Recent advances in paramagnetic-TM-substituted polyoxometalates (TM = Mn, Fe, Co, Ni, Cu)

A Mixed-Valence Manganese Cubane Trapped by Inequivalent Trilacunary Polyoxometalate Ligands

(2011) Scott G. Mitchell et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Planar {Mn19(OH)12}26+ Unit Incorporated in a 60-Tungsto-6-Silicate Polyanion

(2011) Bassem S. Bassil et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Molecular Growth of a Core-Shell Polyoxometalate

(2011) Xikui Fang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hexadecacobalt(II)-Containing Polyoxometalate-Based Single-Molecule Magnet

(2011) Masooma Ibrahim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

{Mn14W48} aggregate: the perspective of isopolyanions as ligands

(2011) Xikui Fang et al.   CHEMICAL COMMUNICATIONS

A polyoxometalate-based single-molecule magnet with an S = 21/2 ground state

(2011) Xikui Fang et al.   CHEMICAL COMMUNICATIONS

High-Nuclearity Ni-Substituted Polyoxometalates: A Series of Poly(polyoxotungstate)s Containing 20-22 Nickel Centers

(2011) Xin-Xiong Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Three Transition-Metal Substituted Polyoxotungstates Containing Keggin Fragments: From Trimer to One-Dimensional Chain to Two-Dimensional Sheet

(2011) Lijuan Chen et al.   CRYSTAL GROWTH & DESIGN

Two 1-D multi-nickel substituted arsenotungstate aggregates

(2011) Junwei Zhao et al.   CRYSTENGCOMM

Hexameric polyoxometalates decorated by six 3d–4f heterometallic clusters

(2011) Zhi-Ming Zhang et al.   DALTON TRANSACTIONS

Wateroxidation catalyzed by a new tetracobalt-substituted polyoxometalate complex: [{Co4(μ-OH)(H2O)3}(Si2W19O70)]11−

(2011) Guibo Zhu et al.   DALTON TRANSACTIONS

New Type of Heterometallic 3d–4f Rhomblike Core in Weakley-Like Polyoxometalates

(2011) Santiago Reinoso et al.   INORGANIC CHEMISTRY

Route for the Elaboration of Functionalized Hybrid 3d-Substituted Trivacant Keggin Anions

(2011) Guillaume Rousseau et al.   INORGANIC CHEMISTRY

A novel 1D tungstoarsenate with mixed organic ligands assembled by hexa-Cu sandwiched Keggin units and dinuclear copper-oxalate complexes

(2011) Qiuxia Han et al.   INORGANIC CHEMISTRY COMMUNICATIONS

A series of Ni6-substituted polyoxometalates derivated from tripodal alcohol ligands

(2011) Xin-Xiong Li et al.   INORGANIC CHEMISTRY COMMUNICATIONS

Hydrothermal Synthesis and Structural Characterization of a New Keggin-Type Tungstogermanate Containing Heterometallic 3d–4f Cubane Clusters

(2011) Wei-Dong Wang et al.   JOURNAL OF CLUSTER SCIENCE

Synthesis, structure and magnetism of a S-shaped multi-iron substituted arsenotungstate containing a trivacant Keggin [B-α-AsVW9O34]9− and a hexavacant Keggin [α-AsVW6O26]11− fragments

(2011) Junwei Zhao et al.   JOURNAL OF SOLID STATE CHEMISTRY

Switching slow relaxation in a MnIII3MnIV cluster: an example of grafting single-molecule magnets onto polyoxometalates

(2010) Xikui Fang et al.   CHEMICAL COMMUNICATIONS

Hybrid Organic−Inorganic Polyoxometalate Compounds: From Structural Diversity to Applications

(2010) Anne Dolbecq et al.   CHEMICAL REVIEWS

A functionalized polyoxometalate solid for selective oxidation of styrene to benzaldehyde

(2010) Jing Tang et al.   DALTON TRANSACTIONS

Two hexa-TM-containing (TM = Co2+ and Ni2+) {P2W12}-based trimeric tungstophosphates

(2010) Shuang Yao et al.   DALTON TRANSACTIONS

A New Family of Sandwich-Type Polytungstophosphates Containing Two Types of Metals in the Central Belt: M′2M2(PW9O34)212−(M′ = Na or Li, M = Mn2+, Co2+, Ni2+, and Zn2+)

(2010) Yu Hou et al.   INORGANIC CHEMISTRY

Cobalt, Manganese, Nickel, and Vanadium Derivatives of the Cyclic 48-Tungsto-8-Phosphate [H7P8W48O184]33−

(2010) Bassem S. Bassil et al.   INORGANIC CHEMISTRY

New assembly of transition metal complexes based on [GeW9O34]10− building blocks: Syntheses, crystal structures and magnetic properties

(2010) Ning Jiang et al.   INORGANIC CHEMISTRY COMMUNICATIONS

A novel inorganic–organic hybrid 1D chain built by double banana-shaped tungstoarsenates {Co(Hen)[Co6As3W24O94(H2O)2]}228−

(2010) Pengtao Ma et al.   INORGANIC CHEMISTRY COMMUNICATIONS

A dimeric polyoxometalate sandwich motif containing a truncated {Mn3O4} cubane core

(2010) Scott G. Mitchell et al.   INORGANICA CHIMICA ACTA

Cubic Polyoxometalate−Organic Molecular Cage

(2010) Shou-Tian Zheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, crystal structure and property of a novel Nickel-containing tungstophosphate [Na3(H2O)8{Ni3(H2O)(B-α-PW9O34)(B-β-PW8 O31)}2]21−

(2010) Lili Chu et al.   SOLID STATE SCIENCES

Poly(polyoxotungstate)s with 20 Nickel Centers: From Nanoclusters to One-Dimensional Chains

(2009) Shou-Tian Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron Polyoxometalate Single-Molecule Magnets

(2009) Jean-Daniel Compain et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterometallic 3d–4f cubane clusters inserted in polyoxometalate matrices

(2009) Brigitte Nohra et al.   CHEMICAL COMMUNICATIONS

The trinity of polyoxometalates: connecting {M12} Keggin and {M18} Dawson clusters to triangles

(2009) Scott G. Mitchell et al.   CHEMICAL COMMUNICATIONS

Polyoxometalates: Fascinating structures, unique magnetic properties

(2009) Ulrich Kortz et al.   COORDINATION CHEMISTRY REVIEWS

Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions: first 65·8 CdSO4-type 3-D framework built by hexa-CuII sandwiched polyoxotungstates

(2009) Jun-Wei Zhao et al.   DALTON TRANSACTIONS

Grafting ligands to direct the self-assembly of Co/Ni2+ substituted polyoxometalate clusters

(2009) Chris Ritchie et al.   DALTON TRANSACTIONS

Acetate-controlled demetalation in multiiron polyoxometalates: A triiron cluster trapped between β- and γ-Keggin isomers

(2009) Bogdan Botar et al.   DALTON TRANSACTIONS

A functional hybrid polyoxometalate framework based on a ‘trilacunary’ heteropolyanion [(P4W6O34)2Co2Na2(H2O)2]18−

(2009) Chris Ritchie et al.   DALTON TRANSACTIONS

Preparation of polyoxometalates in ionic liquids by ionothermal synthesis

(2009) Shiwei Lin et al.   DALTON TRANSACTIONS

Dimeric Nickel(II) Containing Tungstogermanate [{β-GeNi2W10O36(OH)2(H2O)}2]12–

(2009) Nadeen H. Nsouli et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

An Unprecedented Trinuclear Dawson Sandwich Complex with Internal Lacuna: Synthesis and31P NMR Spectroscopic Analysis of the Symmetrical [NaNi3(H2O)2(P2W15O56)2]17���and [CoNi3(H2O)2(P2W15O56)2]16���Anions

(2009) Delphine Schaming et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Extending the Lindqvist Family to Late 3d Transition Metals: A Rational Entry to CoW5Hexametalate Chemistry

(2009) R. John Errington et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

A New Ni12Cluster Based on Polyoxometalate Ligands

(2009) Hong-Mei Zhang et al.   INORGANIC CHEMISTRY

Combination Chemistry of Hexa-Copper-Substituted Polyoxometalates Driven by the CuII−Polyhedra Distortion: From Tetramer, 1D Chain to 3D Framework

(2009) Bing Li et al.   INORGANIC CHEMISTRY

Copper-, Cobalt-, and Manganese-Containing 17-Tungsto-2-Germanates

(2009) Nadeen H. Nsouli et al.   INORGANIC CHEMISTRY

Mixed-Valent {Mn14} Aggregate Encapsulated by the Inorganic Polyoxometalate Shell: [MnIII13MnIIO12(PO4)4(PW9O34)4]31−

(2009) Qiong Wu et al.   INORGANIC CHEMISTRY

Heterometallic 3d−4f Polyoxometalate Derived from the Weakley-Type Dimeric Structure

(2009) Santiago Reinoso et al.   INORGANIC CHEMISTRY

A new polynuclear Fe(III) cluster based on inorganic O-donor polyoxometalate and organic N-donor ligands

(2009) Quan Shi et al.   INORGANIC CHEMISTRY COMMUNICATIONS

A new multi-cobalt-substituted C-shaped polyoxotungstogermanate, [((CoOH2)Co2GeW9O34)2(GeW6O26)]20−

(2009) Tong Ruizhan et al.   INORGANIC CHEMISTRY COMMUNICATIONS

Hydrothermal synthesis, crystal structure and magnetic characterization of three hexa-M substituted tungstoarsenates (M=Ni, Zn and Mn)

(2009) Zhifeng Zhao et al.   INORGANICA CHIMICA ACTA

Synthesis, characterization and crystal structure of a novel 2D network structure based on hexacopper(II) substituted tungstoantimonate

(2009) Li-Hua Bi et al.   INORGANICA CHIMICA ACTA

Hydrothermal Synthesis and Structural Characterization of Three One-Dimensional Heteropolytungstates Formed by Mono-CopperII-Substituted Dawson or Keggin Cluster Units

(2009) Bing Li et al.   JOURNAL OF CLUSTER SCIENCE

Two novel Krebs-type polyoxoanions [CuI2(WO2)2(β-XW9O33)2]12− (X=SbIII, BiIII) resulting in 2D layer structures linked by copper(I) ions and copper(II) complex groups

(2009) Wei Zhang et al.   JOURNAL OF MOLECULAR STRUCTURE

One-Pot Assembly of a New Mixed-Valent Aggregate Based on Inorganic Polyoxometalate Ligands

(2009) Weilin Chen et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

PO43−-Mediated Polyoxometalate Supercluster Assembly

(2008) Xikui Fang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Polyoxometalate-Mediated Self-Assembly of Single-Molecule Magnets: {[XW9 O34 ]2 [MnIII 4 MnII 2 O4 (H2 O)4 ]}12−

(2008) Chris Ritchie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

New trimeric polyoxotungstate aggregates based on [P2W12O48]14− building blocks

(2008) Zhi-Ming Zhang et al.   CHEMICAL COMMUNICATIONS

A polyoxometalate-based manganese carboxylate cluster

(2008) Xikui Fang et al.   CHEMICAL COMMUNICATIONS

Functionalization of polyoxometalates: towards advanced applications in catalysis and materials science

(2008) Anna Proust et al.   CHEMICAL COMMUNICATIONS

Fe2 and Fe4 Clusters Encapsulated in Vacant Polyoxotungstates: Hydrothermal Synthesis, Magnetic and Electrochemical Properties, and DFT Calculations

(2008) Céline Pichon et al.   CHEMISTRY-A EUROPEAN JOURNAL

Combination of Lacunary Polyoxometalates and High-Nuclear Transition Metal Clusters under Hydrothermal Conditions: IX. A Series of Novel Polyoxotungstates Sandwiched by Octa-Copper Clusters

(2008) Jun-Wei Zhao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Tetra-Transition-Metal Substituted Weakley-Type Sandwich Germanotungstates and their Derivatives Decorated by Transition-Metal Complexes

(2008) Jingping Wang et al.   CRYSTAL GROWTH & DESIGN

A new heart-like Co-containing polyoxoanion based on the lacunary Preyssler anion

(2008) Zhiming Zhang et al.   DALTON TRANSACTIONS

Isolation of extendable transition metal incorporated polyoxometalate intermediates with structural control

(2008) Scott G. Mitchell et al.   DALTON TRANSACTIONS

Acetate-driven polyoxometalate demetalation: An open-shell diiron polytungstate comprising two rotational Keggin isomers

(2008) Bogdan Botar et al.   DALTON TRANSACTIONS

Two Hexanickel-Substituted Keggin-Type Germanotungstates

(2008) Jun-Wei Zhao et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Copper-Complex-Linked Polytungsto-Bismuthate (-Antimonite) Chain Containing Sandwich Cu(II) Ions Partially Modified with Imidazole Ligand

(2008) Hong Liu et al.   INORGANIC CHEMISTRY

Octa- and Nonanuclear Nickel(II) Polyoxometalate Clusters: Synthesis and Electrochemical and Magnetic Characterizations

(2008) Céline Pichon et al.   INORGANIC CHEMISTRY

Water Substitution on Iron Centers: from 0D to 1D Sandwich Type Polyoxotungstates

(2008) Anne Dolbecq et al.   INORGANIC CHEMISTRY

Hydrothermal synthesis and structure of di-copperII-complex substituted monovacant polyoxotungstate with a 1D chain structure

(2008) Bing Li et al.   INORGANIC CHEMISTRY COMMUNICATIONS

A banana-shaped iron(III)-substituted tungstogermanate containing two types of lacunary polyoxometalate units

(2008) Bing Li et al.   INORGANIC CHEMISTRY COMMUNICATIONS

Hydrothermal Synthesis and Structural Characterization of Two Organic–Inorganic Hybrids Based on Sandwich-type Polyoxometalates

(2008) Bing Li et al.   JOURNAL OF CLUSTER SCIENCE

Synthesis, structure and magnetism of a one-dimensional silicotungstate array: K3H4Cu0.5{Cu[Cu7.5Si2W16O60(H2O)4(OH)4]2}·9H2O

(2008) Zhen Luo et al.   POLYHEDRON

Combination between lacunary polyoxometalates and high-nuclear transition metal clusters under hydrothermal conditions: first (3,6)-connected framework constructed from sandwich-type polyoxometalate building blocks containing a novel {Cu8} cluster

(2007) Jun-Wei Zhao et al.   CHEMICAL COMMUNICATIONS

Nucleation Process in the Cavity of a 48-Tungstophosphate Wheel Resulting in a 16-Metal-Centre Iron Oxide Nanocluster

(2007) Sib Sankar Mal et al.   CHEMISTRY-A EUROPEAN JOURNAL

Square versus tetrahedral iron clusters with polyoxometalate ligands

(2007) Céline Pichon et al.   DALTON TRANSACTIONS

Two extended structures constructed from sandwich-type polyoxometalates functionalized by organic amines

(2007) Zhiming Zhang et al.   DALTON TRANSACTIONS

A new polyoxometalate-based 3d–4f heterometallic aggregate: a model for the design and synthesis of new heterometallic clusters

(2007) Weilin Chen et al.   DALTON TRANSACTIONS

Synthesis, structure and magnetism of a new dimeric silicotungstate: K9Na2Cu0.5[γ-Cu2(H2O)SiW8O31]2·38H2O

(2007) Zhen Luo et al.   DALTON TRANSACTIONS

Sandwich transitional metal complexes with tungstobismuthates and 1-methylimidazole ligands: Syntheses, structures and magnetic properties

(2007) Hong Liu et al.   JOURNAL OF MOLECULAR STRUCTURE