Journal
CATALYSIS SCIENCE & TECHNOLOGY
Volume 6, Issue 4, Pages 998-1002Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cy01907a
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Funding
- Fundamental Research Funds for the Central Universities [30920130111002]
- National Natural Science Foundation of China [21476116]
- Natural Science Foundation of Jiangsu [BK20141394]
- Center for Advanced Materials and Technology
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An investigation into the regiochemistry of radical functionalization of indoles using cycloalkanes through di-tertbutyl peroxide (DTBP)-promoted C(sp(3))-H activation was conducted. A wide range of indoles bearing substituents at different positions was functionalized directly with simple cycloalkanes in moderate to high regioselectivity. 2-, 4- and 7-positions were mainly functionalized.
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