Article
Chemistry, Applied
Wenjian Li, Yu Yin, Kuofeng Xu, Fengjiao Li, Kristina Maliutina, Qixing Wu, Cuihua Li, Bin Zhu, Liangdong Fan
Summary: In this study, cobalt compounds were used to modify (La, Sr)MnO3, improving the performance of the oxygen evolution reaction. By adjusting the loading amounts and phase-microstructure of the cobalt phase, better oxygen electrocatalytic activity was achieved. The research demonstrates that surface modification is an effective method to modify the intrinsic activity of OER inert perovskite materials for multifunctional applications.
Article
Materials Science, Ceramics
Emerson Luiz dos Santos Veiga, Xavier Vendrell Villafruela, Jordi Llorca, Hector Beltran-Mir, Eloisa Cordoncillo
Summary: Pyrochlore structures are promising candidates for heterogeneous catalysts in the oxidation reaction of CO to CO2. Higher iron concentrations result in better catalytic activity, and these samples are able to convert all CO oxidation reactions in a narrower temperature range.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2023)
Article
Chemistry, Physical
Isaac T. T. Daniel, Liang Zhao, Donald Bethell, Mark Douthwaite, Samuel Pattisson, Richard J. J. Lewis, Ouardia Akdim, David J. J. Morgan, Steven McIntosh, Graham J. J. Hutchings
Summary: Recent studies have shown that the rate of catalytic alcohol and formyl dehydrogenation in bimetallic Au-Pd systems is closely related to the rate of oxygen reduction. In this study, the rate enhancement resulting from the coupling of these two processes is evaluated for the oxidative dehydrogenation of 5-hydroxymethylfurfural. By changing the molar ratio of Au and Pd in a physical mixture of carbon-supported catalysts, the influence of the ratio on the activity is explored. It is found that the activity of the bimetallic system exceeds the combined activity of the monometallic analogues. The kinetic analysis of the system predicts the locations of the maxima in activity for both monometallic and bimetallic systems. The accuracy of the model provides further evidence and understanding of cooperative redox enhancement effects observed in bimetallic, heterogeneous catalytic systems.
CATALYSIS SCIENCE & TECHNOLOGY
(2023)
Article
Food Science & Technology
Fatemeh Ghiasi, Seyed Mohammad Bagher Hashemi, Elahe Abedi
Summary: This review provides an updated overview of the research progress in the last decade on the use of Lactobacillus strains in food fermentation to enhance oxidative stability. It emphasizes the importance of incorporating these strains in various food products and discusses the mechanisms and methods for evaluating their antioxidant activity. Lactobacillus strains such as L. acidophilus, L. helveticus, L. rhamnosus, L. fermentum, L. plantarum, and L. reuteri have shown to improve the antioxidant activity of fermented foods through various mechanisms.
Article
Nanoscience & Nanotechnology
A. Martinez-Lazaro, M. H. Rodriguez-Barajas, N. Rey-Raap, F. I. Espinosa, L. Alvarez-Contreras, J. Ledesma-Garcia, A. Arenillas, L. G. Arriaga
Summary: In this research, unsupported Pd-TM aerogel catalysts were synthesized using a combination of microwave heating and lyophilization. The aim was to investigate the effect of transition metals on a Pd aerogel matrix to improve its electrocatalytic properties. The physicochemical characterization of Pd-TM aerogels showed a successful combination of high specific surface area, electrochemical surface area, and specific oxidation states. Among all the Pd-TM aerogels, PdNi aerogel exhibited the highest current per unit mass, indicating a significant improvement compared to bare Pd aerogel.
MATERIALS TODAY NANO
(2023)
Article
Chemistry, Physical
Alexandros Safakas, Vasileios Ch. Kournoutis, Georgios Bampos, Symeon Bebelis
Summary: Perovskites are a promising alternative catalyst for oxidation reactions due to their lower cost and greater thermal stability. Increasing the Co/Fe ratio can enhance the catalytic activity for CO and propane oxidation, under both oxidative and stoichiometric conditions. The increase in Co content facilitates the formation of oxygen vacancies, improving the catalytic performance.
Article
Chemistry, Physical
Maila Danielis, Luis E. Betancourt, Ivan Orozco, Nuria J. Divins, Jordi Llorca, Jose A. Rodriguez, Sanjaya D. Senanayake, Sara Colussi, Alessandro Trovarelli
Summary: The milling of Palladium acetate and CeO2 under dry conditions results in robust and environmentally friendly catalysts with excellent methane oxidation activity. The characterization techniques used in this study identified the presence of Pd-0/Pd2+ species with different degrees of interaction with ceria (Ce3+/Ce4+), which are believed to be responsible for the enhanced catalytic activity. This study provides insight into the mechanistic understanding of the catalytic performance of Pd/CeO2 catalysts prepared by dry milling.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2021)
Article
Engineering, Chemical
Yanbo Deng, Lian Fu, Wenjia Song, Like Ouyang, Shaojun Yuan
Summary: Cerium oxide-based materials doped with valence metals can effectively increase the oxygen vacancy content and regulate the surface and interface structure of CeO2 supported metal catalysts. In this study, CeO2 nanorods doped with transition metals (Fe, Co, Mn) and Pr were prepared and used to support Pd, significantly enhancing the activity of CO catalytic oxidation. The co-doping of Pr and Fe increases the oxygen vacancy content on the catalyst surface, promotes the activation of lattice oxygen, and strengthens the interaction and electron transport ability between Pd and the support, leading to excellent catalytic performance in CO oxidation.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Article
Chemistry, Applied
Lijun Fan, Jun Wang, Zhiyong Huang, Xueli Yao, Nianjun Hou, Tian Gan, Juanjuan Gan, Yicheng Zhao, Yongdan Li
Summary: In this study, the surface properties of La0.6Sr0.4Co0.2Fe0.8O3-delta (LSCF) perovskite electrode were modified with HNO3 treatment to improve its catalytic activity towards oxygen reduction reaction. The acid etching reduced the surface concentrations of A-site cations and suppressed the segregation of Sr on the surface. The HNO3 treatment also led to the formation of highly reactive oxygen species and Fe4+ species on the surface, accelerating the reduction of oxygen species adsorbed on the LSCF surface.
Article
Materials Science, Multidisciplinary
R. Oishi, K. Umeo, Y. Shimura, T. Onimaru, A. M. Strydom, T. Takabatake
Summary: In the CePt6Al3 compound, the development of magnetic order is observed with partial Pd substitution, and as the amount of Pd substitution increases, the antiferromagnetic ordered state becomes stronger.
Article
Chemistry, Physical
Mengyin Liao, Weiping Li, Jiaxi Peng, Fan Zhang, Wenyuan Xu, Zhichao Huang
Summary: The catalytic properties of Pd-Fe bimetallic catalysts can be continuously adjusted by treatment at different temperatures, affecting their activity in formic acid oxidation. The Pd-Fe/C catalyst treated at 500 degrees Celsius shows the highest electrocatalytic activity for formic acid oxidation, outperforming the commercial Pt/C catalyst.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Physical
Xin Min, Mingming Guo, Kan Li, Jia-nan Gu, Xin Guo, Yixin Xue, Jianxing Liang, Songjie Hu, Jinping Jia, Tonghua Sun
Summary: The study successfully synthesized a series of alpha@delta-MnO2 catalysts with different alpha/delta phase ratios using a hydrothermal method, accurately controlling the molar ratio of KMnO4 to MnSO4•H2O. It was found that the catalysts exhibited significantly better catalytic performance compared to single-phase MnO2.
APPLIED SURFACE SCIENCE
(2021)
Article
Engineering, Chemical
Hatem M. Altass, Moataz Morad, Abd El-Rahman S. Khder, Mohammed A. Mannaa, Rabab S. Jassas, Abdulrahman A. Alsimaree, Saleh A. Ahmed, Reda S. Salama
Summary: Pd nanoparticles were successfully dispersed on rGO@Cu-BTC nanocomposite surface, showing excellent catalytic activity for CO oxidation. The presence of rGO played a vital role in the dispersion of Pd NPs on the catalyst surface, leading to higher catalytic activity compared to catalyst without rGO.
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
(2021)
Article
Engineering, Environmental
Yin Li, Jiahui Hu, Yubin Zou, Lin Lin, Hebin Liang, Huaxin Lei, Bing Li, Xiao-yan Li
Summary: In this study, a highly efficient Fe-single atom catalyst (FeSA-NPS@C) was synthesized, which can selectively and stably degrade organic pollutants over a wide pH range with low dosages of the catalyst and peroxymonosulfate (PMS). The heteroatom doping in the catalyst effectively altered its electronic structure, enhanced its coordination with PMS, and promoted the interaction between FeVN4 = O and the target pollutant OFX, resulting in significantly enhanced catalytic activity.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Engineering, Chemical
E. A. Lashina, E. M. Slavinskaya, A. I. Boronin
Summary: The study focused on the kinetics of CO interaction with Pd/CeO2 catalysts under temperature programmed reactions (TPR-CO). As the calcination temperature increases, the palladium states in the catalyst structure transition from solid solution to surface clusters and nanoparticles. Surface clusters are found to be the most active species at temperatures below 100 degrees C, while the bulk-surface transfer of lattice oxygen to the surface clusters contributes to CO2 evolution in the temperature range 100-250 degrees C. Additionally, the reduction of nanoparticles is attributed to a separate sharp peak at 200 degrees C. In the high-temperature range of TPR-CO, active oxygen on the surface of ceria is supplied from the ceria bulk, and increasing the calcination temperature results in a higher concentration of active oxygen in the ceria lattice.
CHEMICAL ENGINEERING SCIENCE
(2021)
Article
Materials Science, Multidisciplinary
Pinkie Ntola, Holger B. Friedrich, Abdul S. Mahomed, Ezra J. Olivier, Alisa Govender, Sooboo Singh
Summary: This study presents the structural characterization of VOx/MgO powders prepared by a stoichiometric solution combustion synthesis using five different fuels. The synthesized powders were characterized using X-ray diffraction, Raman spectroscopy, Inductively Coupled Plasma Emission Spectroscopy, Scanning Electron Microscopy, and Aberration Corrected Transmission Electron Microscopy. The results showed that the selection of fuel influenced the microstructure, vanadate phase formation, and dispersion of each powder. By correlating experimental microstructural parameters with calculated thermodynamic parameters, the study demonstrates the crucial role of fuel in controlling reaction kinetics.
MATERIALS CHEMISTRY AND PHYSICS
(2022)
Article
Chemistry, Physical
Bidyadhar Das, Madhusmita Sahoo, Abhilash Patra, Ashok K. Yadav, S. N. Jha, Prasanjit Samal, Kartik Senapati, Pratap K. Sahoo
Summary: This study explores the feasibility of using X-ray Absorption Spectroscopy (XAS) to track changes in the local bonding environment in NiBi3 and NiBi systems. The decomposition of NiBi3 into NiO and Bi during thermal annealing was successfully tracked through changes in structural and magnetization behavior, which correlated well with the findings from XAS. The study also revealed that NiO becomes the dominant phase at 500 degrees C annealing temperature, as confirmed by magnetic hysteresis measurements and XAS.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)
Article
Crystallography
Halliru Ibrahim, Sizwe J. Zamisa, Muhammad D. Bala, Holger B. Friedrich
Summary: This passage describes the crystal structure parameters and related numerical values of a molecule, including its lattice parameters, cell volume, space group, etc.
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES
(2022)
Article
Chemistry, Multidisciplinary
Revana Chanerika, Mzamo L. Shozi, Holger B. Friedrich
Summary: In this study, catalysts with different silver loadings supported on alumina were prepared and characterized. It was found that the catalysts with different silver loadings had different sizes of metal nanoparticles. In the competitive hydrogenation reaction, nanoparticles with sizes of 10-15 nm showed high conversion and stable operation. The performance of the catalysts was influenced by both the metal and support, with the support playing an important role in the overall acidity of the catalysts.
Article
Chemistry, Multidisciplinary
Umesh P. Gawai, Shilpa D. Kamble, Sanjay K. Gurav, Manvendra N. Singh, Ashok K. Yadav, Shambhu N. Jha, Niranjan P. Lalla, Milind R. Bodke, Mahendra D. Shirsat, Babasaheb N. Dole
Summary: In this study, nanosheets of NiO and β-Ni(OH)(2)/Co3O4, as well as nanorods of Co3O4, were successfully synthesized on a large scale using microwave-assisted chemical coprecipitation method under low temperature and atmospheric pressure. The electronic and atomic structural properties of the samples were characterized using X-ray absorption spectroscopy (XAS), synchrotron X-ray diffraction (SXRD), Raman spectroscopy, FTIR, transmission electron microscopy (TEM), and UV-visible spectroscopy.
Article
Crystallography
David O. Ywaya, Holger B. Friedrich, Muhammad D. Bala, Lynette Soobramoney, Halliru Ibrahim
Summary: This article describes the crystal structure of compound C19H27N5. The compound crystallizes in the orthorhombic Pbca (no. 61) space group with lattice parameters of a = 9.8515(12) angstrom, b = 16.508(2) angstrom, c = 29.817(3) angstrom. Important physical parameters such as V = 4849.3(10) angstrom^3, Z = 8, R-gt(F) = 0.0409, and wR(ref)(F-2) = 0.1082 are also provided.
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES
(2022)
Article
Chemistry, Physical
Revana Chanerika, Mzamo L. Shozi, Mirko Prato, Holger B. Friedrich
Summary: This study investigated the selective hydrogenation of a mixed 1-octyne/1-octene feed using solid catalysts with an ionic liquid layer (SCILLs). Results showed that coating the catalysts with an ionic liquid layer increased the yield of 1-octene and maintained stability during the experiments.
Article
Chemistry, Multidisciplinary
Bidyadhar Das, Tapas Ranjan Senapati, Ashok Kumar Yadav, G. R. Umapathy, Sambhu Nath Jha, Kartik Senapati, Pratap Kumar Sahoo
Summary: This article explores the dynamics involved in the formation of NiBi3 thin films using the codeposition method. By studying films grown at different evaporation rates of Bi, it is found that almost stoichiometric NiBi3 is formed only at the top surface, while a nonlinear stoichiometric variation occurs toward the substrate. The bonding environment around Ni, studied by X-ray absorption spectroscopy, agrees with the findings of RBS. The observed superconducting transition and magnetic coercivity are consistent with the ratio of Ni and Bi.
CRYSTAL GROWTH & DESIGN
(2023)
Article
Chemistry, Physical
Victor O. Anyanwu, Holger B. Friedrich, Abdul S. Mahomed, Sooboo Singh, Thomas Moyo
Summary: Cubic and rhombohedral phases of lanthanum manganite were synthesized using a high-pressure reactor. The synthesized LaMnO3, validated through X-ray diffraction, exhibited significant structural transformation from the cubic to the rhombohedral phase, resulting in changes in unit cell volumes. Transmission electron microscopy analysis confirmed small particle sizes, no agglomeration, and good crystallinity. The material's particle characteristics, high purity, and high surface area make it suitable for important technological applications, including the synthesis of perovskite oxides.
Article
Multidisciplinary Sciences
Majid D. Farahani, Cheslin Moodley, Abdul S. Mahomed, Holger B. Friedrich
Summary: In this study, a Pt-V/CeO2 catalyst was developed for amide hydrogenation under mild conditions. It was found that oxygen vacancies on the ceria surface play a crucial role in the catalytic activity, with the absence of oxygen vacancies enhancing the hydrogenation ability of Pt sites and promoting the in situ formation of oxophilic V3+.
Article
Physics, Applied
P. Manna, S. Kanthal, Md. A. Ahmed, A. Banerjee, S. Adhikary, S. Kanungo, A. K. Yadav, S. N. Jha, D. Bhattacharyya, S. Bandyopadhyay
Summary: The effects of Co doping on the structural and magnetic properties of a rare earth based synthetic analog of mineral francisite have been investigated. Density functional theory calculations show that the studied compounds have strong antiferromagnetic nature. Co-doping at the Cu2+ site confirms incorporation of Co2+ with similar local environment. The observed meta-magnetic and spin reorientation transitions are explained by considering magnetic exchange interactions and competition among different intra-layer exchange interactions.
JOURNAL OF APPLIED PHYSICS
(2023)
Article
Materials Science, Coatings & Films
Petros Abi Younes, Ashok-Kumar Yadav, Medet Zhukush, Van-Hoan Le, Herve Roussel, Marie-Ingrid Richard, Clement Camp, Kai Szeto, Gianluca Ciatto, Nathanaelle Schneider, Elsje Alessandra Quadrelli, Hubert Renevier, Nicolas Gauthier
Summary: Amorphous organic-inorganic hybrid thin films (Ti-thiolate) on thermal SiO2 substrate are converted into textured titanium disulfide (TiS2) ultrathin films through annealing under Ar/H-2 atmosphere. Two annealing strategies were investigated to control the mineralization process. The stoichiometry and crystallinity of the films were characterized by various techniques.
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A
(2023)
Article
Chemistry, Physical
Revana Chanerika, Mzamo L. Shozi, Mirko Prato, Holger B. Friedrich
Summary: The effect of tetrabutylammonium nitrate as a surface coating over 1Pd9Ag/Al2O3 in the selective hydrogenation of 1,7-octadiene was studied. The results showed that the coating significantly decreased the conversion and selectivity of 1-octene. However, no net gain in 1-octene was observed. The thickness of the coating also affected the conversion and selectivity, with a thicker coating leading to further decline. Characterization of the catalysts confirmed leaching of the ionic liquid and re-establishment of the metal-support interaction.
Article
Chemistry, Physical
Lindokuhle B. Ngema, Majid D. Farahani, Shaine Raseale, Nico Fischer, Abdul S. Mohamed, Sooboo Singh, Holger B. Friedrich
Summary: Employing a reduction-oxidation pretreatment successfully modified the Co3O4 | ZrO2 catalyst surface, leading to improved CO oxidation activity. The restructuring of Co3O4 to CoO species on the ZrO2 surface formed a highly active Co3O4-CoO | ZrO2 interface, resulting in enhanced CO2 desorption sites and CO oxidation activity. The findings highlight the importance of surface modification for improving CO preferential oxidation activity.
SURFACES AND INTERFACES
(2023)
Article
Chemistry, Multidisciplinary
Mzamo L. Shozi, Xolelwa Zulu, Holger B. Friedrich
Summary: A series of phosphorus and nitrogen-based ethylene oligomerization ligands were reported, characterized, and tested for activity and selectivity towards 1-octene. The supported catalysts showed comparable activity to their homogeneous counterparts, with high selectivities to 1-octene in the C8 products.
SOUTH AFRICAN JOURNAL OF CHEMISTRY-SUID-AFRIKAANSE TYDSKRIF VIR CHEMIE
(2022)
Article
Chemistry, Physical
Zi-Ye Liu, Qian-Yu Wang, Ji-Ming Hu
Summary: In this study, a layered carbon dot composite catalyst (NiFe LDH@CDs) was prepared using a one-step coprecipitation method, without the need for heating or hydrothermal treatment. The CD-functionalized catalyst facilitated rapid charge transfer and accelerated the oxygen evolution reaction. Additionally, the heterojunction structure formed between NiFe LDH and CDs efficiently suppressed photoelectron-hole recombination.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Article
Chemistry, Physical
Rohit Kumar, Ankit Kumar Srivastava, Palaniyappan Nagarasu, Vedichi Madhu, Ekambaram Balaraman
Summary: We designed and synthesized a NN-CoII bidentate complex and used it for the amination of alcohols under mild and solventless conditions. The complex exhibited good reactivity towards both primary and sterically hindered secondary alcohols, providing high yields of amines. The pyrazole moiety in the ligand played a crucial role in the reaction. Furthermore, we demonstrated the reusability of the complex as a homogeneous cobalt catalyst.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Article
Chemistry, Physical
Shivanand Chettri, Liang-Ting Wu, Sagarmani Rasaily, Debesh Sharma, Bikram Gurung, Rajani Dewan, Sudarsan Tamang, Jyh-Chiang Jiang, Anand Pariyar
Summary: Replicating the enzymatic surface microenvironment in vitro is challenging, but constructing an analogous model could facilitate our understanding of surface effects and aid in developing an efficient bioinspired catalytic system. In this study, five unique Cu2O morphologies were generated, and the surface morphology variations were found to be a consequence of differences in the exposure of low-index facets. The reactivity of Cu2O was found to be influenced by the proportion of {110} planes, with r-Cu2O exhibiting the highest reactivity.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Article
Chemistry, Physical
Yong Tang, Jianhao Qiu, Dingliang Dai, Guanglu Xia, Lu Zhang, Jianfeng Yao
Summary: Defect engineering has been shown to improve the photocatalytic performance. This study investigated the use of defect-rich UiO-66-NH2 wrapped by ZnIn2S4 as a catalyst for photocatalytic H2O2 production. The defects in UiO-66-NH2 enhanced O-2 adsorption and charge separation, leading to higher H2O2 yield. The insights from this work can advance the research in defect engineering of MOFs and photocatalytic H2O2 synthesis.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Article
Chemistry, Physical
Ruiyang Qu, Shuxin Mao, Jana Weiss, Vita A. Kondratenko, Evgenii V. Kondratenko, Stephan Bartling, Haifeng Qi, Annette-Enrica Surkus, Kathrin Junge, Matthias Beller
Summary: The hydrogenation of amides, a challenging reaction usually performed at high temperatures, has been achieved under milder conditions using a new Pt-MoOx/TiO2 catalyst. This catalyst system enables the selective hydrogenation of various amides and imides.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Article
Chemistry, Physical
Xiaoran Niu, Ao Wang, Lei Tong, Lei Wang, Yuan Kong, Chenliang Su, Hai-Wei Liang
Summary: This study introduces a novel intermetallic PdCu3 catalyst supported on defective nanodiamond-graphene (ND@G), which exhibits high selectivity (95%) and remarkable activity (turnover frequency: 2940 h(-1)), six times higher than that of the commercial Lindlar catalyst.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Review
Chemistry, Physical
Zhiyuan Zheng, Yiming Yue, Hongying Zhuo, Qinggang Liu, Yanqiang Huang
Summary: This review presents the recent research advances on single-atom catalysis for deep reduction of CO2. Detailed introductions and summaries were classified into three categories based on proton-coupled multi-electron transfer approaches: strengthening metal-support interaction, rational design and regulation of coordination environment, and development of SACs with multi-atom active sites. The challenges and future research directions in the field of SACs for CO2 reduction are also proposed.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Article
Chemistry, Physical
Shiv Kumar, Paramita Datta, Anup Bhunia, Swadhin K. Mandal
Summary: This article reports a transition-metal-free process for in situ denitrogenation of tosylhydrazones, resulting in the production of various sulfones. The authors used a phenalenyl-based odd alternant hydrocarbon as a photoredox catalyst, which acted as a potent oxidant to facilitate the denitrogenation reaction. The method showed wide functional-group tolerance and high yields, making it suitable for late-stage modification of natural products.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Article
Chemistry, Physical
L. A. Luque-Alvarez, J. Gonzalez-Arias, F. Romero-Sarria, T. R. Reina, L. F. Bobadilla, J. A. Odriozola
Summary: Currently, the production of acetic acid through the carbonylation reaction of methanol has limitations, leading to the exploration of alternative methods using heterogeneous catalysts. This study investigates the methanol carbonylation reaction over a Cu-H-MOR catalyst and proposes a reaction mechanism based on the catalytic behavior and performance of the catalyst. The results provide insights into the reaction mechanism and the involvement of acid and redox centers.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
