Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 147, Issue 21, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.5000755
Keywords
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Funding
- Department of Energy, Laboratory Directed Research and Development funding [DE-AC02-76SF00515]
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-76SF00515]
- Human Frontier Science Program
- NIST Innovations in Measurement Science Program
- DOE Office of Basic Energy Sciences
- National Institute of General Medical Sciences of the National Institutes of Health [R01GM040392]
- National Research Council Postdoctoral Fellowship
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We present X-ray absorption spectroscopy and resonant inelastic X-ray scattering (RIXS) measurements on the iron L-edge of 0.5 mM aqueous ferricyanide. These measurements demonstrate the ability of high-throughput transition-edge-sensor (TES) spectrometers to access the rich soft X-ray (100-2000 eV) spectroscopy regime for dilute and radiation-sensitive samples. Our low-concentration data are in agreement with high-concentration measurements recorded by grating spectrometers. These results show that soft-X-ray RIXS spectroscopy acquired by high-throughput TES spectrometers can be used to study the local electronic structure of dilute metal-centered complexes relevant to biology, chemistry, and catalysis. In particular, TES spectrometers have a unique ability to characterize frozen solutions of radiation-and temperature-sensitive samples. Published by AIP Publishing.
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