Palladium-Catalyzed Direct Arylation of Azulene Based on Regioselective C−H Bond Activation

Rhodium-Catalyzed Synthesis of Chiral Spiro-9-silabifluorenes by Dehydrogenative Silylation: Mechanistic Insights into the Construction of Tetraorganosilicon Stereocenters

(2016) Masahito Murai et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhenium-catalysed dehydrogenative borylation of primary and secondary C(sp3)–H bonds adjacent to a nitrogen atom

(2015) Masahito Murai et al.   CHEMICAL COMMUNICATIONS

Transition-Metal-Catalyzed Direct Addition of Unactivated C–H Bonds to Polar Unsaturated Bonds

(2015) Lei Yang et al.   CHEMICAL REVIEWS

Iridium-Catalyzed Intermolecular Dehydrogenative Silylation of Polycyclic Aromatic Compounds without Directing Groups

(2015) Masahito Murai et al.   CHEMISTRY-A EUROPEAN JOURNAL

Short Synthesis of [5]- and [7]Phenacenes with Silyl Groups at the Axis Positions

(2015) David Roy et al.   Chemistry-An Asian Journal

Acceleration Effects of Phosphine Ligands on the Rhodium-Catalyzed Dehydrogenative Silylation and Germylation of Unactivated C(sp3)–H Bonds

(2015) Masahito Murai et al.   JOURNAL OF ORGANIC CHEMISTRY

Origin of Near-Infrared Absorption for Azulene-Containing Conjugated Polymers upon Protonation or Oxidation

(2015) Tao Tang et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Iridium-Catalyzed Silylation of Aryl C–H Bonds

(2015) Chen Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Dehydrogenative Silylation of Azulenes Based on Regioselective C–H Bond Activation

(2015) Masahito Murai et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed Facile Access to 3,11-Dialkylfulminenes for Transistor Applications

(2015) Masahito Murai et al.   ORGANIC LETTERS

Rhodium-Catalyzed Synthesis of Benzosilolometallocenes via the Dehydrogenative Silylation of C(sp2)–H Bonds

(2015) Masahito Murai et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed Direct C–H Functionalization under External-Oxidant-Free Conditions

(2015) Xiuling Cui et al.   SYNTHESIS-STUTTGART

Palladium-catalyzed three-component coupling reactions of 2-(cyanomethyl)phenol, aryl halides, and carbon monoxide

(2015) Masahito Murai et al.   TETRAHEDRON

C–H arylation of triphenylene, naphthalene and related arenes using Pd/C

(2015) Karl D. Collins et al.   Chemical Science

Modulating the Properties of Azulene-Containing Polymers through Controlled Incorporation of Regioisomers

(2014) Kazuhiko Tsurui et al.   ADVANCED FUNCTIONAL MATERIALS

Synthesis of Biaryls through Aromatic CH Bond Activation: A Review of Recent Developments

(2014) Ibrar Hussain et al.   ADVANCED SYNTHESIS & CATALYSIS

Arene C–H functionalisation using a removable/modifiable or a traceless directing group strategy

(2014) Fengzhi Zhang et al.   CHEMICAL SOCIETY REVIEWS

General Suzuki Coupling of Heteroaryl Bromides by Using Tri-tert-butylphosphine as a Supporting Ligand

(2014) Yinjun Zou et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Mechanism of the Rhodium-Catalyzed Silylation of Arene C–H Bonds

(2014) Chen Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bismuth-Catalyzed Synthesis of Polycyclic Aromatic Hydrocarbons (PAHs) with a Phenanthrene Backbone via Cyclization and Aromatization of 2-(2-Arylphenyl)vinyl Ethers

(2014) Masahito Murai et al.   ORGANIC LETTERS

Rhodium-Catalyzed Dehydrogenative Germylation of C–H Bonds: New Entry to Unsymmetrically Functionalized 9-Germafluorenes

(2014) Masahito Murai et al.   ORGANIC LETTERS

Bismuth(III)-Catalyzed Dehydrative Etherification and Thioetherification of Phenolic Hydroxy Groups

(2014) Masahito Murai et al.   ORGANIC LETTERS

Protonation induced shifting of electron-accepting centers in intramolecular charge transfer chromophores: a theoretical study

(2014) Tao Tang et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Rhodium-Catalyzed Intermolecular C-H Silylation of Arenes with High Steric Regiocontrol

(2014) C. Cheng et al.   SCIENCE

Chelation-Assisted Regioselective Catalytic Functionalization of C–H, C–O, C–N and C–F Bonds

(2014) Fumitoshi Kakiuchi et al.   SYNLETT

Modulating structure and properties in organic chromophores: influence of azulene as a building block

(2014) Masahito Murai et al.   Chemical Science

Conjugated oligomers incorporating azulene building blocks – seven- vs. five-membered ring connectivity

(2014) Elizabeth Amir et al.   Chemical Science

Transition metal-catalyzed direct nucleophilic addition of C–H bonds to carbon–heteroatom double bonds

(2014) Xi-Sha Zhang et al.   Chemical Science

The Cross-Dehydrogenative Coupling of C sp 3H Bonds: A Versatile Strategy for CC Bond Formations

(2013) Simon A. Girard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A straightforward access to guaiazulene derivatives using palladium-catalysed sp2 or sp3 C–H bond functionalisation

(2013) Liqin Zhao et al.   CHEMICAL COMMUNICATIONS

Developments in Direct CH Arylation of (Hetero)Arenes under Microwave Irradiation

(2013) Abhishek Sharma et al.   CHEMISTRY-A EUROPEAN JOURNAL

Platinum-Catalyzed C–H Arylation of Simple Arenes

(2013) Anna M. Wagner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent development of direct asymmetric functionalization of inert C–H bonds

(2013) Chao Zheng et al.   RSC Advances

Beyond Directing Groups: Transition-Metal-Catalyzed CH Activation of Simple Arenes

(2012) Nadine Kuhl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Azulene-containing organic chromophores with tunable near-IR absorption in the range of 0.6 to 1.7 μm

(2012) Fuke Wang et al.   JOURNAL OF MATERIALS CHEMISTRY

Azulene-based conjugated polymers: unique seven-membered ring connectivity leading to stimuli-responsiveness

(2012) Masahito Murai et al.   Chemical Science

Direct Arylation of Polycyclic Aromatic Hydrocarbons through Palladium Catalysis

(2011) Kenji Mochida et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(OAc)2/o-Chloranil/M(OTf)n: A Catalyst for the Direct C–H Arylation of Polycyclic Aromatic Hydrocarbons with Boryl-, Silyl-, and Unfunctionalized Arenes

(2011) Katsuaki Kawasumi et al.   ORGANIC LETTERS

Catalyst Control of Site Selectivity in the PdII/IV-Catalyzed Direct Arylation of Naphthalene

(2011) Amanda J. Hickman et al.   ACS Catalysis

Overview of the Mechanistic Work on the Concerted Metallation–Deprotonation Pathway

(2010) David Lapointe et al.   CHEMISTRY LETTERS

Arylation of unactivated arenes

(2010) Aiwen Lei et al.   DALTON TRANSACTIONS

Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage

(2009) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed arene C–H bond cross-coupling

(2009) Hien-Quang Do et al.   CHEMICAL COMMUNICATIONS

Recent advances in aryl–aryl bond formation by direct arylation

(2009) Gerard P. McGlacken et al.   CHEMICAL SOCIETY REVIEWS

Intermolecular oxidative cross-coupling of arenes

(2009) James A. Ashenhurst   CHEMICAL SOCIETY REVIEWS

Out-of-plane Deformation of the Azulene Ring along Its Short Molecular Axis in Crystal and Theoretical Structures of 1,3-Diheterolyl- and 1,3-Diphenylazulenes

(2009) Shigeyasu Kuroda et al.   HETEROCYCLES

Establishment of Broadly Applicable Reaction Conditions for the Palladium-Catalyzed Direct Arylation of Heteroatom-Containing Aromatic Compounds

(2009) Benoît Liégault et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis, Electronic, and Emission Spectroscopy, and Electrochromic Characterization of Azulene−Fluorene Conjugated Oligomers and Polymers

(2009) Xiaobai Wang et al.   MACROMOLECULES

Theoretical approach to the out-of-plane deformation of 1,3-disubstituted azulenes

(2009) Verónica A. Jiménez   STRUCTURAL CHEMISTRY

Polyborylation of azulenes

(2009) Masayuki Fujinaga et al.   TETRAHEDRON

Palladium-Catalyzed Direct Arylation of (Hetero)Arenes with Aryl Boronic Acids

(2008) Shang-Dong Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct C–H bond arylation of arenes with aryltin reagents catalysed by palladium complexes

(2008) Hiroshi Kawai et al.   CHEMICAL COMMUNICATIONS

Analysis of the Concerted Metalation-Deprotonation Mechanism in Palladium-Catalyzed Direct Arylation Across a Broad Range of Aromatic Substrates

(2008) Serge I. Gorelsky et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY