Article
Chemistry, Multidisciplinary
Fan Yang, Xianzhi Jia, Rui Xu, Lu Liu, Chengyi Dai, Binran Zhao
Summary: This study investigated the kinetics of methanol transformation to aromatics using a 3Zn-3Si/ZSM-5 catalyst for the selective production of p-xylene. The products were divided into four categories in the kinetic model, including methanol and dimethyl ether, alkanes and alkenes, aromatics (except p-xylene), and p-xylene. The kinetic study was conducted at temperatures ranging from 623.15 to 748.15 K. The kinetic model and its parameters were calculated using the Runge-Kutta method and the genetic algorithm. The obtained reaction rate constants and kinetic reaction equations provide valuable theoretical support for subsequent reactor simulation and design.
NEW JOURNAL OF CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Mengya Xia, Qiaoxian Tong, Huai Sun, Yingxin Sun, Sheng Han, Qianggen Li
Summary: The reaction mechanisms of methanol to propene on a phosphorus-modified acidic FAU zeolite were studied using a two-layer ONIOM method. The potential energy surface analysis showed that the rate-determining steps differ for each pathway. The addition of phosphorus atoms to the zeolite decreases the energy barriers of the rate-determining steps. The electron migration direction and nature of the transition states were revealed by DCD, LOL, and RDG plots. The presence of van der Waals and weak covalent interactions were found in the transition state structures.
NEW JOURNAL OF CHEMISTRY
(2023)
Article
Chemistry, Applied
Yanfeng Xue, Shiying Li, Junfen Li, Xiaojing Cui, Pengfei Wang, Hongyan Zheng, Yulan Niu, Qingguo Ma, Lifeng Ding
Summary: ZSM-5/ZSM-48 composite zeolite synthesized using mixed templates of CTAB and HDA shows enhanced catalytic performance with higher propene selectivity and more acid sites.
MICROPOROUS AND MESOPOROUS MATERIALS
(2021)
Review
Chemistry, Multidisciplinary
Xinqiang Wu, Yingxu Wei, Zhongmin Liu
Summary: The methanol-to-hydrocarbons (MTH) process provides a new route for obtaining basic chemicals without relying on oil resources. The reaction reflects the dynamic assembly process of C-C bonds in zeolite catalysts' confined microenvironment. Advanced in situ spectroscopy and computational chemistry methods have helped capture and understand the details of reactants, intermediates, and products, and model the reaction steps at the molecular and atomic levels. The concept of dynamic catalysis provides insights into complex catalytic mechanisms and structure-activity relationships in MTH chemistry.
ACCOUNTS OF CHEMICAL RESEARCH
(2023)
Article
Chemistry, Physical
Yanfeng Xue, Junfen Li, Pengfei Wang, Xiaojing Cui, Hongyan Zheng, Yulan Niu, Mei Dong, Zhangfeng Qin, Jianguo Wang, Weibin Fan
Summary: Regulating the Al distribution in zeolite through Sn leads to a more homogeneous spatial distribution, resulting in decreased formation of aromatics and coke species, and increased propene selectivity and catalytic stability in the MTO process.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2021)
Article
Chemistry, Physical
Haoxin Li, Xiaolin Zhao, Yining Li, Yang Gan, Wujie Qiu, Jifen Wang, Jianjun Liu
Summary: This study presents a new strategy to enhance both cation and anion redox activity in Li2MnO3 by substituting light metals for lithium, resulting in improved reversible capacity. The findings open up possibilities for improving the energy density of rechargeable batteries by low-cost element substitution.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Article
Chemistry, Applied
Shaojie Li, Xianxuan Ren, Brahim Mezari, Yujie Liu, Peerapol Pornsetmetakul, Anna Liutkova, Nikolay Kosinov, Emiel J. M. Hensen
Summary: Nanosized ZSM-5 zeolites with high acidity (Si/Al < 15) are advantageous catalysts for obtaining aromatics in C1 chemistry. However, synthesizing these nanosized zeolites in a cost-effective and scalable manner is challenging. In this study, nanosized ZSM-5 (20-50 nm) with high acidity (Si/Al = 11) was successfully synthesized using p-phenylenedimethylene-bis(tripropylammonium) dichloride as the sole organic structure-directing agent (OSDA). The nanosized ZSM-5 demonstrated enhanced aromatics formation compared to bulk ZSM-5 due to its high acidity and shortened diffusion paths in methanol dehydration and non-oxidative dehydroaromatization of methane reactions.
MICROPOROUS AND MESOPOROUS MATERIALS
(2023)
Article
Energy & Fuels
Haifeng Tian, Jiapeng Jiao, Haizhou Tian, Huanhuan He, Fei Zha, Xiaojun Guo, Xiaohua Tang, Yue Chang
Summary: Methanol to aromatics (MTA) is an effective method to produce aromatics through a non-petroleum route, with the acidity and structure of zeolite catalysts being key factors. Different preparation methods and Zn sources significantly influenced the products distribution in the MTA reaction. Steam-assisted crystallization method was found to improve the crystallinity and pore structure of the ZnZ8 catalyst.
Article
Chemistry, Physical
Siiri Bienz, Sophie H. van Vreeswijk, Yashashwa Pandey, Giovanni Luca Bartolomeo, Bert M. Weckhuysen, Renato Zenobi, Naresh Kumar
Summary: This study investigates the deactivation mechanism of zeolite ZSM-5 catalysts during the methanol-to-hydrocarbon (MTH) reaction using a combination of CFM and TEFL microscopy. The results reveal a preferential formation of coke species at the edges of ZSM-5 crystals within 10 minutes of the reaction, while the amount of coke species uniformly increases over the entire ZSM-5 surface after 90 minutes. Additionally, the TEFL imaging shows a higher formation of coke species at the crystal steps, indicating a higher initial catalytic activity.
CATALYSIS SCIENCE & TECHNOLOGY
(2022)
Article
Chemistry, Physical
S. H. van Vreeswijk, M. Monai, R. Oord, J. E. Schmidt, E. T. C. Vogt, J. D. Poplawsky, B. M. Weckhuysen
Summary: In this study, the nano-scale coking behavior of zeolite SSZ-13 was investigated using atom probe tomography (APT), revealing its similarity to silicoaluminophosphate and difference compared to previously studied zeolite ZSM-5.
CATALYSIS SCIENCE & TECHNOLOGY
(2022)
Article
Chemistry, Multidisciplinary
Chao Wang, Yueying Chu, Min Hu, Wenjin Cai, Qiang Wang, Shenhui Li, Jun Xu, Feng Deng
Summary: By using spectroscopy and calculations, this study clarified the nature of cation-pi interactions between cyclopentenyl cations and benzene over different zeolites. The zeolite structure affects the arrangements of the cations and benzene, leading to different cation-pi interaction strengths. Stronger cation-pi interactions facilitate bimolecular reactions and coke species formation.
CHEMICAL COMMUNICATIONS
(2022)
Article
Chemistry, Multidisciplinary
Ning Wei, Lulu Xu, Huimin Gong, Weiping Zhang, Dazhi Zhang, Shengjun Huang
Summary: Two protocols, sequential fluoride leaching-alkaline treatment and fluorination-alkaline treatment, are used to introduce mesoporosity in commercially available Al-rich mordenite zeolite. The sequential fluoride leaching-alkaline treatment successfully constructs intracrystalline mesopores, while the tandem fluorination-alkaline treatment does not. The different impacts of fluorination and fluoride leaching on mesoporosity development are closely associated with the alteration to the state of Al sites.
NEW JOURNAL OF CHEMISTRY
(2023)
Review
Chemistry, Multidisciplinary
Ana Palcic, Enrico Catizzone
Summary: Zeolites are efficient catalysts for methanol conversion reactions, with the crystal size affecting activity, product distribution, and coke deposition. Recent studies focus on the application of nanosized zeolites in MTD, MTO, and MTG processes, with critical discussion on product distribution, coke formation, and deactivation. Methods for preparing nanosized zeolites are mentioned, highlighting the impact of crystal size on zeolite-catalyzed methanol conversion reactions.
CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY
(2021)
Article
Chemistry, Inorganic & Nuclear
Xin Zhang, Hexun Zhou, Yiru Ye, Xinyu You, Xue Zhou, Shican Jiang, Kun Liu, Abhishek Dutta Chowdhury
Summary: This study focuses on improving the catalyst durability of zeolite FER-catalyzed methanol-to-hydrocarbon (MTH) process through material design, catalysis optimization, and advanced characterization. By optimizing the physicochemical properties, a unique flake-shaped FER zeolite with superior lifetime was developed. Combining it with Y2O3 further increased the catalyst lifespan and exhibited preferential selectivity for C4-C7 hydrocarbons.
INORGANIC CHEMISTRY FRONTIERS
(2023)
Article
Chemistry, Inorganic & Nuclear
Xin Zhang, Hexun Zhou, Yiru Ye, Xinyu You, Xue Zhou, Shican Jiang, Kun Liu, Abhishek Dutta Chowdhury
Summary: This study reports a unique flake-shaped FER zeolite with optimized physicochemical properties that offers a potential alternative catalyst for the MTH process. By combining it with Y2O3, a superior catalyst lifespan and selectivity were achieved compared to traditional FER zeolite.
INORGANIC CHEMISTRY FRONTIERS
(2023)
Article
Energy & Fuels
Satit Yousatit, Ryota Osuga, Junko N. Kondo, Toshiyuki Yokoi, Chawalit Ngamcharussrivichai
Summary: In this study, a mesoporous carbon/silica (MCS) nanocomposite was synthesized as a catalyst support for the production of 5-hydroxymethylfurfural (HMF) from glucose. By modifying the MCS surface, a series of acid-base catalysts were developed, and the acid-base properties could be tuned by adjusting the content of sulfonic acid and amino propyl groups. The developed MCS-SO3H-NH2 catalyst showed high HMF yield and selectivity when compared to other catalyst systems.
Article
Energy & Fuels
Md Abdul Aziz, Syed Shaheen Shah, S. M. Abu Nayem, M. Nasiruzzaman Shaikh, Abbas Saeed Hakeem, Idris Akolade Bakare
Summary: This study investigates the performance of an all-solid-state symmetric supercapacitor fabricated using Marsh clay derived material and PVA/KOH gel electrolyte. The experimental results demonstrate that the device exhibits high specific capacitance, high energy density, and good cycling stability, indicating the great potential for high-performance supercapacitors.
JOURNAL OF ENERGY STORAGE
(2022)
Article
Engineering, Chemical
Ryota Osuga, Atsushi Neya, Motohiro Yoshida, Mizuho Yabushita, Shuhei Yasuda, Sachiko Maki, Kiyoshi Kanie, Toshiyuki Yokoi, Atsushi Muramatsu
Summary: This study successfully improved the catalytic performance of low-temperature oxidative coupling of methane by using Ce-MFI zeolite supported Pd catalysts modified by a second metal. It was found that the coexistence of Pd and Co on Ce-MFI positively affected the C2H6 yield, and the highly dispersed Ce species in Ce-MFI also played a positive role in the catalytic reaction.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2022)
Article
Chemistry, Physical
Atikhun Chottiratanachote, Manaswee Suttipong, Umer Rashid, Vudhichai Parasuk, Junko Nomura Kondo, Toshiyuki Yokoi, Ali Alsalme, Chawalit Ngamcharussrivichai
Summary: This study aims to synthesize alpha,beta-unsaturated carbonyl compounds with branched structures via aldol condensation of furfural and 2-butanone using MgAl mixed oxides as catalysts. The most suitable catalyst is LDO3 with a 3:1 Mg:Al atomic ratio. The suitable reaction conditions to produce the branched-chain C9 ketones are 1:5 furfural:2-butanone molar ratio, 5 wt.% catalyst loading, 120 degrees C reaction temperature, and 8 h reaction time.
Article
Chemistry, Multidisciplinary
Munzir H. Suliman, Zain H. Yamani, Muhammad Usman
Summary: In this study, copper-melamine complex was used to synthesize copper-based electrocatalysts, specifically copper nanoparticles decorated on nitrogen-doped carbon nanosheets. The as-prepared electrocatalysts showed good dispersion, high current density, electrochemical surface area, electrical conductivity, stability, and faradic efficiency in the electrochemical CO2 reduction reaction.
Article
Chemistry, Physical
Tomoki Kanazawa, Shunta Nishioka, Shuhei Yasuda, Daichi Kato, Toshiyuki Yokoi, Shunsuke Nozawa, Hiroshi Kageyama, Kazuhiko Maeda
Summary: The local structure dependence of BaTiO3-xHx on the doped H- amount was investigated using Raman and X-ray absorption fine-structure (XAFS) spectroscopy measurements. It was found that the tetragonal phase transforms into the cubic phase when the doped H- amount is relatively large (x ≥ 0.2). XAFS measurements revealed that the TiO6 octahedral symmetry in BaTiO3-xHx is strongly affected by the doped H- amount, where an increase of H- relaxes the local distortion of the Ti [111] displacement and causes the tetragonal-to-cubic structural change.
JOURNAL OF PHYSICAL CHEMISTRY C
(2023)
Article
Chemistry, Multidisciplinary
Nuttapat Thiensuwan, Sivashunmugam Sankaranarayanan, Toshiyuki Yokoi, Chawalit Ngamcharussrivichai
Summary: The Ru-based nanocomposites supported on exfoliated MgAl-double oxides were investigated for the catalytic oxidation of HMF to FDCA. The exfoliated LDO-supported Ru catalysts showed enhanced textural properties, RuO x dispersion, and basicity, resulting in better catalytic activity. Among them, Ru(3)/ESV-LDC catalyst exhibited good reusability without significant loss of HMF conversion and FDCA yield.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2023)
Article
Chemistry, Multidisciplinary
Bernd Marler, Hermann Gies, Trees De Baerdemaeker, Ulrich Mueller, Andrei-Nicolae Parvulescu, Weiping Zhang, Toshiyuki Yokoi, Feng-Shou Xiao, Xiangju Meng, Dirk De Vos, Ute Kolb
Summary: A new zeolite, COE-11, was synthesized through hydrothermal synthesis and characterized as a microporous borosilicate zeolite with a 2D pore system. It has a close structural relationship with zeolite beta polymorph B but differs in pore system dimensionality.
CHEMISTRY-SWITZERLAND
(2023)
Article
Biochemistry & Molecular Biology
Kamolwan Jermjun, Rujeeluk Khumho, Mookarin Thongoiam, Satit Yousatit, Toshiyuki Yokoi, Chawalit Ngamcharussrivichai, Sakdinun Nuntang
Summary: In this study, natural rubber/hexagonal mesoporous silica (NR/HMS) nanocomposites were synthesized and used as selective adsorbents to separate EGCG and CAF from green tea. The NR/HMS materials showed high adsorption capacity for EGCG and could be reused multiple times. This research suggests the potential use of NR/HMS nanocomposites for enriching EGCG in green tea and reducing CAF content. Rating: 8/10.
Article
Chemistry, Multidisciplinary
Akinobu Miyoshi, Megumi Okazaki, Kosaku Kato, Tomoki Kanazawa, Toshiyuki Yokoi, Shunta Nishioka, Shunsuke Nozawa, Akira Yamakata, Kazuhiko Maeda
Summary: The development of a photocatalyst capable of evolving H-2 from water under visible light is important. Pd was found to be the best-performing cocatalyst for TiO2:N,F under UV-vis irradiation. However, under visible-light irradiation, the activity of Pd/TiO2:N,F for H-2 evolution was negligibly small.
Article
Materials Science, Multidisciplinary
Kenta Aihara, Ryusuke Mizuochi, Megumi Okazaki, Shunta Nishioka, Shuhei Yasuda, Toshiyuki Yokoi, Fumitaka Ishiwari, Akinori Saeki, Miki Inada, Kazuhiko Maeda
Summary: Mixed-anion compounds are difficult to synthesize compared to ordinary single-anion counterparts, but they have great potential as visible-light-driven photocatalysts. In this study, Pb2Ti2O5.4F1.2 particles with a well-defined octahedral shape were successfully synthesized by a microwave-assisted hydrothermal (MHT) method at 473 K. The MHT-Pb2Ti2O5.4F1.2 showed improved activity for visible-light H-2 evolution compared to its analogue synthesized by a conventional solid-state reaction (SSR). A postheating treatment further enhanced its activity, and the optimized MHT-Pb2Ti2O5.4F1.2 achieved nonsacrificial H-2 evolution in the presence of a reversible electron donor.
ACS MATERIALS LETTERS
(2023)
Article
Chemistry, Physical
Peipei Xiao, Yong Wang, Kengo Nakamura, Yao Lu, Junko N. Kondo, Hermann Gies, Toshiyuki Yokoi
Summary: In this study, a strategy to reduce the thickness along the c-axis of AEI-type zeolite crystals was adopted to improve the catalytic properties and stability in the direct oxidation of methane to methanol. The sheet-like Cu-exchanged AEI zeolite exhibited better performance compared to the typical cubic-shaped zeolite. This was attributed to the decreased straight channel length, which facilitated reactant and product diffusion and suppressed the secondary reaction of methanol to olefins.
CATALYSIS SCIENCE & TECHNOLOGY
(2023)
Article
Chemistry, Physical
Mizuho Yabushita, Ryota Osuga, Toshiyuki Yokoi, Atsushi Muramatsu
Summary: Oxidative upgrading of methane into valuable products can be achieved at low temperatures over zeolite-based catalysts. The unique tunability provided by zeolite framework structures enables the design of active species, resulting in excellent catalytic performance. This article categorizes the active species in zeolite-based catalysts into three groups and provides a comprehensive overview of their performance, structure, and catalysis.
CATALYSIS SCIENCE & TECHNOLOGY
(2023)
Article
Chemistry, Physical
Yuta Shiroma, Hiroto Mogi, Takeaki Mashiko, Shuhei Yasuda, Shunta Nishioka, Toshiyuki Yokoi, Shintaro Ida, Koji Kimoto, Kazuhiko Maeda
Summary: Modification of the interlayer nanospaces of lamellar solids can enhance their physical properties and chemical functions. In this study, the interlayer of a layered perovskite oxynitride was modified by H+/K+ exchange, ethylamine intercalation, and exfoliation-restacking. The ethylamine intercalated specimen showed significantly improved photocatalytic H-2 evolution activity, while the restacked nanosheets exhibited decreased activity. These findings suggest that ethylamine intercalation provided suitable interlayer nanospaces for Pt cocatalyst loading, promoting the photocatalytic reaction.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Chemistry, Physical
Daniele Padovan, Koichiro Endo, Takeshi Matsumoto, Toshiyuki Yokoi, Atsushi Fukuoka, Hideki Kato, Kiyotaka Nakajima
Summary: The acid-base properties of amphoteric crystalline YNbO4 are adjusted by impregnating phosphate groups, resulting in materials with increased activity and selectivity in glucose dehydration. The introduction of phosphate groups leads to the optimal catalyst, 5P-YNbO4, which exhibits 50% selectivity at 75% conversion. The catalyst can be deactivated due to carbon deposits, but its activity can be completely recovered through washing and calcination.
Article
Chemistry, Physical
Zi-Ye Liu, Qian-Yu Wang, Ji-Ming Hu
Summary: In this study, a layered carbon dot composite catalyst (NiFe LDH@CDs) was prepared using a one-step coprecipitation method, without the need for heating or hydrothermal treatment. The CD-functionalized catalyst facilitated rapid charge transfer and accelerated the oxygen evolution reaction. Additionally, the heterojunction structure formed between NiFe LDH and CDs efficiently suppressed photoelectron-hole recombination.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Article
Chemistry, Physical
Rohit Kumar, Ankit Kumar Srivastava, Palaniyappan Nagarasu, Vedichi Madhu, Ekambaram Balaraman
Summary: We designed and synthesized a NN-CoII bidentate complex and used it for the amination of alcohols under mild and solventless conditions. The complex exhibited good reactivity towards both primary and sterically hindered secondary alcohols, providing high yields of amines. The pyrazole moiety in the ligand played a crucial role in the reaction. Furthermore, we demonstrated the reusability of the complex as a homogeneous cobalt catalyst.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Article
Chemistry, Physical
Shivanand Chettri, Liang-Ting Wu, Sagarmani Rasaily, Debesh Sharma, Bikram Gurung, Rajani Dewan, Sudarsan Tamang, Jyh-Chiang Jiang, Anand Pariyar
Summary: Replicating the enzymatic surface microenvironment in vitro is challenging, but constructing an analogous model could facilitate our understanding of surface effects and aid in developing an efficient bioinspired catalytic system. In this study, five unique Cu2O morphologies were generated, and the surface morphology variations were found to be a consequence of differences in the exposure of low-index facets. The reactivity of Cu2O was found to be influenced by the proportion of {110} planes, with r-Cu2O exhibiting the highest reactivity.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Article
Chemistry, Physical
Yong Tang, Jianhao Qiu, Dingliang Dai, Guanglu Xia, Lu Zhang, Jianfeng Yao
Summary: Defect engineering has been shown to improve the photocatalytic performance. This study investigated the use of defect-rich UiO-66-NH2 wrapped by ZnIn2S4 as a catalyst for photocatalytic H2O2 production. The defects in UiO-66-NH2 enhanced O-2 adsorption and charge separation, leading to higher H2O2 yield. The insights from this work can advance the research in defect engineering of MOFs and photocatalytic H2O2 synthesis.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Article
Chemistry, Physical
Ruiyang Qu, Shuxin Mao, Jana Weiss, Vita A. Kondratenko, Evgenii V. Kondratenko, Stephan Bartling, Haifeng Qi, Annette-Enrica Surkus, Kathrin Junge, Matthias Beller
Summary: The hydrogenation of amides, a challenging reaction usually performed at high temperatures, has been achieved under milder conditions using a new Pt-MoOx/TiO2 catalyst. This catalyst system enables the selective hydrogenation of various amides and imides.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Article
Chemistry, Physical
Xiaoran Niu, Ao Wang, Lei Tong, Lei Wang, Yuan Kong, Chenliang Su, Hai-Wei Liang
Summary: This study introduces a novel intermetallic PdCu3 catalyst supported on defective nanodiamond-graphene (ND@G), which exhibits high selectivity (95%) and remarkable activity (turnover frequency: 2940 h(-1)), six times higher than that of the commercial Lindlar catalyst.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Review
Chemistry, Physical
Zhiyuan Zheng, Yiming Yue, Hongying Zhuo, Qinggang Liu, Yanqiang Huang
Summary: This review presents the recent research advances on single-atom catalysis for deep reduction of CO2. Detailed introductions and summaries were classified into three categories based on proton-coupled multi-electron transfer approaches: strengthening metal-support interaction, rational design and regulation of coordination environment, and development of SACs with multi-atom active sites. The challenges and future research directions in the field of SACs for CO2 reduction are also proposed.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Article
Chemistry, Physical
Shiv Kumar, Paramita Datta, Anup Bhunia, Swadhin K. Mandal
Summary: This article reports a transition-metal-free process for in situ denitrogenation of tosylhydrazones, resulting in the production of various sulfones. The authors used a phenalenyl-based odd alternant hydrocarbon as a photoredox catalyst, which acted as a potent oxidant to facilitate the denitrogenation reaction. The method showed wide functional-group tolerance and high yields, making it suitable for late-stage modification of natural products.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
Article
Chemistry, Physical
L. A. Luque-Alvarez, J. Gonzalez-Arias, F. Romero-Sarria, T. R. Reina, L. F. Bobadilla, J. A. Odriozola
Summary: Currently, the production of acetic acid through the carbonylation reaction of methanol has limitations, leading to the exploration of alternative methods using heterogeneous catalysts. This study investigates the methanol carbonylation reaction over a Cu-H-MOR catalyst and proposes a reaction mechanism based on the catalytic behavior and performance of the catalyst. The results provide insights into the reaction mechanism and the involvement of acid and redox centers.
CATALYSIS SCIENCE & TECHNOLOGY
(2024)
