Journal
RSC ADVANCES
Volume 6, Issue 41, Pages 34428-34433Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra05646f
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Funding
- Department of Science and Technology (DST), New Delhi [SB/S1/OC-17/2013]
- Council of Scientific and Industrial Research (CSIR), New Delhi [CSC0108, CSC0130]
- CSIR-New Delhi
- UGC-New Delhi
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An easy and straightforward preparation of pyrrole-embedded aza-heterocyclic scaffolds employing a Ru/B-H binary catalyst system has been developed. The strategy generates a diverse array of privileged scaffolds from 2-aminophenyl group appended pyrroles that can be prepared by a two-step process from corresponding aminoaryl-substituted pyrroles. The technique of incorporating 2-aminoaromatic groups in the heterocycles and their subsequent ring-closing-metathesis (RCM) isomerization followed by subsequent Pictet-Spengler type reaction should also be applicable to other heterocycles for generating a library of multi-ring compounds in an efficient manner.
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