Metal-free tandem oxidative C(sp3)–H bond functionalization of alkanes and dearomatization of N-phenyl-cinnamamides: access to alkylated 1-azaspiro[4.5]decanes

A novel carbamoyl radical based dearomatizing spiroacylation process

(2015) Alejandra Millán-Ortiz et al.   CHEMICAL COMMUNICATIONS

Metal-free cascade construction of C–C bonds by activation of inert C(sp3)–H bonds

(2015) Honglin Zhang et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed oxidative C(sp3)–H/N–H coupling of sulfoximines and amides with simple alkanes via a radical process

(2015) Fan Teng et al.   CHEMICAL COMMUNICATIONS

Copper(i)-promoted cycloalkylation–peroxidation of unactivated alkenes via sp3 C–H functionalisation

(2015) Arghya Banerjee et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Metal-Free Preparation of Cycloalkyl Aryl SulfidesviaDi-tert-butyl Peroxide-Promoted Oxidative C(sp3)H Bond Thiolation of Cycloalkanes

(2014) Jincan Zhao et al.   ADVANCED SYNTHESIS & CATALYSIS

Metal-free oxidative direct C(sp3)–H bond functionalization of ethers with α,α-diaryl allylic alcohols

(2014) Xue-Qiang Chu et al.   CHEMICAL COMMUNICATIONS

tert-Butyl peroxybenzoate (TBPB)-mediated 2-isocyanobiaryl insertion with 1,4-dioxane: efficient synthesis of 6-alkyl phenanthridines via C(sp3)–H/C(sp2)–H bond functionalization

(2014) Jia-Jia Cao et al.   CHEMICAL COMMUNICATIONS

The benzoyl peroxide-promoted functionalization of simple alkanes with 2-aryl phenyl isonitrile

(2014) Wanxing Sha et al.   CHEMICAL COMMUNICATIONS

Copper-catalysed oxidative C–H/C–H coupling between olefins and simple ethers

(2014) Dong Liu et al.   CHEMICAL COMMUNICATIONS

n-Bu4NI/TBHP-catalyzed direct amination of allylic and benzylic C(sp3)–H with anilines under metal-free conditions

(2014) Xusheng Zhang et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed tandem oxidative cyclization of cinnamamides with benzyl hydrocarbons through cross-dehydrogenative coupling

(2014) Shi-Liu Zhou et al.   CHEMICAL COMMUNICATIONS

Gold-catalyzed C(sp3)–H bond functionalization

(2014) Jin Xie et al.   CHEMICAL SOCIETY REVIEWS

Hypervalent Iodine-Mediated Selective Oxidative Functionalization of (Thio)chromones with Alkanes

(2014) Rishikesh Narayan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iron-Catalyzed Cross-Dehydrogenative Coupling Esterification of Unactive C(sp3)–H Bonds with Carboxylic Acids for the Synthesis of α-Acyloxy Ethers

(2014) Jincan Zhao et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Intramolecular Trifluoromethylation of N-Benzylacrylamides Coupled with Dearomatization: Access to CF3-Containing 2-Azaspiro[4.5]decanes

(2014) Guifang Han et al.   ORGANIC LETTERS

Copper-Mediated α-Trifluoromethylation of N-Phenylcinnamamides Coupled with Dearomatization: Access to Trifluoromethylated 1-Azaspiro[4.5]decanes

(2014) Guifang Han et al.   ORGANIC LETTERS

Cu-Catalyzed C(sp3)–H Bond Activation Reaction for Direct Preparation of Cycloallyl Esters from Cycloalkanes and Aromatic Aldehydes

(2014) Jincan Zhao et al.   ORGANIC LETTERS

A Free Radical Cascade Cyclization of Isocyanides with Simple Alkanes and Alcohols

(2014) Zejiang Li et al.   ORGANIC LETTERS

Metal-Free Oxidative C(sp3)–H Bond Functionalization of Alkanes and Conjugate Addition to Chromones

(2014) Jincan Zhao et al.   ORGANIC LETTERS

Copper catalyzed direct alkenylation of simple alkanes with styrenes

(2014) Yefeng Zhu et al.   Chemical Science

Synthesis of Oxindoles by Iron-Catalyzed Oxidative 1,2-Alkylarylation of Activated Alkenes with an Aryl C(sp2)H Bond and a C(sp3)H Bond Adjacent to a Heteroatom

(2013) Wen-Ting Wei et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Selective Oxidative Cross-Coupling of Simple Alkanes with Heteroarenes

(2013) Andrey P. Antonchick et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Functionalization of Tetrahydrofuran and 1,4-Dioxane: Nickel-Catalyzed Oxidative C(sp3)H Arylation

(2013) Dong Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Functionalization of C(sp2)H and C(sp3)H Bonds by Using Bidentate Directing Groups

(2013) Guy Rouquet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-free, highly efficient organocatalytic amination of benzylic C–H bonds

(2013) Qicai Xue et al.   CHEMICAL COMMUNICATIONS

Silver-catalyzed oxidative coupling/cyclization of acrylamides with 1,3-dicarbonyl compounds

(2013) Hua Wang et al.   CHEMICAL COMMUNICATIONS

Amide bond formation via C(sp3)–H bond functionalization and CO insertion

(2013) Huizhen Liu et al.   CHEMICAL COMMUNICATIONS

Iron-catalyzed direct alkenylation of sp3(C–H) bonds via decarboxylation of cinnamic acids under ligand-free conditions

(2013) Hailong Yang et al.   GREEN CHEMISTRY

Iron-Catalyzed Allylic Arylation of Olefins via C(sp3)–H Activation under Mild Conditions

(2013) Masaki Sekine et al.   ORGANIC LETTERS

Antiviral Spirooliganones A and B with Unprecedented Skeletons from the Roots of Illicium oligandrum

(2013) Shuang-Gang Ma et al.   ORGANIC LETTERS

Cu-Catalyzed Cross-Dehydrogenative Coupling Reactions of (Benzo)thiazoles with Cyclic Ethers

(2013) Zengyang Xie et al.   ORGANIC LETTERS

Directing Group Assisted Copper-Catalyzed Chemoselective O-Aroylation of Phenols and Enols Using Alkylbenzenes

(2013) Saroj Kumar Rout et al.   ORGANIC LETTERS

Free-Radical Cascade Alkylarylation of Alkenes with Simple Alkanes: Highly Efficient Access to Oxindoles via Selective (sp3)C–H and (sp2)C–H Bond Functionalization

(2013) Zejiang Li et al.   ORGANIC LETTERS

Metal-Free Oxidative C(sp3)–H Bond Thiolation of Ethers with Disulfides

(2013) Sheng-rong Guo et al.   ORGANIC LETTERS

When C–H bond functionalization meets visible-light photoredox catalysis

(2013) Jin Xie et al.   TETRAHEDRON LETTERS

Metal-Catalyzed Nitrogen-Atom Transfer Methods for the Oxidation of Aliphatic C–H Bonds

(2012) Jennifer L. Roizen et al.   ACCOUNTS OF CHEMICAL RESEARCH

Biomimetic diversity-oriented synthesis of benzannulated medium rings via ring expansion

(2012) Renato A Bauer et al.   Nature Chemical Biology

Application of Dearomatization Strategy on the Synthesis of Furoquinolinone and Angelicin Derivatives

(2012) Yang Ye et al.   ORGANIC LETTERS

CuI Controlled C–C and C–N Bond Formation of Heteroaromatics through C(sp3)–H Activation

(2012) Ran Xia et al.   ORGANIC LETTERS

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

If CH Bonds Could Talk: Selective CH Bond Oxidation

(2011) Timothy Newhouse et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bond Formations between Two Nucleophiles: Transition Metal Catalyzed Oxidative Cross-Coupling Reactions

(2011) Chao Liu et al.   CHEMICAL REVIEWS

Discorhabdins and Pyrroloiminoquinone-Related Alkaloids

(2011) Jin-Feng Hu et al.   CHEMICAL REVIEWS

Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

(2011) Charles S. Yeung et al.   CHEMICAL REVIEWS

Direct Sp3α-C–H activation and functionalization of alcohol and ether

(2011) Shu-Yu Zhang et al.   CHEMICAL SOCIETY REVIEWS

Guiding principles for site selective and stereoselective intermolecular C–H functionalization by donor/acceptor rhodium carbenes

(2011) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

A Strategy for the Late-Stage Divergent Syntheses of Scyphostatin Analogues

(2011) Jacob Y. Cha et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium(0)-Catalyzed Arylative Dearomatization of Phenols

(2011) Sophie Rousseaux et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Para-Selective Oxidative Cross-Coupling of Arenes and Cycloalkanes‡

(2011) Xiangyu Guo et al.   ORGANIC LETTERS

A Hypervalent Iodine-Induced Double Annulation Enables a Concise Synthesis of the Pentacyclic Core Structure of the Cortistatins

(2009) Jessica L. Frie et al.   ORGANIC LETTERS

Sc(OTf)3-Catalyzed Direct Alkylation of Quinolines and Pyridines with Alkanes

(2009) Guojun Deng et al.   ORGANIC LETTERS

Cross-Dehydrogenative Coupling (CDC): Exploring C−C Bond Formations beyond Functional Group Transformations

(2008) Chao-Jun Li   ACCOUNTS OF CHEMICAL RESEARCH

Ruthenium-Catalyzed Oxidative Cross-Coupling of Chelating Arenes and Cycloalkanes

(2008) Guojun Deng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A New H2O2/Acid Anhydride System for the Iodoarene-Catalyzed C−C Bond-Forming Reactions of Phenols

(2008) Toshifumi Dohi et al.   ORGANIC LETTERS