECULES

Direct Arylation of 2-Methylthiophene with Isolated [PdAr(μ-O2CR)(PPh3)]n Complexes: Kinetics and Mechanism

(2012) Masayuki Wakioka et al.   ORGANOMETALLICS

Easy and versatile synthesis of new poly(thieno[3,4-d]thiazole)s

(2012) Nicolas Allard et al.   Polymer Chemistry

Synthesis of 4,4′-dinonyl-2,2′-bithiazole-based copolymers via Pd-catalyzed direct C–H arylation

(2012) Wei Lu et al.   Polymer Chemistry

Synthesis of new n-type isoindigo copolymers

(2012) François Grenier et al.   Polymer Chemistry

Direct arylation polycondensation for the synthesis of bithiophene-based alternating copolymers

(2012) Junpei Kuwabara et al.   Polymer Chemistry

A New Terthiophene-Thienopyrrolodione Copolymer-Based Bulk Heterojunction Solar Cell with High Open-Circuit Voltage

(2012) Jang Jo et al.   Advanced Energy Materials

Synthesis of Poly(4,4-dialkyl-cyclopenta[2,1-b:3,4-b′]dithiophene-alt-2,1,3-benzothiadiazole) (PCPDTBT) in a Direct Arylation Scheme

(2012) Sebastian Kowalski et al.   ACS Macro Letters

End-Capping Effect of a Narrow Bandgap Conjugated Polymer on Bulk Heterojunction Solar Cells

(2011) Jin Kuen Park et al.   ADVANCED MATERIALS

Synthesis of 5-Alkyl[3,4-c]thienopyrrole-4,6-dione-Based Polymers by Direct Heteroarylation

(2011) Philippe Berrouard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stille Polycondensation for Synthesis of Functional Materials

(2011) Bridget Carsten et al.   CHEMICAL REVIEWS

Analysis of the Palladium-Catalyzed (Aromatic)C–H Bond Metalation–Deprotonation Mechanism Spanning the Entire Spectrum of Arenes

(2011) Serge I. Gorelsky et al.   JOURNAL OF ORGANIC CHEMISTRY

Optoelectronic Properties of Hyperbranched Polythiophenes

(2011) Hannah S. Mangold et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Assessment of the Intermediacy of Arylpalladium Carboxylate Complexes in the Direct Arylation of Benzene: Evidence for C−H Bond Cleavage by “Ligandless” Species

(2011) Yichen Tan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Kumada Catalyst-Transfer Polycondensation: Mechanism, Opportunities, and Challenges

(2011) Anton Kiriy et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Polycondensation of Dibromofluorene Analogues with Tetrafluorobenzene via Direct Arylation

(2011) Wei Lu et al.   MACROMOLECULES

Ruthenium-Catalyzed Direct C–H Bond Arylations of Heteroarenes

(2011) Lutz Ackermann et al.   ORGANIC LETTERS

Synthesis of Thiophene- and Bithiophene-Based Alternating Copolymers via Pd-Catalyzed Direct C–H Arylation

(2011) Yohei Fujinami et al.   ACS Macro Letters

The Impact of Polymer Regioregularity on Charge Transport and Efficiency of P3HT:PCBM Photovoltaic Devices

(2010) Ralf Mauer et al.   ADVANCED FUNCTIONAL MATERIALS

High-Efficiency Organic Solar Cells Based on End-Functional-Group-Modified Poly(3-hexylthiophene)

(2010) Jong Soo Kim et al.   ADVANCED MATERIALS

Palladium-Catalyzed Dehydrohalogenative Polycondensation of 2-Bromo-3-hexylthiophene: An Efficient Approach to Head-to-Tail Poly(3-hexylthiophene)

(2010) Qifeng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Computational and Experimental Studies of Methyl Group Exchange between Palladium(II) Centers

(2010) Matthew S. Remy et al.   ORGANOMETALLICS

Palladium Nanoparticle Incorporation in Conjugated Microporous Polymers by Supercritical Fluid Processing

(2009) Tom Hasell et al.   CHEMISTRY OF MATERIALS

trans-Difluoro Complexes of Palladium(II)

(2009) Vladimir V. Grushin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Design of Soluble Hyperbranched Polythiophenes with Tailor-Made Optoelectronic Properties

(2009) Thomas V. Richter et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Suzuki Polycondensation: Polyarylenes à la Carte

(2009) Junji Sakamoto et al.   MACROMOLECULAR RAPID COMMUNICATIONS

The Grignard Reagents

(2009) Dietmar Seyferth   ORGANOMETALLICS

Single step reductive polymerization of functional 3,4-propylenedioxythiophenes via direct C–H arylation catalyzed by palladium acetate

(2009) Anshu Kumar et al.   Polymer Chemistry

Advances in Molecular Design and Synthesis of Regioregular Polythiophenes

(2008) Itaru Osaka et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-Nanoparticle-Catalysed Ullmann Reactions in Ionic Liquids with Aldehydes as the Reductants: Scope and Mechanism

(2008) Vincenzo Calò et al.   CHEMISTRY-A EUROPEAN JOURNAL

Analysis of the Concerted Metalation-Deprotonation Mechanism in Palladium-Catalyzed Direct Arylation Across a Broad Range of Aromatic Substrates

(2008) Serge I. Gorelsky et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Influence of Poly(3-hexylthiophene) Regioregularity on Fullerene-Composite Solar Cell Performance

(2008) Claire H. Woo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY