Review
Chemistry, Multidisciplinary
Mykyta O. Ivanytsya, Vladyslav V. Subotin, Konstantin S. Gavrilenko, Serhiy V. Ryabukhin, Dmytro M. Volochnyuk, Sergey V. Kolotilov
Summary: The actual problems of catalyst development for hydrogenation of heterocyclic compounds are summarized and discussed in this review. The scope includes composites of nanoparticles of platinum group metals and 3d metals for heterogeneous catalytic processes. The review focuses on catalyst activity increase, decrease of precious metals content, selectivity, reproducibility, and quality control of the catalysts.
Article
Chemistry, Physical
Mengying Lu, Xiaoyan Hu, Qingxun Hu, Haichao Yang, Delin Lai, Xinlong Yan, Rui Feng, Guofeng Zhao
Summary: Efficient catalysts for benzyl alcohol oxidation are crucial for economic and environmentally friendly processes. A cobalt-based zeolitic imidazolate framework, ZIF-67, was utilized to synthesize different catalysts, with the Co@CN catalyst showing superior activity and recyclability under mild conditions. The main active sites were identified as metallic cobalt or Co2+, with nitrogen species also contributing to the efficient conversion of benzyl alcohol.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2021)
Article
Chemistry, Physical
Nafiseh Sadat Saffari, Behzad Aghabarari, Masoumeh Javaheri, Ali Khanlarkhani, Maria Victoria Martinez-Huerta
Summary: This study demonstrates the successful use of waste clamshell-derived calcium hydroxide as a low-cost and environmentally friendly catalyst support (CaSUP) for Pd and V nanoparticles in the solvent-free oxidation of benzyl alcohol. The optimized conditions result in high conversion and selectivity to benzaldehyde, showcasing the potential of the clamshell-derived supports for industrial applications.
Article
Chemistry, Multidisciplinary
Claudia E. Berdugo-Diaz, Melissa T. Manetsch, Yang Sik Yun, Jieun Lee, Jing Luo, Xue Chen, David W. Flaherty
Summary: Esters can be reduced to ethers and alcohols through C-O bond cleavage by hydrogenation and hydrogenolysis pathways on Bronsted acidic faujasite (M-FAU) supported metal nanoparticles. The rates and selectivities of each pathway are influenced by the metal identity (M=Co, Ni, Cu, Ru, Rh, Pd, and Pt). Pt-FAU catalyst exhibits propyl acetate consumption rates up to 100 times higher than other M-FAU catalysts and achieves a 34% selectivity for ethyl propyl ether. The reduction of esters appears to involve a bifunctional mechanism, with stepwise addition of H* atoms to the carbonyl to form hemiacetals on the metal sites, followed by hemiacetal diffusion to Bronsted acid sites for dehydration to ethers or decomposition to alcohol and aldehyde. The reduction rates of propyl acetate seem to be determined by H* addition to the carbonyl and C-O cleavage of hemiacetal.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Review
Chemistry, Multidisciplinary
Qiuju Fu, Huimin Jiang, Yujia Wang, Haiyan Wang, Xuebo Zhao
Summary: Metal-organic framework (MOF) based heterogeneous catalysts are widely used in furfural (FFR) hydrogenation reactions. This review summarizes recent advances in upgrading FFR over MOF-based heterogeneous catalysts, ranging from MOFs and MOF derivatives to MOF composites. It also highlights critical issues and perspectives in the hydrogenation of FFR to high-value-added chemicals. This review provides valuable guidance for the preparation and rational design of MOF-based heterogeneous catalysts for upgrading FFR to high value-added chemicals.
MATERIALS CHEMISTRY FRONTIERS
(2023)
Article
Chemistry, Physical
Zhaoyu Zhou, Ya-Nan Xie, Wenze Zhu, Hongying Zhao, Nianjun Yang, Guohua Zhao
Summary: Hydrogen production can be promoted by replacing the sluggish oxygen evolution reaction with a thermodynamically more favorable primary oxidation reaction, resulting in a 5.5 times higher efficiency and 100% selectivity. Utilizing a Bi2MoO6@TiO(2)NTA photocathode, the electrons generated during the oxidation reaction are then used for synergistical hydrogen production, achieving an efficiency as high as 85%.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2021)
Article
Chemistry, Physical
Guangdong Gao, Ran Rong, Zheng Zhang, Bingbing Pan, Xu Sun, Qilong Zhang, Gengxiu Zheng, Kun Xu, Lingfeng Gao
Summary: Co/Fe bimetallic spherical nanomaterials synthesized by hydrothermal method exhibit excellent catalytic performance for the selective oxidation of benzyl alcohol to benzaldehyde, providing an alternative to less environmentally friendly oxidation reagents. The catalyst achieves high conversion and yield under suitable conditions and maintains stable catalytic performance after multiple cycles of use.
CATALYSIS COMMUNICATIONS
(2023)
Article
Chemistry, Physical
Xiaolei Bao, Huiliang Li, Zeyan Wang, Fengxia Tong, Mu Liu, Zhaoke Zheng, Peng Wang, Hefeng Cheng, Yuanyuan Liu, Ying Dai, Yuchen Fan, Zhiyong Li, Baibiao Huang
Summary: In this study, a composite of TiO2 and Ti3C2 was developed to achieve efficient and selective oxidation of benzyl alcohol. The composite stabilizes active intermediates and enhances selectivity, leading to significantly improved conversion efficiency and selectivity compared to pristine TiO2.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2021)
Article
Chemistry, Multidisciplinary
Jiehong He, Shaoshuai Chang, Haoran Du, Bo Jiang, Wenzhao Yu, Zhenwu Wang, Weiwei Chu, Lanfang Han, Jian Zhu, Hexing Li
Summary: This study introduces a reliable amorphous NiRu0.1B catalyst with high catalytic activity for the hydrogenation of CO2 into formic acid. The synergistic effect of amorphous structure and electron donation allows this catalyst to exhibit higher activity and stability at low temperatures compared to other catalysts.
JOURNAL OF CO2 UTILIZATION
(2021)
Article
Chemistry, Physical
Mohamed Sadou, Adel Saadi, Mohammed Hadj Meliani, Rami K. Suleiman, Tawfik A. Saleh
Summary: A facile synthetic method was used to prepare copper-modified SBA-15 catalysts. The catalysts showed high activity, which could be attributed to the well-dispersed copper nanoparticles on the mesoporous support.
SURFACES AND INTERFACES
(2022)
Article
Energy & Fuels
Yasar Zengin, Gulin Selda Pozan Soylu
Summary: In this study, a novel strategy was developed for the selective hydrogenation of benzaldehyde under visible light illumination. The use of immobilized Pd-0 on amine-functionalized clinoptilolite was found to enhance the selectivity toward benzyl alcohol. This work provides a new approach for the development of a bifunctional hydrogenation catalyst and may have a significant impact on the advancement of technology to obtain benzyl alcohol with high efficiencies.
BIOMASS CONVERSION AND BIOREFINERY
(2022)
Article
Polymer Science
Eduard Karakhanov, Anton Maximov, Anna Zolotukhina
Summary: This article reviews the recent advances and applications of dendritic catalysis in the past two decades, with a focus on heterogeneous dendrimer-based catalysts. Three main approaches to synthesizing immobilized heterogeneous dendrimer-based catalysts are considered, and magnetically separable dendritic catalysts are also discussed. These dendritic catalysts can be stored as powders and easily separated from the reaction medium, maintaining efficiency similar to homogeneous dendritic catalysts.
Review
Chemistry, Physical
Luiz H. H. Vieira, Leticia F. Rasteiro, Cassia S. Santana, Gabriel L. L. Catuzo, Alisson H. M. da Silva, Jose M. Assaf, Elisabete M. M. Assaf
Summary: Following advances in capture technologies, utilizing low-cost renewable H-2 in catalytic hydrogenation for CO2 utilization shows great potential in reducing the carbon footprint of industrial processes by providing valuable chemicals and fuels. However, the scalability and economic viability of these processes heavily rely on the development of efficient catalysts. This review summarizes recent progress in noble metal-based heterogeneous catalysts for the thermocatalytic conversion of CO2 into various products, highlighting their impact on catalyst properties and discussing challenges and potential future research opportunities.
Article
Chemistry, Multidisciplinary
Lili Liu, Xiaojing Zhou, Chunling Xin, Baoli Zhang, Guangman Zhang, Shanshan Li, Li Liu, Xishi Tai
Summary: This study prepared bimetallic and monometallic catalysts of Au and Sn nanoparticles loaded on graphene oxide (GO) and reduced graphene oxide (rGO) using three different techniques. The chemical and physical properties of these catalysts were characterized using various techniques. The catalytic performance of the nanocatalysts was evaluated in the selective oxidation of benzyl alcohol to benzaldehyde, and the optimal conditions for the reaction were determined. The bimetallic Au-Sn nanoparticles supported on GO exhibited higher catalytic activity and yield of benzaldehyde compared to the Au-Sn/rGO catalysts.
Article
Chemistry, Physical
Zhiying Zhang, Siqinhaolu Hao, Xueyi Duan, Tinglan Wang, Haiying Li, Guilan Fan, Yanhong Zhao, Jingyi Li
Summary: In this study, a CuBi2O4/WO3 p-n heterojunction composite was synthesized and used for the selective oxidation of benzyl alcohol. The origin of its excellent photocatalytic activity was investigated using multiple characterization methods. The composite catalyst showed high selectivity for benzaldehyde and conversion of benzyl alcohol under optimized conditions. The stability of the catalyst was also examined, and a possible mechanism for the oxidation of benzyl alcohol to benzaldehyde was proposed.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Physical
Itika Kainthla, Venkata Ramesh Babu Gurram, Jayesh T. Bhanushali, Seetha Rama Rao Kamaraju, Rangappa S. Keri, Suresh W. Gosavi, Arvind H. Jadhav, Bhari Mallanna Nagaraja
Article
Chemistry, Physical
Divya Prasad, Komal N. Patil, C. R. Chaitra, N. Sandhya, Jayesh T. Bhanushali, Suresh W. Gosavi, Arvind H. Jadhav, Bhari Mallanna Nagaraja
APPLIED SURFACE SCIENCE
(2019)
Article
Chemistry, Physical
Divya Prasad, Komal N. Patil, N. Sandhya, C. R. Chaitra, Jayesh T. Bhanushali, Akshaya K. Samal, Rangappa S. Keri, Arvind H. Jadhav, Bhari Mallanna Nagaraja
APPLIED SURFACE SCIENCE
(2019)
Article
Chemistry, Physical
Komal N. Patil, Divya Prasad, Jayesh T. Bhanushali, Hern Kim, Amol B. Atar, Bhari Mallanna Nagaraja, Arvind H. Jadhav
Article
Chemistry, Physical
Jayesh T. Bhanushali, Divya Prasad, Komal N. Patil, K. Saidulu Reddy, Kamaraju Seetha Rama Rao, Arvind H. Jadhav, Bhari Mallanna Nagaraja
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2020)
Article
Chemistry, Physical
Jayesh T. Bhanushali, Divya Prasad, Komal N. Patil, K. Saidulu Reddy, Itika Kainthla, Kamaraju Seetha Rama Rao, Arvind H. Jadhav, Bhari Mallanna Nagaraja
CATALYSIS COMMUNICATIONS
(2020)
Article
Chemistry, Multidisciplinary
Komal N. Patil, Divya Prasad, Vilas K. Manoorkar, Jayesh T. Bhanushali, Arvind H. Jadhav, Bhari Mallanna Nagaraja
Summary: This study designs Cu/ZnAl2O4-CeO2 catalyst for the production of GBL from 1,4-butanediol. CeO2 promoter prevents catalyst agglomeration and increases its basic character to selectively obtain GBL. Under optimized process conditions, a high yield of 94% GBL product was achieved.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2022)
Article
Chemistry, Physical
Iranna Udachyan, Jayesh T. Bhanushali, Amir Mizrahi, Tomer Zidki, Dan Meyerstein
Summary: This study investigated Mn2(CO3)3/NF as an electrocatalyst for the oxygen evolution reaction, showing lower overpotential and good long-term stability in both KOH and NaHCO3 media.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
Iranna Udachyan, Jayesh T. Bhanushali, Shanti G. Patra, Tomer Zidki, Amir Mizrahi, Dan Meyerstein
Summary: Nickel carbonate was electrodeposited on Pt and Pd electrode surfaces and characterized using various techniques. The electrodeposited Ni-2(CO3)(3)/Pt and Ni-2(CO3)(3)/Pd showed enhanced activity for methanol oxidation in KOH and Na2CO3 electrolytes. The Ni-2(CO3)(3)/Pt catalyst exhibited the highest forward scan peak current density of 19.8 mA cm(-2).
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Chemistry, Physical
Iranna Udachyan, Jayesh T. Bhanushali, Amir Mizrahi, Tomer Zidki, Dan Meyerstein
Summary: Energy generation from sustainable renewable sources is crucial, and the oxidation of ammonia using Mn-2(CO3)(3)/Pd electrode as an electrocatalyst could be a potential solution. The electrocatalyst exhibits a high oxidation current density at a specific anodic potential in solutions containing Na2CO3 and NH4OH. The durability test shows the stability of Mn-2(CO3)(3) for over 4 hours, and nitrogen is the only observed product of the ammonia oxidation reaction.
SUSTAINABLE ENERGY & FUELS
(2023)
Article
Chemistry, Multidisciplinary
Komal N. Patil, Divya Prasad, Jayesh T. Bhanushali, Bhalchandra Kakade, Arvind H. Jadhav, Bhari Mallanna Nagaraja
Summary: The development of oxygen vacancies in Pd@ZrO2 catalysts through a two-step synthesis method was studied, and it was found that the synergistic effect between oxygen vacancies and nano-sized active Pd metals played a crucial role in enhancing the selectivity for the hydrogenation of cinnamaldehyde to hydrocinnamaldehyde. The optimized reaction parameters, including 4 wt% Pd loading, 100 degrees C temperature, and 10 bar H-2 pressure, were identified to provide efficient conversion of cinnamaldehyde with high yield and excellent recyclability of the catalyst, making oxygen-vacancy-rich Pd@ZrO2 catalysts promising for industrial applications.
NEW JOURNAL OF CHEMISTRY
(2021)
Article
Chemistry, Physical
Divya Prasad, Komal N. Patil, Jayesh T. Bhanushali, Bhari Mallana Nagaraja, Arvind H. Jadhav
CATALYSIS SCIENCE & TECHNOLOGY
(2019)
Article
Chemistry, Multidisciplinary
Jayesh T. Bhanushali, Divya Prasad, Komal N. Patil, Gurram Venkata Ramesh Babu, Itika Kainthla, Kamaraju Seetha Rama Rao, Arvind H. Jadhav, Bhari Mallanna Nagaraja
NEW JOURNAL OF CHEMISTRY
(2019)