Journal
CATALYSIS SCIENCE & TECHNOLOGY
Volume 6, Issue 1, Pages 201-207Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cy01259g
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Funding
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- University of Ottawa
- Canadian Foundation for Innovation
- Canada Research Chairs program
- NSERC
- government of Ontario
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The light mediated reduction of unactivated carbon-halogen bonds using polynuclear gold(I) complexes provides a mild and temporally controlled route to the generation of C-H, and C-C bonds. Through complete photophysical and electrochemical charaterization of a series of gold(I) complexes we have been able to achieve a more intimate understanding of the complexities surrounding the excited state processes and mechanism which underly these transformations, allowing for, and facilitating further and future optimizations and applications.
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