Article
Chemistry, Physical
Yuting Zhao, Tonghui Hao, Wei Wu, Yuan Meng, Xianwu Cao, Qunchao Zhang, Wei She, Jun You, Dean Shi, Tao Jiang
Summary: This work demonstrates an eco-friendly and robust superhydrophobic coating based on siloxane-modified hyperbranched waterborne polyurethane (Si-HBPU) and fluorinated silica nanoparticles (F-SiO2). The coating shows excellent water repellency and mechanical robustness, and is capable of maintaining superhydrophobicity even after sandpaper abrasion. Additionally, it exhibits outstanding anti-icing/deicing performance and scratch resistance, anti-fouling, and anti-corrosion properties.
APPLIED SURFACE SCIENCE
(2022)
Article
Polymer Science
Na Wang, Xinhui Wang, Jinyan Lang, Zhenhua Hu, Heng Zhang
Summary: A new type of waterborne polyurethane acrylate for UV curing coating was synthesized, characterized, and tested for optimal properties. The influence of various components on film properties was analyzed, and the conversion rate of isocyanate groups was studied under different conditions to determine the best formulation and process parameters.
Article
Polymer Science
Chengbing Gong, Bihua Xiao, Xianhai Hu, Yuxi Xian, Ping Wang, Yuqing Yang, Xiang Luo, Mingjun Li, Jin Liu, Yunsheng Ding, Pei Xu, Chao Liu
Summary: An amino-hydroxy-functionalized strongly fluorescent hybrid silicon quantum dots (znoSiQDs) were prepared using a green and simple method. These znoSiQDs were then used as chain extenders to synthesize waterborne polyurethane-based hybrid fluorescent silicon quantum dots (znoSiQDs-WPU). The znoSiQDs-WPU exhibited enhanced fluorescence intensity, expanded UV shielding range, longer luminescent life, and improved thermal stability compared to znoSiQDs. The use of water as a solvent also makes znoSiQDs-WPU a safer and more environmentally friendly material option.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Article
Chemistry, Physical
N. Chakrabarty, A. Dey, S. Krishnamurthy, Amit K. Chakraborty
Summary: A simple hydrothermal method was used to synthesize CeO2/Ce2O3 quantum dots anchored on reduced graphene oxide (RGO) sheets for supercapacitor electrode applications. The optimized weight fraction of RGO in the CRGO3 electrode showed the highest specific capacitance and good cycling stability at different current densities, indicating potential use in supercapacitors. High resolution transmission electron microscopy (HRTEM) and X-ray photoelectron spectroscopy (XPS) analysis confirmed the presence of well crystalline CeO2 nanoparticles and Ce2O3 mixed oxides on the RGO sheets, contributing to the enhanced electrocatalytic activity and performance of the electrode.
APPLIED SURFACE SCIENCE
(2021)
Article
Polymer Science
Reihaneh Farajollah, Mir Mohammad Alavi Nikje, Ebrahim Saadat, Farid Abedin Dorkoosh
Summary: In this study, a novel three-dimensional waterborne polymer network containing a pentol star core was designed and synthesized. The polymer showed increased hydrophilicity, degradability, and biocompatibility compared to the core material. These results suggest that the prepared polymer has potential for biomedical applications in the future.
EUROPEAN POLYMER JOURNAL
(2021)
Review
Polymer Science
Arantzazu Santamaria-Echart, Isabel Fernandes, Filomena Barreiro, Maria Angeles Corcuera, Arantxa Eceiza
Summary: Polyurethanes and polyurethane-ureas, particularly in their water-based dispersions, have become crucial in environmentally friendly applications. The evolution of synthesis methods and reactants towards sustainability has positioned these dispersions as essential products for diverse applications. The review covers basic concepts of polyurethane chemistry to evolving dispersion preparation strategies, highlighting the use of renewable reactants and green strategies.
Article
Materials Science, Multidisciplinary
Lang Rui, Mao Yang, Deyi Zhu, Wenjia Han, Xugang Dang
Summary: A potential nanocomposite scaffold based on waterborne polyurethane grafted collagen polypeptide/hydroxyapatite (WPU-g-CP/HAp) was successfully synthesized and characterized in terms of its mechanical properties, structural composition, and biodegradation performance, showing promising potential as an ideal bone healing material.
MATERIALS TODAY COMMUNICATIONS
(2021)
Article
Polymer Science
Liang Chen, Zhuding Dai, Wenxue Lou, Pingping Jiang, Pingbo Zhang, Yanmin Bao, Xuewen Gao, Jialiang Xia
Summary: In this study, vegetable oil-based waterborne polyurethane with self-healing properties was synthesized by incorporating Diels-Alder diol. The addition of the Diels-Alder diol improved the properties of the polyurethane film, including increased particle size, enhanced tensile strength, and improved water contact angle. Additionally, the polyurethane film exhibited self-healing behavior at high temperatures, with a maximum self-healing efficiency of 100%.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Article
Polymer Science
Fangfang Wang, Jihao Ci, Jiang Fan
Summary: By treating the fillers and using electrostatic spraying, conductive and superhydrophobic waterborne polyurethane (WPU) composites were prepared in this study. The crosslinking of the fillers with the polymer improved the uniformity of the coating and enhanced its corrosion resistance. The reaction between the coupling agent and the substrate increased the adhesion of the coating to the steel substrate, solving the problems of low adhesion and easy delamination.
Article
Polymer Science
Haidong Liu, Hengsen Xiong, Yongming Chang, Jianhui Xu, Chuanlai Xu, Yaolu Liu
Summary: In this study, eco-friendly superhydrophobic coatings were prepared by dispersing hydrophobic silica nanoparticles and a waterborne silicone-modified polyurethane dispersion into an ethanol solution, which was free of fluorine and volatile toxic solvents. The effects of the silica content on the hydrophobicity and scratch resistance of the coatings were investigated, and it was found that coatings with silica content exceeding 30% exhibited superhydrophobicity and optimal mechanical stability. The morphology and roughness of the coatings were analyzed to explain the influence mechanism of silica content. Anti-icing and oil-water separation experiments demonstrated the excellent performance of the superhydrophobic coatings in these applications.
Article
Materials Science, Composites
Lanqing Fang, Tingtian Qiu, Quan Yang, Lingqiang Kong, Fei Yan, Mengjie Zhang, Yu Liu, Liu Liu, Yuhui Ao
Summary: A novel UV-resistant hyperbranched polyurethane was designed for waterborne sizing agents, resulting in improved interfacial adhesion and mechanical properties of short carbon fiber/polyamide6 composites. The mechanical properties of the composites remained about 99% after a week of UV aging treatment, indicating excellent UV resistance of the sizing agent.
COMPOSITES COMMUNICATIONS
(2021)
Article
Polymer Science
Xinxiang Li, Tengchao Zeng, Yunjie Yin, Chaoxia Wang
Summary: This study successfully synthesized castor oil-based colored PUs with excellent stability and color properties on cotton fabrics, achieving color fastness through hydrogen bonding and polymer network structure formation. The insertion of dye molecules and vegetable oils into the PU macromolecular chain provided a way to impart exceptional color characteristics and fastness to PU coatings.
JOURNAL OF APPLIED POLYMER SCIENCE
(2021)
Article
Polymer Science
Yuan Lei, Bo Wu, Anqian Yuan, Jingxin Lei, Liang Jiang
Summary: A novel class of waterborne polyurethanes (WPUs) were synthesized in this work, demonstrating self-healing and photoluminescent properties after incorporating carbon quantum dots (CQs). The prepared WPUs showed excellent mechanical performance with uniform size distribution and self-healing efficiency. Additionally, the WPUs with CQs emitted bright orange fluorescence under ultraviolet light, showing outstanding photoluminescence properties and environmental friendliness.
JOURNAL OF APPLIED POLYMER SCIENCE
(2021)
Article
Polymer Science
Lingli Ni, Shanshan Li, Yongtao Liu, Xiaowu Jiang, Peng Cai, Liangdong Feng, Shizhong Zhang, Xiaoyan Gao
Summary: The research successfully synthesized a new type of active anti-corrosion coating, using waterborne polyurethane and Ce3+ modified palygorskite. The incorporation of Ce-PAL into WPU with just 2wt% led to a significant improvement in corrosion protection properties.
JOURNAL OF APPLIED POLYMER SCIENCE
(2021)
Article
Materials Science, Composites
Shengtao Dai, Fei Yan, Jiaming Guo, Mingxin Li, Yanan Zhao, Yu Liu, Liu Liu, Yuhui Ao
Summary: A hyperbranched waterborne polyurethane (HWPU) sizing agent, based on bio-based materials, was designed to improve the interfacial performance of carbon fiber reinforced nylon 6 composites. The addition of nano titanium dioxide in the HWPU led to a significant enhancement in UV resistance and mechanical properties of the composites.
COMPOSITES SCIENCE AND TECHNOLOGY
(2023)
Retraction
Nanoscience & Nanotechnology
Bibekananda De, Brigitte Voit, Niranjan Karak
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Materials Science, Paper & Wood
Geeti Kaberi Dutta, Niranjan Karak
Summary: This study presents an environmentally friendly fabrication method of a bio-based waterborne polyester nanocomposite for corrosion protection of metal surfaces. The nanocomposite, reinforced with a cellulose nanofiber-reduced graphene oxide-zinc oxide nanohybrid, showed excellent anticorrosion activity and maintained transparency, mechanical toughness, thermal stability, and chemical resistance. The prepared thermosetting nanocomposites have enormous potential as sustainable anticorrosive coating materials.
Article
Polymer Science
Nobomi Borah, Niranjan Karak
Summary: This scientific paper discusses the synthesis of a bio-based tannic acid epoxy resin TAE100 with excellent mechanical properties and adhesive strength, showing potential applications in eco-coatings and adhesives. The thermosets are also biodegradable, as confirmed by microbial testing, making them suitable for environmentally friendly purposes.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Article
Engineering, Environmental
Sukanya Kundu, Niranjan Karak
Summary: This article reviews the recent progress in the application of polymeric photocatalytic membranes (PPM) for environmental remediation. It focuses on the removal efficiency and mechanisms for degrading various pollutants, and highlights the challenges and performances of fabricating PPMs in the presence of sunlight.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Polymer Science
Annesha Kar, Niranjan Karak
Summary: This article reports the synthesis of a bio-based water-soluble poly(ester amide) through a solvent-free environmentally friendly method, and its further modification using poly(vinyl alcohol). The prepared polymeric resin exhibited excellent mechanical properties, good thermal stability, transparency, and biodegradability, making it a potential environmentally friendly coating material.
JOURNAL OF POLYMER RESEARCH
(2022)
Correction
Chemistry, Multidisciplinary
Suman Thakur, Niranjan Karak
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2022)
Review
Chemistry, Multidisciplinary
Poonam Singh, Anuj Rana, Niranjan Karak, Indresh Kumar, Sravendra Rana, Pankaj Kumar
Summary: Sustainable development is a critical concern in today's fast-paced technological world, and the use of renewable resources is essential in achieving sustainable development goals. Researchers have been focusing on the development of bio-based polymers derived from renewable resources like lignin, chitosan, vegetable oils, cellulose, etc. These polymers, particularly those derived from vegetable oils, offer unique properties that can be used to create value-added systems, such as coatings with improved protective properties against corrosion. This review explores the use of vegetable oil-based self-healing polymers in anti-corrosion coatings.
Article
Materials Science, Composites
Raghav Poudel, Niranjan Karak
Summary: In this study, a green composite of yam and alkali-treated corn stalk fiber was prepared, which exhibited good mechanical and thermal properties and excellent biodegradability under normal environmental conditions. The potential applications of this composite material include packaging, biomedical, automobile, and construction sectors.
COMPOSITES SCIENCE AND TECHNOLOGY
(2023)
Article
Polymer Science
Kalyan Dutta, Niranjan Karak
Summary: BPA-based epoxy thermoset has toxic effects on human health, so there is a need for environmentally friendly bio-based alternatives. In this study, a gallic acid amide was synthesized from renewable gallic acid and diethanol amine, and the epoxy resin was obtained through a condensation reaction. The synthesized epoxy thermosets showed excellent properties.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Materials Science, Multidisciplinary
Samiran Morang, Ashutosh Bandyopadhyay, Jay Hind Rajput, Biman B. Mandal, Atharva Poundarik, Niranjan Karak
Summary: Waterborne polyurethanes with smart attributes like self-healing, shape-memory, reprocessability, and excellent mechanical properties are achieved through the triple synergistic effect of dynamic hard domains, asymmetric IPDI-IPDA architecture, and shape memory effect. This strategy leads to the synthesis of robust self-healable WPUs with high healing efficiency, shape recovery, and outstanding mechanical strength. The SHWPU elastomer exhibits all characteristics of advanced materials with smart attributes and eco-friendly nature.
ACS APPLIED POLYMER MATERIALS
(2023)
Article
Nanoscience & Nanotechnology
Samiran Morang, Ashutosh Bandyopadhyay, Biman B. Mandal, Niranjan Karak
Summary: A transparent, self-healable, and highly tough waterborne polyurethane elastomer with amazing mechanical properties has been developed by molecular engineering. The elastomer shows excellent shape recovery, high fracture energy, and good hemocompatibility. Additionally, it retains its mechanical strength during melt re-processability and can be biodegraded with the help of microbes. This material holds great potential as a smart biomaterial and coating for biomedical devices.
ACS APPLIED BIO MATERIALS
(2023)
Article
Materials Science, Biomaterials
Dimpee Sarmah, Munmi Borah, Manabendra Mandal, Niranjan Karak
Summary: In recent years, polysaccharide-based hydrogels have gained attention due to their biodegradability, biocompatibility, and non-toxicity. This study presents a simple method for synthesizing a mechanically tough, biocompatible, and biodegradable hydrogel using polysaccharides like starch and agar. The hydrogel showed high mechanical strength and cell viability, and also exhibited good encapsulation efficiency for antibacterial drugs. The hydrogel with loaded drug demonstrated the potential to be used as a promising candidate in wound dressing applications.
JOURNAL OF MATERIALS CHEMISTRY B
(2023)
Article
Materials Science, Multidisciplinary
Samiran Morang, Jay Hind Rajput, Anwesha Mukherjee, Atharva Poundarik, Bodhisatwa Das, Niranjan Karak
Summary: This study introduces a new strategy to enhance the self-healing ability and mechanical properties of polyurethane (PU) films. By utilizing the triple synergistic effect of a dynamic hard domain, multiple hierarchical hydrogen bonding, and semi-interpenetrating network formation, a series of self-healable waterborne PU/polyacrylic films were prepared. These films exhibit excellent mechanical robustness and biodegradability. The study also demonstrates the potential of these films in biomedical applications.
MATERIALS ADVANCES
(2023)
Article
Chemistry, Multidisciplinary
Nobomi Borah, Muzamil Ahmad Rather, Bibrita Bhar, Biman B. Mandal, Manabendra Mandal, Niranjan Karak
Summary: This study successfully synthesized a nanohybrid of cellulose nanofibers loaded with iron oxide nanoparticles, which showed improved thermomechanical performance and tunable applicability in a bio-based epoxy matrix. Additionally, the nanocomposite exhibited pH-responsive release behavior when used as a carrier platform for an antibacterial drug.
NEW JOURNAL OF CHEMISTRY
(2023)
Meeting Abstract
Cell Biology
Kanhaiya Singh, Yashika Rustagi, Priyanka Verma, Edward Hernandez, Manishekhar Kumar, Poornachander Guda, Rajneesh Srivastava, Sujit Mohanty, Sumit Verma, Savita Khanna, Sashwati Roy, Chandan K. Sen
WOUND REPAIR AND REGENERATION
(2022)