Cu-catalyzed hydrofluoroacetylation of alkynes or alkynyl carboxylic acids leading highly stereoselectively to fluoroacetylated alkenes

Diboron as a reductant for nickel-catalyzed reductive coupling: rational design and mechanistic studies

(2015) Guoying Zhang et al.   CHEMICAL COMMUNICATIONS

Highly selective copper-catalyzed trifunctionalization of alkynyl carboxylic acids: an efficient route to bis-deuterated β-borylated α,β-styrene

(2015) Qiang Feng et al.   CHEMICAL COMMUNICATIONS

Recent Progress toward the Introduction of Functionalized Difluoromethylated Building Blocks onto C(sp2) and C(sp) Centers

(2015) Marie-Charlotte Belhomme et al.   CHEMISTRY-A EUROPEAN JOURNAL

Direct Vicinal Difunctionalization of Alkynes: An Efficient Approach Towards the Synthesis of Highly Functionalized Fluorinated Alkenes

(2015) Tatiana Besset et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

β-Ketophosphonate Formation via Aerobic Oxyphosphorylation of Alkynes or Alkynyl Carboxylic Acids with H-Phosphonates

(2015) Mingxin Zhou et al.   ORGANIC LETTERS

A General Synthesis of Fluoroalkylated Alkenes by Palladium-Catalyzed Heck-Type Reaction of Fluoroalkyl Bromides

(2014) Zhang Feng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Difluoroalkylation of Aryl Boronic Acids: A New Method for the Synthesis of Aryldifluoromethylated Phosphonates and Carboxylic Acid Derivatives

(2014) Zhang Feng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed 1,2-Addition of Perfluoroalkyl Iodides to Alkynes and Alkenes

(2014) Tao Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective difluoroalkylation of alkenes by using visible light photoredox catalysis

(2014) Chunghyeon Yu et al.   CHEMICAL COMMUNICATIONS

Access to Difluoromethylated Alkynes through the Castro-Stephens Reaction

(2014) Tatiana Besset et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Highly Selective gem-Difluoroallylation of Organoborons with Bromodifluoromethylated Alkenes Catalyzed by Palladium

(2014) Qiao-Qiao Min et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-Light-Mediated Fluoroalkylation of Isocyanides with Ethyl Bromofluoroacetates: Unified Synthesis of Mono- and Difluoromethylated Phenanthridine Derivatives

(2014) Xiaoyang Sun et al.   ORGANIC LETTERS

Copper-Catalyzed Decarboxylative C–P Cross-Coupling of Alkynyl Acids with H-Phosphine Oxides: A Facile and Selective Synthesis of (E)-1-Alkenylphosphine Oxides

(2014) Gaobo Hu et al.   ORGANIC LETTERS

Copper-Mediated Direct Functionalization of Unsaturated C–C Bonds with Ethyl Bromo(difluoro)acetate: A Straightforward Access to Highly Valuable Difluoromethylated Alkenes

(2014) Tatiana Besset et al.   SYNTHESIS-STUTTGART

Controlled Trifluoromethylation Reactions of Alkynes through Visible-Light Photoredox Catalysis

(2013) Naeem Iqbal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand-free hydroboration of alkynes catalyzed by heterogeneous copper powder with high efficiency

(2013) Jie Zhao et al.   CHEMICAL COMMUNICATIONS

Copper-Catalyzed Oxidative Decarboxylative Couplings of Sulfoximines and Aryl Propiolic Acids

(2013) Daniel L. Priebbenow et al.   ORGANIC LETTERS

Nickel-catalyzed cross-coupling of unactivated alkyl halides using bis(pinacolato)diboron as reductant

(2013) Hailiang Xu et al.   Chemical Science

Copper(I)-Catalyzed Boron Addition Reactions of Alkynes with Diboron Reagents

(2013) Jaesook Yun   Asian Journal of Organic Chemistry

Tamed Arene and Heteroarene Trifluoromethylation

(2012) Tatiana Besset et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Mediated Difluoromethylation of (Hetero)aryl Iodides and β-Styryl Halides with Tributyl(difluoromethyl)stannane

(2012) G. K. Surya Prakash et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct CH Functionalization of Enamides and Enecarbamates by Using Visible-Light Photoredox Catalysis

(2012) Heng Jiang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Mediated Difluoromethylation of Aryl and Vinyl Iodides

(2012) Patrick S. Fier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible Light-Mediated Atom Transfer Radical Addition via Oxidative and Reductive Quenching of Photocatalysts

(2012) Carl-Johan Wallentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aromatic Trifluoromethylation with Metal Complexes

(2011) Olesya A. Tomashenko et al.   CHEMICAL REVIEWS

Copper-Catalyzed C-P Coupling through Decarboxylation

(2011) Jie Hu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Pd-Catalyzed Decarboxylative Coupling of Propiolic Acids: One-Pot Synthesis of 1,4-Disubstituted 1,3-Diynes via Sonogashira−Homocoupling Sequence

(2011) Jihye Park et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalysis for fluorination and trifluoromethylation

(2011) Takeru Furuya et al.   NATURE

Click-alkynylation of N- and P-nucleophiles by oxidative cross-coupling with alkynylcopper reagents: a general synthesis of ynamides and alkynylphosphonates

(2011) Kévin Jouvin et al.   Chemical Science

Copper-catalyzed decarboxylative cross-coupling of alkynyl carboxylic acids with aryl halides

(2010) Dongbing Zhao et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Decarboxylative Coupling of Alkynyl Carboxylic Acids with Benzyl Halides or Aryl Halides

(2010) Wen-Wu Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Mediated Oxidative Trifluoromethylation of Boronic Acids

(2010) Lingling Chu et al.   ORGANIC LETTERS

Synthesis of Vinyl Sulfides by Copper-Catalyzed Decarboxylative C−S Cross-Coupling

(2010) Sadananda Ranjit et al.   ORGANIC LETTERS

Copper-catalyzed addition of diboron reagents to α,β-acetylenic esters: efficient synthesis of β-boryl-α,β-ethylenic esters

(2008) Ji-Eon Lee et al.   CHEMICAL COMMUNICATIONS

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS