4.6 Article

A simple spraying process greatly enhanced field emission of novel T-ZnO-supported CNT emitters

Journal

JOURNAL OF MATERIALS CHEMISTRY C
Volume 4, Issue 8, Pages 1658-1664

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5tc03507d

Keywords

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Funding

  1. Natural Science Foundation Program of China [61574039]
  2. Natural Science Foundation Program of Fujian Province [2015J01252]
  3. Science Development Foundation of Fuzhou University [2012-XQ-40]
  4. Foundation Program of the Ministry of Education for Returned Exchange Personnel [LXKQ201101]

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T-ZnO-supported CNT emitters were fabricated by using a simple process involving two spraying steps followed by heat treatment in air. The T-ZnO-supported CNT emitter was observed to form a particular architecture with the T-ZnO support containing a vertically aligned CNT emitter firmly attached to the electrode. These particular T-ZnO-supported carbon nanotube emitters displayed good contacts with the substrate, vertically aligned CNT emitters and density-controllable T-ZnO supports, which all appear to explain the excellent field emission performance of the electrode. Of the materials tested, the T-ZnO-supported CNT emitters exhibited the best field emission capability, i.e., the lowest turn-on electrical field, with a value of 0.96 V mu m(-1) at a current density of 0.01 mA cm(-2), and the highest field enhancement factor, with a value of 13 883, as well as good emission stability, with only similar to 18% of the current attenuated over an operating span of similar to 200 min. These characteristics indicate that the T-ZnO-supported CNT emitters constitute a very promising cathode material candidate for field emission.

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