4.6 Article

Fabrication, degradation behavior and cytotoxicity of nanostructured hardystonite and titania/hardystonite coatings on Mg alloys

Journal

VACUUM
Volume 129, Issue -, Pages 9-12

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.vacuum.2016.03.021

Keywords

Mg alloy; Hardystonite; Titania; Corrosion behavior; Cytotoxicity

Funding

  1. Malaysian Ministry of Higher Education (MOHE)
  2. Universiti Teknologi Malaysia

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In this study, nanostructured hardystonite (HT) and titania (TiO2)/hardystonite (HT) dual-layered coatings were deposited on biodegradable Mg-Ca-Zn alloy via physical vapor deposition (PVD) combined with electrophoretic deposition (EPD). Although a single layer nano-HT coating can decrease the corrosion rate from 1.68 to 1.02 mm/year, due to the presence of porosities and microcracks, the nano-HT layer cannot sufficiently protect the Mg substrate. In contrast, the corrosion resistance of nano-HT coating is further improved by using nano-TiO2 underlayer since it was a smooth, very uniform and compact layer with higher contact angle (52.30 degrees). In addition, the MTT assay showed the viability of MC3T3-E1 on the nano-HT and nano-TiO2/HT coatings. The results demonstrated that the two-step surface modification improved both corrosion resistance and the cytocompatibility of the Mg alloy, hence making it feasible for orthopedic applications. (C) 2016 Elsevier Ltd. All rights reserved.

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