Significant developments in rare-earth-containing polyoxometalate chemistry: synthetic strategies, structural diversities and correlative properties

Recent Advances in Polyoxometalate-Catalyzed Reactions

(2015) Sa-Sa Wang et al.   CHEMICAL REVIEWS

Synthesis and magnetic properties of tartrate-bridging rare-earth-containing polytungstoarsenate aggregates from an adaptive precursor [As2W19O67(H2O)]14−

(2015) Yuan Wang et al.   DALTON TRANSACTIONS

A novel Dawson-like cerium(IV)-hybridizing selenotungstate Na13H7[Ce(SeW17O59)2]·31H2O

(2015) Hailou Li et al.   INORGANIC CHEMISTRY COMMUNICATIONS

Synthesis, structure, spectroscopic and ferroelectric properties of an acentric polyoxotungstate containing 1:2-type [Sm(α-PW11O39)2]11− fragment and d-proline components

(2015) Yingjie Liu et al.   SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY

Polyoxometalate based open-frameworks (POM-OFs)

(2014) Haralampos N. Miras et al.   CHEMICAL SOCIETY REVIEWS

Modular Molecules: Site-Selective Metal Substitution, Photoreduction, and Chirality in Polyoxometalate Hybrids

(2014) Michele Vonci et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cation-Directed Dimeric versus Tetrameric Assemblies of Lanthanide-Stabilized Dilacunary Keggin Tungstogermanates

(2014) Beñat Artetxe et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rectangle versus Square Oxalate-Connective Tetralanthanide Cluster Anchored in Lacunary Lindqvist Isopolytungstates: Syntheses, Structures, and Properties

(2014) Junwei Zhao et al.   CRYSTAL GROWTH & DESIGN

From a versatile arsenotungstate precursor to a large lanthanide-containing polyoxometalate–carboxylate hybrid

(2014) Suzhi Li et al.   CRYSTENGCOMM

Lanthanoid containing phosphotungstates: the syntheses, crystal structure, electrochemistry, photoluminescence and magnetic properties

(2014) Rakesh Gupta et al.   DALTON TRANSACTIONS

Syntheses, Crystal Structures and Solid-State Properties of the Lanthanoid-Containing Nanoclusters [(Ln2PW10O38)4(W3O8)(OH)4(H2O)2]26-

(2014) Rakesh Gupta et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Two Supramolecular Inorganic-Organic Hybrids of 12-Silicotungstic Acid Heteropolyoxometalate and Trinuclear Lanthanide Clusters: Syntheses, Structures, and Magnetic Properties

(2014) Nahid Lotfian et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Enantiomerically Pure Lanthanide–Organic Polytungstates Exhibiting Two-Photon Absorption Properties

(2014) Wei-Wei Ju et al.   INORGANIC CHEMISTRY

pH-Controlled and Sulfite Anion-Directed Assembly of a Family of Cerium(III)-Containing Polyoxotungstates Clusters

(2014) Wei-Chao Chen et al.   INORGANIC CHEMISTRY

Controlling the Ring Curvature, Solution Assembly, and Reactivity of Gigantic Molybdenum Blue Wheels

(2014) Weimin Xuan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent progress in metal-functionalized germanotungstates: from structures to properties

(2014) Yanzhou Li et al.   RSC Advances

Dimeric complexes of rare-earth substituted Keggin-type silicotungstates: syntheses, crystal structure and solid state properties

(2014) Mukesh Kumar Saini et al.   RSC Advances

Heterodinuclear Lanthanoid-Containing Polyoxometalates: Stepwise Synthesis and Single-Molecule Magnet Behavior

(2013) Rinta Sato et al.   CHEMISTRY-A EUROPEAN JOURNAL

Assembly of Cerium(III)-Stabilized Polyoxotungstate Nanoclusters with SeO32−/TeO32−Templates: From Single Polyoxoanions to Inorganic Hollow Spheres in Dilute Solution

(2013) Wei-Chao Chen et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Series of Multi-Dimensional Lanthanide-Containing Peroxoisopolymolybdates

(2013) Jingjing Wei et al.   CRYSTAL GROWTH & DESIGN

Assembly of chainlike polyoxometalate-based lanthanide complexes in one-pot reaction system

(2013) Xiao-Jia Feng et al.   CRYSTENGCOMM

An unprecedented trimer based on monovacant Dawson anion: [(α2-P2W17O61)Ln(H2O)4]321− (Ln = LaIII, CeIII and PrIII)

(2013) Shaowei Zhang et al.   CRYSTENGCOMM

Lanthanide-containing peroxoisopolytungstate with tetrahedral WO42− template core, [Ln4(WO4)(H2O)16{W7O22(O2)2}4]14−

(2013) Lanying Song et al.   CRYSTENGCOMM

Syntheses, structures, properties and DFT study of hybrid inorganic–organic architectures constructed from trinuclear lanthanide frameworks and Keggin-type polyoxometalates

(2013) Masoud Mirzaei et al.   DALTON TRANSACTIONS

Octanuclear {Ln(III)8}(Ln = Gd, Tb, Dy, Ho) Macrocyclic Complexes in a Cyclooctadiene-like Conformation: Manifestation of Slow Relaxation of Magnetization in the Dy(III) Derivative

(2013) Vadapalli Chandrasekhar et al.   INORGANIC CHEMISTRY

Mono- and Di-Lanthanide Derivatives of 22-Tungsto-2-antimonate(III), [Ln(H2O)4Sb2W21O72(OH)]10-and [Ln2(H2O)8Sb2W20O70)]8-

(2013) Amal H. Ismail et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Magnetic polyoxometalates: from molecular magnetism to molecular spintronics and quantum computing

(2012) Juan M. Clemente-Juan et al.   CHEMICAL SOCIETY REVIEWS

Engineering polyoxometalates with emergent properties

(2012) Haralampos N. Miras et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in paramagnetic-TM-substituted polyoxometalates (TM = Mn, Fe, Co, Ni, Cu)

(2012) Shou-Tian Zheng et al.   CHEMICAL SOCIETY REVIEWS

Polyoxometalate water oxidation catalysts and the production of green fuel

(2012) Hongjin Lv et al.   CHEMICAL SOCIETY REVIEWS

From serendipity to design of polyoxometalates at the nanoscale, aesthetic beauty and applications

(2012) Leroy Cronin et al.   CHEMICAL SOCIETY REVIEWS

Three-dimensional lanthanide polyoxometalate organic complexes: correlation of structure with properties

(2012) Ke Wang et al.   CRYSTENGCOMM

Lanthanide–tungstobismuthate clusters based on [BiW9O33]9− building units: synthesis, crystal structures, luminescent and magnetic properties

(2012) Keyu Cui et al.   DALTON TRANSACTIONS

Two dysprosium-incorporated tungstoarsenates: synthesis, structures and magnetic properties

(2012) Fengyan Li et al.   DALTON TRANSACTIONS

Two types of oxalate-bridging rare-earth-substituted Keggin-type phosphotungstates {[(α-PW11O39)RE(H2O)]2(C2O4)}10− and {(α-x-PW10O38)RE2(C2O4)(H2O)2}3−

(2012) Shaowei Zhang et al.   DALTON TRANSACTIONS

A series of three-dimensional architectures constructed from lanthanide-substituted polyoxometalosilicates and lanthanide cations or lanthanide–organic complexes as linkers

(2012) Haiyan An et al.   DALTON TRANSACTIONS

Assembly of Saturated Nb/W Mixed-Addendum Polyoxometalate [P2W15Nb3O62]9- and Lanthanide Ions (Ln = Eu, Ce)

(2012) Cong-Cong Li et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Two Types of Polyoxometalates Based on Circular P8W48Cluster Units and Different Inclusions of Tetralanthanide and Octamanganese Centers

(2012) Ling Huang et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Strategic Design and Refinement of Lewis Acid–Base Catalysis by Rare-Earth-Metal-Containing Polyoxometalates

(2012) Kosuke Suzuki et al.   INORGANIC CHEMISTRY

Diamond-Shaped [Ag4]4+ Cluster Encapsulated by Silicotungstate Ligands: Synthesis and Catalysis of Hydrolytic Oxidation of Silanes

(2011) Yuji Kikukawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Molecular Growth of a Core-Shell Polyoxometalate

(2011) Xikui Fang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Luminescent Functional Metal–Organic Frameworks

(2011) Yuanjing Cui et al.   CHEMICAL REVIEWS

Lanthanide Polyoxocationic Complexes: Experimental and Theoretical Stability Studies and Lewis Acid Catalysis

(2011) Hani El Moll et al.   CHEMISTRY-A EUROPEAN JOURNAL

Constructing nanosized polyanions with diverse structures by the self-assembly of W/Nb mixed-addendum polyoxometalate and lanthanide ion

(2011) Shu-Jun Li et al.   CRYSTENGCOMM

Lanthanoid-Containing Open Wells–Dawson Silicotungstates: Synthesis, Crystal Structures, and Properties

(2011) Lubin Ni et al.   INORGANIC CHEMISTRY

Utilizing the Adaptive Polyoxometalate [As2W19O67(H2O)]14–To Support a Polynuclear Lanthanoid-Based Single-Molecule Magnet

(2011) Chris Ritchie et al.   INORGANIC CHEMISTRY

Sensitization of Lanthanoid Luminescence by Organic and Inorganic Ligands in Lanthanoid-Organic-Polyoxometalates

(2011) Chris Ritchie et al.   INORGANIC CHEMISTRY

Enantioselective Resolutions and Circular Dichroism Studies of Lanthanide-Containing Keggin-Type [Ln(PW11O39)2]11–Polyoxometalates

(2011) Haruo Naruke et al.   INORGANIC CHEMISTRY

Synthesis and Crystal Structure of a Rare Tetra-Yttrium-Supported Krebs-Type Tungstoantimonate

(2011) Rongxin Tan et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Metal−Organic Frameworks with Functional Pores for Recognition of Small Molecules

(2010) Banglin Chen et al.   ACCOUNTS OF CHEMICAL RESEARCH

Giant Crown-Shaped Polytungstate Formed by Self-Assembly of CeIII-Stabilized Dilacunary Keggin Fragments

(2010) Santiago Reinoso et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Terbium Polyoxometalate Organic Complexes: Correlation of Structure with Luminescence Properties

(2010) Chris Ritchie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hybrid Organic−Inorganic Polyoxometalate Compounds: From Structural Diversity to Applications

(2010) Anne Dolbecq et al.   CHEMICAL REVIEWS

Chemoselective Catalysis with Organosoluble Lewis Acidic Polyoxotungstates

(2010) Nathalie Dupré et al.   CHEMISTRY-A EUROPEAN JOURNAL

Lewis-Acidic Polyoxometalates as Reusable Catalysts for the Synthesis of Glucuronic Acid Esters under Microwave Irradiation

(2010) Michael Bosco et al.   ChemSusChem

Disassembly and Reassembly of Polyoxometalates: The Formation of Chains from an Adaptable Precursor

(2010) Chris Ritchie et al.   CRYSTAL GROWTH & DESIGN

Self-assembly of dilacunary building blocks into high-nuclear [Ln16As16W164O576(OH)8(H2O)42]80−(Ln = EuIII, GdIII, TbIII, DyIII, and HoIII) polyoxotungstates

(2010) Firasat Hussain et al.   CRYSTENGCOMM

Four New Dysprosium and Neodymium Octamolybdate Hydrates: Assembly of RE2(Mo8O27) Sheets and Topotactic Transformations

(2010) Xiaojun Kuang et al.   INORGANIC CHEMISTRY

Three-Dimensional Architectures Based on Lanthanide-Substituted Double-Keggin-Type Polyoxometalates and Lanthanide Cations or Lanthanide-Organic Complexes

(2010) Haiyan An et al.   INORGANIC CHEMISTRY

Yttrium(III)-Containing Tungstoantimonate(III) Stabilized by Tetrahedral WO42−Capping Unit, [{Y(α-SbW9O31(OH)2)(CH3COO)(H2O)}3(WO4)]17−

(2010) Masooma Ibrahim et al.   INORGANIC CHEMISTRY

Cubic Polyoxometalate−Organic Molecular Cage

(2010) Shou-Tian Zheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Advances in Lanthanide-Containing Polyoxotungstates

(2010) Bassem S. Bassil et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

From Antenna to Assay: Lessons Learned in Lanthanide Luminescence

(2009) Evan G. Moore et al.   ACCOUNTS OF CHEMICAL RESEARCH

A Gadolinium-Bridged Polytungstoarsenate(III) Nanocluster: [Gd8As12W124O432(H2O)22]60���

(2009) Firasat Hussain et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Recognition of Hybrid Metal Oxide by Peptides

(2009) Kévin Micoine et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lanthanide-Based Luminescent Hybrid Materials

(2009) Koen Binnemans   CHEMICAL REVIEWS

Lanthanide luminescence for functional materials and bio-sciences

(2009) Svetlana V. Eliseeva et al.   CHEMICAL SOCIETY REVIEWS

Polyoxometalates: Fascinating structures, unique magnetic properties

(2009) Ulrich Kortz et al.   COORDINATION CHEMISTRY REVIEWS

Design of luminescent lanthanide complexes: From molecules to highly efficient photo-emitting materials

(2009) L. Armelao et al.   COORDINATION CHEMISTRY REVIEWS

Assembly Chemistry between Lanthanide Cations and Monovacant Keggin Polyoxotungstates: Two Types of Lanthanide Substituted Phosphotungstates [{(α-PW11O39H)Ln(H2O)3}2]6−and [{(α-PW11O39)Ln(H2O)(η2,μ-1,1)-CH3COO}2]10−

(2009) Jingyang Niu et al.   CRYSTAL GROWTH & DESIGN

New fabrication of lanthanide complexes based on the polyoxometalate ligand of the [α(1,4)-GeW10O38]12− anion

(2009) YunGao Li et al.   CRYSTENGCOMM

Caesium-templated lanthanoid-containing polyoxotungstates

(2009) Firasat Hussain et al.   DALTON TRANSACTIONS

Synthesis and Structural Characterization of the 28-Isopolytungstate Fragment [H2W28O95]20–Stabilized by Two External Lanthanide Ions [Ln2(H2O)10W28O93(OH)2]14–

(2009) Amal H. Ismail et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Zeolitic Polyoxometalate-Based Metal−Organic Frameworks (Z-POMOFs): Computational Evaluation of Hypothetical Polymorphs and the Successful Targeted Synthesis of the Redox-Active Z-POMOF1

(2009) L. Marleny Rodriguez-Albelo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structural Evolution of “S”-Shaped [H4W22O74]12−and “§”-Shaped [H10W34O116]18−Isopolyoxotungstate Clusters

(2008) Haralampos N. Miras et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Designed Synthesis of POM–Organic Frameworks from {Ni6PW9} Building Blocks under Hydrothermal Conditions

(2008) Shou-Tian Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lanthanide Bimetallic Helicates forin VitroImaging and Sensing

(2008) Jean-Claude G. Bünzli et al.   Annals of the New York Academy of Sciences

Polyoxotungstate-encapsulated Gd6and Yb10complexes

(2008) Firasat Hussain et al.   CHEMICAL COMMUNICATIONS

Chirality in Polyoxometalate Chemistry

(2008) Bernold Hasenknopf et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Pentadecatungstate with Dinuclear Cerium(III) Unit: Synthesis, Crystal Structure and Properties

(2008) Taohai Li et al.   INORGANIC CHEMISTRY

Discrete Polyoxovanadate Cluster into an Organic Free Metal-Oxide-Based Material: Syntheses, Crystal Structures, and Magnetic Properties of a New Series of Lanthanide Linked-POV Compounds [{Ln(H2O)6}2As8V14O42(SO3)]·8H2O (Ln = La3+, Sm3+, and Ce3+)†

(2008) T. Arumuganathan et al.   INORGANIC CHEMISTRY

22-Isopolytungstate Fragment [H2W22O74]14−Coordinated to Lanthanide Ions

(2008) Amal H. Ismail et al.   INORGANIC CHEMISTRY

Role of the Antenna in Tissue Selective Probes Built of Lanthanide−Organic Chelates

(2008) B. Andes Hess et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Synthesis and Catalysis of Di- and Tetranuclear Metal Sandwich-Type Silicotungstates [(γ-SiW10O36)2M2(μ-OH)2]10−and [(γ-SiW10O36)2M4(μ4-O)(μ-OH)6]8−(M = Zr or Hf)

(2008) Yuji Kikukawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A new polyoxometalate-based 3d–4f heterometallic aggregate: a model for the design and synthesis of new heterometallic clusters

(2007) Weilin Chen et al.   DALTON TRANSACTIONS