Chemoselective Carbophilic Addition of α-Diazoesters through Ligand-Controlled Gold Catalysis

A Non-Diazo Approach to α-Oxo Gold Carbenes via Gold-Catalyzed Alkyne Oxidation

(2014) Liming Zhang   ACCOUNTS OF CHEMICAL RESEARCH

Enantioselective Palladium-Catalyzed Insertion of α-Aryl-α-diazoacetates into the OH Bonds of Phenols

(2014) Xiu-Lan Xie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structure of a Reactive Gold Carbenoid

(2014) Günter Seidel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Experimental evaluation of the electron donor ability of a gold phosphine fragment in a gold carbene complex

(2014) Rachel E. M. Brooner et al.   CHEMICAL COMMUNICATIONS

Highly Site-Selective Direct C–H Bond Functionalization of Phenols with α-Aryl-α-diazoacetates and Diazooxindoles via Gold Catalysis

(2014) Zhunzhun Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselective Synthesis of Functionalized PyrrolesviaGold(I)-Catalyzed [3+2] Cycloaddition of Stabilized Vinyl Diazo Derivatives and Nitriles

(2013) Giacomo Lonzi et al.   ADVANCED SYNTHESIS & CATALYSIS

Gold-Catalyzed Formal Cycloaddition of 2-Ethynylbenzyl Ethers with Organic Oxides and α-Diazoesters

(2013) Samir Kundlik Pawar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Observation of a Cationic Gold(I)-Bicyclo[3.2.0]hept-1(7)-ene Complex Generated in the Cycloisomerization of a 7-Phenyl-1,6-enyne

(2013) Rachel E. M. Brooner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold Carbenoids: Lessons Learnt from a Transmetalation Approach

(2013) Günter Seidel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ambient gold-catalyzedO-vinylation of cyclic 1,3-diketone: A vinyl ether synthesis

(2013) Yumeng Xi et al.   Beilstein Journal of Organic Chemistry

Enantioselective Gold(I)-Catalyzed Vinylogous [3 + 2] Cycloaddition between Vinyldiazoacetates and Enol Ethers

(2013) John F. Briones et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Stereoselective Olefin Cyclopropanation of Diazooxindoles Catalyzed by a C2-Symmetric Spiroketal Bisphosphine/Au(I) Complex

(2013) Zhong-Yan Cao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synergistic Au/Ga Catalysis in Ambient Nakamura Reaction

(2013) Yumeng Xi et al.   ORGANIC LETTERS

A Csp3–Csp3 Bond Forming Reductive Condensation of α-Keto Esters and Enolizable Carbon Pronucleophiles

(2013) Wei Zhao et al.   ORGANIC LETTERS

Direct Spectroscopic Characterization of a Transitory Dirhodium Donor-Acceptor Carbene Complex

(2013) K. P. Kornecki et al.   SCIENCE

Transition-Metal-Catalyzed Enantioselective Heteroatom–Hydrogen Bond Insertion Reactions

(2012) Shou-Fei Zhu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Development of a Povarov Reaction/Carbene Generation Sequence for Alkenyldiazocarbonyl Compounds

(2012) Appaso Mahadev Jadhav et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent developments in copper-catalyzed reactions of diazo compounds

(2012) Xia Zhao et al.   CHEMICAL COMMUNICATIONS

Reactivity of Stabilized Vinyl Diazo Derivatives toward Unsaturated Hydrocarbons: Regioselective Gold-Catalyzed Carbon-Carbon Bond Formation

(2012) José Barluenga et al.   CHEMISTRY-A EUROPEAN JOURNAL

Gold(I)-Catalyzed Asymmetric Cyclopropenation of Internal Alkynes

(2012) John F. Briones et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tempering the Reactivities of Postulated α-Oxo Gold Carbenes Using Bidentate Ligands: Implication of Tricoordinated Gold Intermediates and the Development of an Expedient Bimolecular Assembly of 2,4-Disubstituted Oxazoles

(2012) Yingdong Luo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Guiding principles for site selective and stereoselective intermolecular C–H functionalization by donor/acceptor rhodium carbenes

(2011) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

Gold catalysis in total synthesis—an update

(2011) Matthias Rudolph et al.   CHEMICAL SOCIETY REVIEWS

Nature of the Intermediates in Gold(I)-Catalyzed Cyclizations of 1,5-Enynes

(2011) Verónica López-Carrillo et al.   CHEMISTRY-A EUROPEAN JOURNAL

Improving the Accuracy of Hybrid Meta-GGA Density Functionals by Range Separation

(2011) Roberto Peverati et al.   Journal of Physical Chemistry Letters

Gold-Catalyzed Formal [3 + 3] and [4 + 2] Cycloaddition Reactions of Nitrosobenzenes with Alkenylgold Carbenoids

(2011) Vinayak Vishnu Pagar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Potential Energy Surface for (Retro-)Cyclopropanation: Metathesis with a Cationic Gold Complex

(2011) Alexey Fedorov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Steering the Surprisingly Modular π-Acceptor Properties of N-Heterocyclic Carbenes: Implications for Gold Catalysis

(2010) Manuel Alcarazo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper(II) Triflate Catalyzed Intermolecular Aromatic Substitution of N,N-Disubstituted Anilines with Diazo Esters

(2010) Eiji Tayama et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Elementary Steps of Gold Catalysis: NMR Spectroscopy Reveals the Highly Cationic Character of a “Gold Carbenoid”

(2009) Günter Seidel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly active gold-based catalyst for the reaction of benzaldehyde with ethyl diazoacetate

(2009) Manuel R. Fructos et al.   CHEMICAL COMMUNICATIONS

Catalytic Carbene Insertion into C−H Bonds

(2009) Michael P. Doyle et al.   CHEMICAL REVIEWS

Addition of carbenes derived from aryldiazoacetates to arenes using chloro(tetraphenylporphyrinato)iron as catalyst

(2009) Harun M. Mbuvi et al.   JOURNAL OF PORPHYRINS AND PHTHALOCYANINES

Ligand-Controlled Access to [4 + 2] and [4 + 3] Cycloadditions in Gold-Catalyzed Reactions of Allene-Dienes

(2009) Pablo Mauleón et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold-Catalyzed [4C+2C] Cycloadditions of Allenedienes, including an Enantioselective Version with New Phosphoramidite-Based Catalysts: Mechanistic Aspects of the Divergence between [4C+3C] and [4C+2C] Pathways

(2009) Isaac Alonso et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A bonding model for gold(I) carbene complexes

(2009) Diego Benitez et al.   Nature Chemistry

Carbene or cation?

(2009) Antonio M. Echavarren   Nature Chemistry

“High Noon” in Gold Catalysis: Carbene versus Carbocation Intermediates

(2008) A. Stephen K. Hashmi   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

On the Nature of the Reactive Intermediates in Gold-Catalyzed Cycloisomerization Reactions

(2008) Alois Fürstner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand Effects in Homogeneous Au Catalysis

(2008) David J. Gorin et al.   CHEMICAL REVIEWS

Alternative Synthetic Methods through New Developments in Catalysis by Gold

(2008) Antonio Arcadi   CHEMICAL REVIEWS

Gold-Catalyzed Cycloisomerizations of Enynes: A Mechanistic Perspective

(2008) Eloísa Jiménez-Núñez et al.   CHEMICAL REVIEWS

Gold(I)-Catalyzed Intermolecular Addition of Carbon Nucleophiles to 1,5- and 1,6-Enynes

(2008) Catelijne H. M. Amijs et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion

(2008) Huw M. L. Davies et al.   NATURE

Recent studies on the reactions of α-diazocarbonyl compounds

(2008) Zhenhua Zhang et al.   TETRAHEDRON

Gold-catalyzed olefin cyclopropanation

(2008) Auxiliadora Prieto et al.   TETRAHEDRON

Golden Carousel in Catalysis: The Cationic Gold/Propargylic Ester Cycle

(2007) Andrea Correa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION