4.6 Article

Palladium-catalyzed N-arylsulfonamide formation from arylsulfonyl hydrazides and nitroarenes

Journal

RSC ADVANCES
Volume 6, Issue 16, Pages 13010-13013

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra26588f

Keywords

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Funding

  1. National Natural Science Foundation of China [21172185, 21372187, 21572194]
  2. Hunan Provincial Innovative Foundation for Postgraduate [CX2014B258]
  3. Research Fund for the Doctoral Program of Higher Education of China, Ministry of Education of China [20124301110005]

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A palladium-catalyzed construction for N-arylsulfonamide from nitroarenes and arylsulfonyl hydrazides is developed. In this protocol, abundant and stable nitroarenes serve as the nitrogen sources by in situ reduction reaction of hydrogen released from arylsulfonyl hydrazides. No external oxidants or reductants are needed for this kind of transformation.

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