Article
Engineering, Environmental
Jia Deng, Xin-Ming Hu, Enlai Gao, Feng Wu, Weizhao Yin, Li-Zhi Huang, Dionysios D. Dionysiou
Summary: Electrochemical dechlorination using FeNC catalysts is an effective strategy for removing TCE in groundwater, with FeNC-1000 showing the highest electron transfer efficiency and electrochemical active surface area.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Engineering, Environmental
Jingyao Huang, Zhengyuan Zhou, Shuguang Lyu
Summary: Based on a comparative study, it was found that citric acid (CA), oxalic acid (OA), and glutamic acid (GA) chelating agents could relieve the inhibition of sodium dodecyl sulfate (SDS) on trichloroethylene (TCE) removal in the Fe(II) catalyzed sodium percarbonate (SPC) system. GA, in particular, had the most significant promoting effect on TCE degradation due to the presence of SDS. The combination of GA and SDS could maintain the highest Fe(II) content and accelerate the formation of hydroxyl radical (HO center dot), leading to increased TCE removal.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Engineering, Environmental
Jingyao Huang, Zhengyuan Zhou, Muhammad Danish, Qian Sui, Shuguang Lyu
Summary: This study investigated the effect of synergistic strengthening by citric acid (CA) coupled with micron zero valent iron (mZVI) in Fe(II) catalyzed sodium percarbonate (SPC) system on trichloroethylene (TCE) removal in an aqueous environment with the existence of sodium dodecyl sulfate (SDS). Compared with SPC/Fe(II), SPC/Fe (II)/mZVI, SPC/Fe(II)/CA, and SPC/Fe(II)/CA/mZVI systems, the synergistic strengthening effect by CA and mZVI could maximize TCE removal to 92.0 % and dechlorination of TCE to 88.0 % within 30 min. Furthermore, the synergistic system has the widest pH range of 3-7. The presence of CA and mZVI continuously releases Fe(II) and efficiently promotes the formation of hydroxyl radicals, as well as other reductive radicals such as superoxide radical and carbon dioxide radical. The system shows superiority in the remediation of actual contaminated groundwater.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Environmental Sciences
Yu-Chen Chang, Ku-Fan Chen, Ting-Yu Chen, Hung-Hsiang Chen, Wei-Yu Chen, Ying-Chih Mao
Summary: In this study, a biodegradable binder, hydroxypropyl methyl cellulose (HPMC), was used for the first time to develop persulfate-releasing tablets for remediation of TCE-contaminated groundwater. The persulfate tablets showed controlled release of persulfate, which could effectively degrade highly concentrated TCE. The results also demonstrated the biodegradation efficiency of HPMC by microbes under different conditions.
Article
Engineering, Environmental
Usman Farooq, Fei Wang, Jingyi Shang, Malik Zeeshan Shahid, Waseem Akram, Xinhai Wang
Summary: This study developed an efficient and environmentally friendly method for remediating groundwater contaminants using a natural organic ligand cysteine. By improving the redox cycling of iron species, the method achieved enhanced degradation of trichloroethylene (TCE) under neutral conditions.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Environmental Sciences
Jun Hou, Anqi Wang, Lingzhan Miao, Jun Wu, Baoshan Xing
Summary: This study systematically investigated the effect of NO3- on the degradation of TCE by S-ZVI and its mechanism. The results showed that NO3- did not affect the degradation pathway of TCE, but at high concentrations, it competed for electrons and led to an increase in the production of acetylene. Additionally, the presence of NO3- promoted the formation of Fe3O4, which improved the degradation efficiency of TCE.
SCIENCE OF THE TOTAL ENVIRONMENT
(2022)
Article
Engineering, Geological
Cuicui Liu, Yue Ma, Steven A. Banwart, Xiaohui Chen, Wenchao Du, Ying Yin, Hongyan Guo
Summary: A one-dimensional reactive transport model was developed to study the removal of phenanthrene from groundwater using new PRB materials A and B. The results showed that Material B had a higher removal efficiency than Material A due to its higher adsorption capacity and microbial yield coefficient. The findings are of significance for practical applications in groundwater remediation.
JOURNAL OF GEOTECHNICAL AND GEOENVIRONMENTAL ENGINEERING
(2022)
Article
Engineering, Environmental
Ayad A. H. Faisal, Mohammed B. Abdul-Kareem, Alaa Kareem Mohammed, Ayman A. Ghfar
Summary: The study utilized nanoparticles of humic acid and iron oxide impregnated on inert sand to create sorbent for treating groundwater contaminants. Batch tests showed high removal efficiencies of metal ions under specific conditions. Kinetic studies indicated physicosorption as the main mechanism, with Langmuir model calculating adsorption capacities of 25.273 and 114.142 mg/g for cadmium and copper ions.
JOURNAL OF POLYMERS AND THE ENVIRONMENT
(2021)
Review
Green & Sustainable Science & Technology
Pankaj Kumar Gupta, Hassana Ibrahim Mustapha, Bhaskar Singh, Yogesh Chandra Sharma
Summary: This paper reviews the feasibility of using neat biodiesel as a biostimulator in the treatment of diesel and biodiesel blends contaminated soil and groundwater resources. It suggests that the successive bioaugmentation with neat biodiesel as a biostimulant can achieve more than 98% degradation for petroleum compounds.
SUSTAINABLE ENERGY TECHNOLOGIES AND ASSESSMENTS
(2022)
Article
Environmental Sciences
Zhiliang Li, Yanyan Gong, Dongye Zhao, Zhi Dang, Zhang Lin
Summary: The study found that for immobilization of heavy metals in contaminated soil, CaO and Mg(OH)(2) were more effective than NaOH, with CaO being the most suitable alkaline agent for soil remediation based on considerations of chemical cost, technical effectiveness, and environmental impact.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2021)
Article
Engineering, Environmental
Ayesha Idrees, Ali Shan, Meesam Ali, Zain Abbas, Tanvir Shahzad, Sabir Hussain, Faisal Mahmood, Usman Farooq, Muhammad Danish, Shuguang Lyu
Summary: Polyvinylpyrrolidone coated nano zero valent iron-copper (PVP-nZVI-Cu) bimetallic nanoparticles were successfully synthesized for dechlorination of trichloroethylene (TCE) into non-toxic byproducts in the presence of persulfate oxidant. The system showed significant potential in real groundwater for remediation of TCE contaminated groundwater.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Environmental Sciences
Peng Wang, Zhiqiang Xu, Yulong Liu, Xianxian Sheng, Jiaqi Dong, Zhanpeng Lu, Ali Shan, Shuguang Lyu
Summary: This study demonstrated that peroxymonosulfate (PMS) activated by Fe(II)/citric acid (CA) could effectively degrade trichloroethylene (TCE) in the presence of surfactants, with the sulfate radical (SO4•−) identified as the major reactive species responsible for TCE degradation. The study also investigated the influence of pH and inorganic anions on TCE removal, and confirmed the practical potential of the PMS/Fe(II)/CA process in remediating TCE-contaminated groundwater.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2022)
Article
Environmental Sciences
Chenju Liang, Sheng-Yu Yang
Summary: Soil vapor extraction (SVE) alone has limitations in removing less volatile compounds in diesel fuel mixtures in the unsaturated zone. This study showed that combining SVE with foam flushing using TW80/SPS foam could enhance the dissolution or mobilization of sorbed diesel in soil. The effectiveness of diesel removal by different foams was observed to be TW80 foam > TW80/SPS foam > N2 gas flow alone, indicating that foam flushing may be a more effective alternative approach for reducing diesel contamination in the unsaturated zone.
Article
Engineering, Environmental
Miroslav Brumovsky, Jana Oborna, Vesna Micic, Ondrej Malina, Josef Kaslik, Daniel Tunega, Miroslav Kolos, Thilo Hofmann, Frantisek Karlicky, Jan Filip
Summary: The article discusses the significant enhancement in reactivity and corrosion resistance of zerovalent iron nanoparticles (nZVI) through nitriding. The study demonstrates the outstanding catalytic performance of iron nitrides (FexN) in various applications and their potential as a tool for trichloroethylene (TCE) dechlorination. The research findings provide valuable insights into the application of nitriding nanoparticles in environmental remediation.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2022)
Article
Engineering, Environmental
Jih-Hsing Chang, Cheng-Di Dong, Mohanraj Kumar, Shan-Yi Shen
Summary: A novel integrated remediation system combining cosolvent, electrokinetics, and pumping techniques demonstrated its practical feasibility to clean up chlorinated-contaminated groundwater, effectively removing tetrachloroethylene (PCE).
CHEMICAL ENGINEERING JOURNAL
(2023)
Review
Environmental Sciences
Khanh Chau Dao, Chih-Chi Yang, Ku-Fan Chen, Yung-Pin Tsai
Article
Environmental Sciences
Ku-Fan Chen, Yung-Pin Tsai, Chia-Hsiang Lai, Yao-Kai Xiang, Kuen-Yuan Chuang, Zhen-Hong Zhu
Summary: The study evaluated the health effects of carbonyl compounds and metal-containing incense particles at two temples in Nantou County in 2018. The results showed that reducing incense burning activities led to lower particle masses at one temple, while another temple had higher metal contents in their particles. These findings indicate the importance of incense reduction in creating healthier temple environments.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2021)
Article
Environmental Sciences
Yen-Ping Peng, Ling-Chen Peng, Ku-Fan Chen, Chia-Hung Chen, Ken-Lin Chang, Kang-Shin Chen, Zhi Dang, Gui-Ning Lu, Jian Sun
Article
Environmental Sciences
Yi-Chun Chen, Ku-Fan Chen, Jun-Hong Lin, Shih-Wei Huang, Hung-Hsiang Chen, Kun-Yi Andrew Lin, Chia-Hua Lin
Summary: Biochars (BCs) produced at different pyrolysis temperatures have varying impacts on pulmonary toxicity in human lung cells, with higher temperature BCs potentially causing greater cytotoxicity and genotoxicity.
Article
Environmental Sciences
Yen-Ping Peng, Chih-Chen Liu, Ku-Fan Chen, Chin-Pao Huang, Chia-Hung Chen
Summary: In this study, silver deposited titanate nanotube array composite was successfully synthesized using tea leaves and ground coffee as reducing agents for the first time. The composite exhibited excellent photocatalytic performance and simultaneous anodic oxidation and cathodic hydrogen generation in a photoelectrochemical system. Results showed that caffeine and chlorogenic acid were the main reducing agents, and nano-Ag particles deposited on TNA enhanced oxidation and reduction reactions. The proposed mechanism illustrated the oxidation and reduction reactions in the PEC system.
Article
Environmental Sciences
Yi-Chun Chen, Kun-Yi Andrew Lin, Ku-Fan Chen, Xin-Yu Jiang, Chia-Hua Lin
Summary: HKUST-1 induced concentration-dependent cytotoxic effects in HEK293 cells, causing depolarization of mitochondrial membrane potential, formation of apoptotic bodies and autophagic vesicles, as well as oxidative and inflammatory responses. HKUST-1 may lead to reduced NAD(P)H levels and depletion of zonula occludens proteins, increasing the risk of chronic kidney diseases. However, most adverse effects were significantly induced only at high concentrations, suggesting the toxic risk of actual exposure to HKUST-1 can be negligible.
ENVIRONMENTAL POLLUTION
(2021)
Article
Environmental Sciences
Thanh Tam Nguyen, Hung-Hsiang Chen, Thi Hien To, Yu-Chen Chang, Cheng-Kuo Tsai, Ku-Fan Chen, Yung-Pin Tsai
Summary: Biochar generated by pyrolysis of water bamboo husks and ultrasound-assisted biochar showed differences in adsorption capacity and surface properties, with the latter demonstrating higher reaction rate, greater removal efficiency, and improved physiochemical properties. Adsorption isotherms and kinetics indicated the preference for monolayer adsorption and chemisorption of RB5 on water bamboo husk-based ultrasonic-assisted biochar.
Article
Environmental Sciences
Chih-Chi Yang, Khanh-Chau Dao, Yo-Sheng Lin, Teng-Yun Cheng, Ku-Fan Chen, Yung-Pin Tsai
Summary: This study investigates the effects of initial Cr(VI) concentration, wavelength, hole-scavenger, and oxygen conditions on the photocatalytic reduction of hexavalent chromium over titanium dioxide photocatalyst. The results show strong interactions between these factors, with the hole-scavenger factor being more important for lower Cr(VI) concentrations. Higher UV wavelengths result in less chromium retained on the TiO2 surface. The presence of oxygen has a more significant impact on the reduction of higher Cr(VI) concentrations in the presence of salicylic acid, and simple stirring is more efficient than aeration.
Article
Engineering, Environmental
Wei-Ting Chen, Ku-Fan Chen, Rao Y. Surmpalli, Tian C. Zhang, Jiun-Hau Ou, Chih-Ming Kao
Summary: Emulsified castor oil (ECO) was developed as a substrate for long-term supplement of biodegradable carbon with pH buffering capacity to effectively remediate trichloroethylene (TCE) contaminated groundwater. The ECO emulsion had uniform droplets, negative zeta potential, and biodegradable properties facilitating the removal of TCE without accumulation of dechlorination byproducts. Addition of ECO led to an increase in microbial communities and TCE-degrading bacterial consortia, enhancing anaerobic TCE biodegradation.
WATER ENVIRONMENT RESEARCH
(2022)
Article
Environmental Sciences
Yu-Chen Chang, Ku-Fan Chen, Ting-Yu Chen, Hung-Hsiang Chen, Wei-Yu Chen, Ying-Chih Mao
Summary: In this study, a biodegradable binder, hydroxypropyl methyl cellulose (HPMC), was used for the first time to develop persulfate-releasing tablets for remediation of TCE-contaminated groundwater. The persulfate tablets showed controlled release of persulfate, which could effectively degrade highly concentrated TCE. The results also demonstrated the biodegradation efficiency of HPMC by microbes under different conditions.
Article
Engineering, Environmental
Yi-Chun Chen, Ku-Fan Chen, Kun-Yi Andrew Lin, Jen-Kun Chen, Xin-Yu Jiang, Chia-Hua Lin
Summary: This study demonstrates that exposure to polystyrene microplastics (PSMPs) may have nephrotoxic effects, as they can adhere to and be engulfed by kidney cells. PSMPs induce cytotoxicity through oxidative stress and can simultaneously induce apoptosis and autophagy. In addition, PSMPs can dampen inflammation and impair kidney barrier integrity, increasing the risk of acute kidney injury.
JOURNAL OF HAZARDOUS MATERIALS
(2022)
Article
Biochemistry & Molecular Biology
Khanh-Chau Dao, Chih-Chi Yang, Ku-Fan Chen, Yung-Pin Tsai
Summary: Pharmaceuticals and personal care products have raised concerns due to their extensive use, presence in aquatic environments, and potential impacts on wildlife and humans. The low removal efficiency of carbamazepine by conventional wastewater treatment plants can be improved by using a membrane bioreactor (MBR), which has shown effectiveness in separating pollutants and tolerance to high or shock loadings.
Article
Engineering, Environmental
Yu-Chen Chang, Yen-Ping Peng, Ku-Fan Chen, Ting-Yu Chen, Chen-Ting Tang
Summary: This study investigates the impact of different in situ chemical oxidation technologies on soil microorganisms and total petroleum hydrocarbon degradation. The findings indicate that permanganate is the most suitable oxidant for the process, and chemical oxidation plays a dominant role in TPH removal. Additionally, the addition of oxidants alters the indigenous bacterial communities in the soil.
PROCESS SAFETY AND ENVIRONMENTAL PROTECTION
(2022)
Article
Biochemistry & Molecular Biology
Khanh-Chau Dao, Yung-Pin Tsai, Chih-Chi Yang, Ku-Fan Chen
Summary: This study proposes a method to simultaneously remove CBZ and phosphate from the effluent of a moving-bed membrane bioreactor using an electrochemical process. The experimental results show that this method can achieve high removal efficiency under suitable conditions.
Article
Engineering, Environmental
Hung-Hsiang Chen, Lin-Sin Lu, Jia-Jie Jhang, Chang-Hsueh Lee, Hsiang Chen, Ku-Fan Chen
Summary: This study investigated the integration of carbon nanotube, graphene, and biochar with zinc oxide nanorods for efficient water pollutant removal. The results showed that the hybrid of zinc oxide nanorods and biochar exhibited good performance in adsorbing methylene blue. The findings of this study are significant for addressing water pollution.
WATER ENVIRONMENT RESEARCH
(2023)