Hypervalent Iodine Reagents in High Valent Transition Metal Chemistry

Continuous-Flow Synthesis and Derivatization of Aziridines through Palladium-Catalyzed C(sp3)−H Activation

(2016) Jacek Zakrzewski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Quest for Palladium-Catalysed Alkyl-Nitrogen Bond Formation

(2016) Kilian Muñiz et al.   CHEMICAL RECORD

Platinum-Catalyzed C–H Functionalization

(2016) Jay A. Labinger   CHEMICAL REVIEWS

Advances in Synthetic Applications of Hypervalent Iodine Compounds

(2016) Akira Yoshimura et al.   CHEMICAL REVIEWS

Gold catalysis in total synthesis – recent achievements

(2016) Daniel Pflästerer et al.   CHEMICAL SOCIETY REVIEWS

Accessing Pincer Bis(carbene) Ni(IV) Complexes from Ni(II) via Halogen and Halogen Surrogates

(2016) Gabriel Espinosa Martinez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Organometalllic NiIV Complex That Participates in Competing Transmetalation and C(sp2)–O Bond-Forming Reductive Elimination Reactions

(2016) Elizabeth A. Meucci et al.   ORGANOMETALLICS

Halide-Dependent Mechanisms of Reductive Elimination from Gold(III)

(2015) Matthew S. Winston et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of the Palladium-Catalyzed Arene C–H Acetoxylation: A Comparison of Catalysts and Ligand Effects

(2015) Amanda K. Cook et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidation of Ni(II) to Ni(IV) with Aryl Electrophiles Enables Ni-Mediated Aryl–CF3 Coupling

(2015) James R. Bour et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trap-Free Halogen Photoelimination from Mononuclear Ni(III) Complexes

(2015) Seung Jun Hwang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stable gold(III) catalysts by oxidative addition of a carbon–carbon bond

(2015) Chung-Yeh Wu et al.   NATURE

Design, synthesis, and carbon-heteroatom coupling reactions of organometallic nickel(IV) complexes

(2015) N. M. Camasso et al.   SCIENCE

Carbon–hydrogen (C–H) bond activation at PdIV: a Frontier in C–H functionalization catalysis

(2015) Joseph J. Topczewski et al.   Chemical Science

Nickel: The “Spirited Horse” of Transition Metal Catalysis

(2015) Valentine P. Ananikov   ACS Catalysis

Reactions of [PhI(pyridine)2]2+ with Model Pd and Pt II/IV Redox Couples

(2014) Robert Corbo et al.   INORGANIC CHEMISTRY

Nickel(II)-Catalyzed Direct Arylation of C–H Bonds in Aromatic Amides Containing an 8-Aminoquinoline Moiety as a Directing Group

(2014) Ayana Yokota et al.   JOURNAL OF ORGANIC CHEMISTRY

Facile Formation of Homoleptic Au(III) Trications via Simultaneous Oxidation and Ligand Delivery from [PhI(pyridine)2]2+

(2014) Robert Corbo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Cascade Carbochloromethylation of Activated Alkenes: Highly Efficient Access to Chloro-Containing Oxindoles

(2014) Ming-Zhu Lu et al.   ORGANIC LETTERS

An Efficient Palladium-Catalyzed CH Alkoxylation of Unactivated Methylene and Methyl Groups with Cyclic Hypervalent Iodine (I3+) Oxidants

(2013) Gang Shan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold-Catalyzed Regioselective Synthesis of 2- and 3-Alkynyl Furans

(2013) Yifan Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold-Catalyzed Alkynylation: Acetylene-Transfer instead of Functionalization

(2013) Jonathan P. Brand et al.   ISRAEL JOURNAL OF CHEMISTRY

Terminal Olefins to Linear α,β-Unsaturated Ketones: Pd(II)/Hypervalent Iodine Co-catalyzed Wacker Oxidation–Dehydrogenation

(2013) Marinus A. Bigi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Platinum-Catalyzed C–H Arylation of Simple Arenes

(2013) Anna M. Wagner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed Enantioselective C–H Activation/C–O Bond Formation: Synthesis of Chiral Benzofuranones

(2013) Xiu-Fen Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Palladium-Catalyzed Diamination of Alkenes Using N-Fluorobenzenesulfonimide

(2013) Erica L. Ingalls et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Exceptionally fast carbon–carbon bond reductive elimination from gold(III)

(2013) William J. Wolf et al.   Nature Chemistry

Oxyarylation and Aminoarylation of Styrenes Using Photoredox Catalysis

(2013) Gabriele Fumagalli et al.   ORGANIC LETTERS

Synthesis, Characterization, and Catalytic Activity of Cationic NHC Gold(III) Pyridine Complexes

(2013) Serena Orbisaglia et al.   ORGANOMETALLICS

Detailed Structural, Spectroscopic, and Electrochemical Trends of Halido Mono- and Bis(NHC) Complexes of Au(I) and Au(III)

(2013) Han Vinh Huynh et al.   ORGANOMETALLICS

Thermal versus Photochemical Reductive Elimination of Aryl Chlorides from NHC–Gold Complexes

(2013) Michael J. Ghidiu et al.   ORGANOMETALLICS

Mechanism of Pd-Catalyzed Ar–Ar Bond Formation Involving Ligand-Directed C–H Arylation and Diaryliodonium Oxidants: Computational Studies of Orthopalladation at Binuclear Pd(II) Centers, Oxidation To Form Binuclear Palladium(III) Species, and Ar···Ar Reductive Coupling

(2013) Allan J. Canty et al.   ORGANOMETALLICS

Cross-coupling of arene–gold(III) complexes

(2013) Manuel Hofer et al.   TETRAHEDRON

Redox-Controlled Selectivity of CH Activation in the Oxidative Cross-Coupling of Arenes

(2012) Xacobe C. Cambeiro et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Vicinal Difunctionalization of Internal Alkenes: Diastereoselective Synthesis of Diamines

(2012) Claudio Martínez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Intermolecular C(sp3)H Amidation

(2012) Álvaro Iglesias et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cyclometallated gold(iii) hydroxides as versatile synthons for Au–N, Au–C complexes and luminescent compounds

(2012) Dragoş-Adrian Roşca et al.   CHEMICAL COMMUNICATIONS

Studies on AlkylNitrogen Bond FormationviaReductive Elimination from Monomeric Palladium Complexes in High Oxidation State

(2012) Álvaro Iglesias et al.   HELVETICA CHIMICA ACTA

Oxygen Reduction Reactions of Monometallic Rhodium Hydride Complexes

(2012) Thomas S. Teets et al.   INORGANIC CHEMISTRY

Stereoselective Intermolecular Allylic C–H Trifluoroacetoxylation of Functionalized Alkenes

(2012) Rauful Alam et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Mediated Oxidative Fluorination for PET with Aqueous [18F] Fluoride

(2012) Eunsung Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Alkyl Ether Synthesis via Palladium-Catalyzed, Picolinamide-Directed Alkoxylation of Unactivated C(sp3)–H and C(sp2)–H Bonds at Remote Positions

(2012) Shu-Yu Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Connecting Binuclear Pd(III) and Mononuclear Pd(IV) Chemistry by Pd–Pd Bond Cleavage

(2012) David C. Powers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

High-valent organometallic copper and palladium in catalysis

(2012) Amanda J. Hickman et al.   NATURE

Asymmetric Chiral Ligand-Directed Alkene Dioxygenation

(2012) Sharon R. Neufeldt et al.   ORGANIC LETTERS

Para-Selective Gold-Catalyzed Direct Alkynylation of Anilines

(2012) Jonathan P. Brand et al.   ORGANIC LETTERS

C2-Selective Direct Alkynylation of Indoles

(2012) Gergely L. Tolnai et al.   ORGANIC LETTERS

Pd-Catalyzed C–H Fluorination with Nucleophilic Fluoride

(2012) Kate B. McMurtrey et al.   ORGANIC LETTERS

Gold-Catalyzed Direct Arylation

(2012) L. T. Ball et al.   SCIENCE

Intermolecular Regioselective 1,2-Diamination of Allylic Ethers

(2011) Kilian Muñiz et al.   ADVANCED SYNTHESIS & CATALYSIS

Gold for CC Coupling Reactions: A Swiss-Army-Knife Catalyst?

(2011) Hermann A. Wegner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Remarkably High Reactivity of Pd(OAc)2/Pyridine Catalysts: Nondirected CH Oxygenation of Arenes

(2011) Marion H. Emmert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Trifluoromethylation of Unactivated Olefins

(2011) Andrew T. Parsons et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Oxidative Trifluoromethylation of Indoles at Room Temperature

(2011) Xin Mu et al.   CHEMISTRY-A EUROPEAN JOURNAL

AuI/AuIII Catalysis: An Alternative Approach for CC Oxidative Coupling

(2011) Matthew N. Hopkinson et al.   CHEMISTRY-A EUROPEAN JOURNAL

Unexpected Outcomes of the Oxidation of (Pentafluorophenyl)triphenylphosphanegold(I)

(2011) Manuel Hofer et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Bis-N-heterocyclic Carbene Palladium(IV) Tetrachloride Complexes: Synthesis, Reactivity, and Mechanisms of Direct Chlorinations and Oxidations of Organic Substrates

(2011) A. Scott McCall et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic and Computational Studies of Oxidatively-Induced Aryl−CF3Bond-Formation at Pd: Rational Design of Room Temperature Aryl Trifluoromethylation

(2011) Nicholas D. Ball et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Heterocycle Synthesis via Direct C–H/N–H Coupling

(2011) Enrico T. Nadres et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Efficient Syntheses of Azetidines, Pyrrolidines, and Indolines via Palladium Catalyzed Intramolecular Amination of C(sp3)–H and C(sp2)–H Bonds at γ and δ Positions

(2011) Gang He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Modulating Sterics in Trimethylplatinum(IV) Diimine Complexes To Achieve C–C Bond-Forming Reductive Elimination

(2011) Michael P. Lanci et al.   ORGANOMETALLICS

A Fluoride-Derived Electrophilic Late-Stage Fluorination Reagent for PET Imaging

(2011) E. Lee et al.   SCIENCE

Catalyst Control of Site Selectivity in the PdII/IV-Catalyzed Direct Arylation of Naphthalene

(2011) Amanda J. Hickman et al.   ACS Catalysis

An Intermolecular Palladium-Catalyzed Diamination of Unactivated Alkenes

(2010) Álvaro Iglesias et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Alkynylation of Thiophenes: Cooperative Activation of TIPS-EBX with Gold and Brønsted Acids

(2010) Jonathan P. Brand et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective CH Borylation of Alkenes by Palladium Pincer Complex Catalyzed Oxidative Functionalization

(2010) Nicklas Selander et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Emergence of Palladium(IV) Chemistry in Synthesis and Catalysis

(2010) Petr Sehnal et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

C(sp3)-C(sp3) Bond Breaking in Methylenecyclopropanes Involving a AuI/AuIII Catalytic Cycle

(2010) Di-Han Zhang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Facile Access to Tetravalent Cerium Compounds: One-Electron Oxidation Using Iodine(III) Reagents

(2010) Peter Dröse et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aryl−CF3Bond-Forming Reductive Elimination from Palladium(IV)

(2010) Nicholas D. Ball et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold-Catalyzed Ethynylation of Arenes

(2010) Teresa de Haro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzedortho-Trifluoromethylation of Arenes Using TFA as a Promoter

(2010) Xisheng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidation of a Cyclometalated Pd(II) Dimer with “CF3+”: Formation and Reactivity of a Catalytically Competent Monomeric Pd(IV) Aquo Complex

(2010) Yingda Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bimetallic Reductive Elimination from Dinuclear Pd(III) Complexes

(2010) David C. Powers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed C−H Arylation of 2,5-Substituted Pyrroles

(2010) Anna M. Wagner et al.   ORGANIC LETTERS

Synthesis and Reactivity of NiII(Phpy)2(Phpy = 2-Phenylpyridine)†

(2010) Andrew T. Higgs et al.   ORGANOMETALLICS

Expeditious Synthesis of [Au(NHC)(L)]+(NHC = N-Heterocyclic Carbene; L = Phosphine or NHC) Complexes†

(2010) Sylvain Gaillard et al.   ORGANOMETALLICS

Synthesis, Reactivity, and Electrochemical Studies of Gold(I) and Gold(III) Complexes Supported byN-Heterocyclic Carbenes and Their Application in Catalysis

(2010) Marek Pažický et al.   ORGANOMETALLICS

The Palladium-Catalyzed Trifluoromethylation of Aryl Chlorides

(2010) E. J. Cho et al.   SCIENCE

Direct Alkynylation of Indole and Pyrrole Heterocycles

(2009) Jonathan P. Brand et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organopalladium(iv) chemistry

(2009) Ling-Min Xu et al.   CHEMICAL SOCIETY REVIEWS

Oxidative Interception of the Hydroamination Pathway: A Gold-Catalyzed Diamination of Alkenes

(2009) Alvaro Iglesias et al.   CHEMISTRY-A EUROPEAN JOURNAL

Organopalladium and platinum chemistry in oxidising milieu as models for organic synthesis involving the higher oxidation states of palladium

(2009) Allan J. Canty   DALTON TRANSACTIONS

Catalytic Direct Acetoxylation of Indoles

(2009) Ilga Mutule et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis, structure and reactivity of organogold compounds of relevance to homogeneous gold catalysis

(2009) A. Stephen K. Hashmi et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Versatile Pd(OTf)2·2H2O-Catalyzedortho-Fluorination Using NMP as a Promoter

(2009) Xisheng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Detailed Study of C−O and C−C Bond-Forming Reductive Elimination from Stable C2N2O2−Ligated Palladium(IV) Complexes

(2009) Joy M. Racowski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthetic and Mechanistic Studies of Pd-Catalyzed C−H Arylation with Diaryliodonium Salts: Evidence for a Bimetallic High Oxidation State Pd Intermediate

(2009) Nicholas R. Deprez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bimetallic Palladium Catalysis: Direct Observation of Pd(III)−Pd(III) Intermediates

(2009) David C. Powers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Diamination of Unactivated Alkenes UsingN-Fluorobenzenesulfonimide as Source of Electrophilic Nitrogen

(2009) Paul A. Sibbald et al.   ORGANIC LETTERS

Catalytic Allylic C−H Acetoxylation and Benzoyloxylation via Suggested (η3-Allyl)palladium(IV) Intermediates

(2009) Lukasz T. Pilarski et al.   ORGANIC LETTERS

O-Acetyl Oximes as Transformable Directing Groups for Pd-Catalyzed C−H Bond Functionalization

(2009) Sharon R. Neufeldt et al.   ORGANIC LETTERS

Oxidatively Induced Carbon−Halogen Bond-Forming Reactions at Nickel

(2009) Andrew T. Higgs et al.   ORGANOMETALLICS

A Meta-Selective Copper-Catalyzed C-H Bond Arylation

(2009) R. J. Phipps et al.   SCIENCE

PdII‐Catalyzed MonoselectiveorthoHalogenation of CH Bonds Assisted by Counter Cations: A Complementary Method to Directedortho Lithiation

(2008) Tian‐Sheng Mei et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Mediated Fluorination of Arylboronic Acids

(2008) Takeru Furuya et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Stable Tetraalkyl Complex of Nickel(IV)

(2008) Matthew Carnes et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct synthesis of bicyclic guanidines through unprecedented palladium(ii) catalysed diamination with copper chloride as oxidant

(2008) Claas H. Hövelmann et al.   CHEMICAL COMMUNICATIONS

Gold-catalyzed direct oxidative coupling reactions of non-activated arenes

(2008) Anirban Kar et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Palladium-Catalyzed Olefin Dioxygenation

(2008) Yang Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidative Pd(II)-Catalyzed C−H Bond Amination to Carbazole at Ambient Temperature

(2008) James A. Jordan-Hore et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu(II)-Catalyzed Direct and Site-Selective Arylation of Indoles Under Mild Conditions

(2008) Robert J. Phipps et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Sequential Intermolecular Aminopalladation/ortho-Arene C−H Activation Reactions ofN-Phenylpropiolamides with Phthalimide

(2008) Shi Tang et al.   ORGANIC LETTERS

Platinum(IV) Complexes: C−H Activation at Low Temperatures

(2008) Jemini Mamtora et al.   ORGANOMETALLICS

Reactions of Platinum(II) Complexes with Chloride-Based Oxidants: Routes to Pt(III) and Pt(IV) Products

(2008) Salena R. Whitfield et al.   ORGANOMETALLICS

A general gold-catalyzed direct oxidative coupling of non-activated arenes

(2007) Anirban Kar et al.   CHEMICAL COMMUNICATIONS

Oxidative Diamination of Alkenes with Ureas as Nitrogen Sources:  Mechanistic Pathways in the Presence of a High Oxidation State Palladium Catalyst

(2007) Kilian Muñiz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY