Two Reaction Mechanisms via Iminium Ion Intermediates: The Different Reactivities of Diphenylprolinol Silyl Ether and Trifluoromethyl-Substituted Diarylprolinol Silyl Ether

Pyrrolidine catalyzed reactions of cyclopentadiene with α,β-unsaturated carbonyl compounds: 1,2- versus 1,4-additions

(2015) Necdet Coskun et al.   TETRAHEDRON

Diphenylprolinol Silyl Ether Catalyzed Asymmetric Michael Reaction of Nitroalkanes and β,β-Disubstituted α,β-Unsaturated Aldehydes for the Construction of All-Carbon Quaternary Stereogenic Centers

(2014) Yujiro Hayashi et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Theoretical and Experimental Study of the Effects of Silyl Substituents in Enantioselective Reactions Catalyzed by Diphenylprolinol Silyl Ether

(2014) Yujiro Hayashi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Transfer of 1-Alkenyl Groups between Secondary Amines. Relative Stability and Reactivity of Enamines from Popular Organocatalysts

(2014) Héctor Carneros et al.   ORGANIC LETTERS

Stoichiometric Reactions of Enamines Derived from Diphenylprolinol Silyl Ethers with Nitro Olefins and Lessons for the Corresponding Organocatalytic Conversions - a Survey

(2013) Dieter Seebach et al.   HELVETICA CHIMICA ACTA

Imidazolidinone-Derived Enamines: Nucleophiles with Low Reactivity

(2012) Sami Lakhdar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A quantitative approach to nucleophilic organocatalysis

(2012) Herbert Mayr et al.   Beilstein Journal of Organic Chemistry

Curtin–Hammett Paradigm for Stereocontrol in Organocatalysis by Diarylprolinol Ether Catalysts

(2012) Jordi Burés et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalyzed Michael Addition of Aldehydes to Nitro Alkenes - Generally Accepted Mechanism Revisited and Revised

(2011) Krystyna Patora-Komisarska et al.   HELVETICA CHIMICA ACTA

Mechanistic Rationalization of Organocatalyzed Conjugate Addition of Linear Aldehydes to Nitro-olefins

(2011) Jordi Burés et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iminium ion catalysis: direct comparison of imidazolidinone and diarylprolinol ether reactivity

(2011) John B. Brazier et al.   TETRAHEDRON LETTERS

Asymmetric Synthesis with Silicon-Based Bulky Amino Organocatalysts

(2010) Li-Wen Xu et al.   ADVANCED SYNTHESIS & CATALYSIS

Organocatalyzed Asymmetric Friedel-Crafts Reactions

(2010) Vincent Terrasson et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Asymmetric organocatalysis in total synthesis – a trial by fire

(2010) Eugenia Marqués-López et al.   NATURAL PRODUCT REPORTS

One-pot synthesis of chiral bicyclo[3.3.0]octatrienes using diphenylprolinol silyl ether-mediated ene-type reaction

(2010) Hiroaki Gotoh et al.   TETRAHEDRON

Organocatalysis—after the gold rush

(2009) Søren Bertelsen et al.   CHEMICAL SOCIETY REVIEWS

Structures of the Reactive Intermediates in Organocatalysis with Diarylprolinol Ethers

(2009) Uroš Grošelj et al.   HELVETICA CHIMICA ACTA

Electrophilic Reactivities of α,β-Unsaturated Iminium Ions

(2008) Sami Lakhdar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Kinetics of Iminium Ion Catalysis

(2008) Gareth Evans et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diphenylprolinol Silyl Ether as a Catalyst in an Enantioselective, Catalytic, Formal Aza [3+3] Cycloaddition Reaction for the Formation of Enantioenriched Piperidines

(2008) Yujiro Hayashi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Aminocatalysis-Gold Rush in Organic Chemistry

(2008) Paolo Melchiorre et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Diels-Alder Reactions of α,β-Unsaturated Aldehydes Catalyzed by a Diarylprolinol Silyl Ether Salt in the Presence of Water

(2008) Yujiro Hayashi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Organocatalysis: From Infancy to Adolescence

(2008) Alessandro Dondoni et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

α,α-Diarylprolinol Ethers: New Tools for Functionalization of Carbonyl Compounds

(2008) Antonia Mielgo et al.   Chemistry-An Asian Journal

Diphenylprolinol Silyl Ether as a Catalyst in an Enantioselective, Catalytic Michael Reaction for the Formation of α,α-Disubstituted α-Amino Acid Derivatives

(2008) Yujiro Hayashi et al.   Chemistry-An Asian Journal

The advent and development of organocatalysis

(2008) David W. C. MacMillan   NATURE

Diphenylprolinol Silyl Ether Catalysis in an Asymmetric Formal Carbo [3 + 3] Cycloaddition Reaction via a Domino Michael/Knoevenagel Condensation

(2008) Yujiro Hayashi et al.   ORGANIC LETTERS

Organocatalysis Lost: Modern Chemistry, Ancient Chemistry, and an Unseen Biosynthetic Apparatus

(2007) Carlos F. Barbas   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION