Palladium-catalyzed Suzuki–Miyaura coupling of amides by carbon–nitrogen cleavage: general strategy for amide N–C bond activation

Enantioselective oxidative boron Heck reactions

(2016) A.-L. Lee   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhodium-Catalyzed C–H Bond Functionalization with Amides by Double C–H/C–N Bond Activation

(2016) Guangrong Meng et al.   ORGANIC LETTERS

Cross-Couplings Using Aryl Ethers via C–O Bond Activation Enabled by Nickel Catalysts

(2015) Mamoru Tobisu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Strong Bonds Made Weak: Towards the General Utility of Amides as Synthetic Modules

(2015) Stefan A. Ruider et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

General Olefin Synthesis by the Palladium-Catalyzed Heck Reaction of Amides: Sterically Controlled Chemoselective NC Activation

(2015) Guangrong Meng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd-Catalyzed CH Activation: Expanding the Portfolio of Metal-Catalyzed Functionalization of Unreactive CH Bonds by Arene-Chromium π-Complexation

(2015) Feng Hu et al.   ChemCatChem

An efficient computational model to predict protonation at the amide nitrogen and reactivity along the C–N rotational pathway

(2015) Roman Szostak et al.   CHEMICAL COMMUNICATIONS

Acylative Suzuki coupling of amides: acyl-nitrogen activation via synergy of independently modifiable activating groups

(2015) Xijing Li et al.   CHEMICAL COMMUNICATIONS

Olefins from biomass feedstocks: catalytic ester decarbonylation and tandem Heck-type coupling

(2015) Alex John et al.   CHEMICAL COMMUNICATIONS

Transition-Metal-Catalyzed Cleavage of C–N Single Bonds

(2015) Kunbing Ouyang et al.   CHEMICAL REVIEWS

Determination of Structures and Energetics of Small- and Medium-Sized One-Carbon-Bridged Twisted Amides using ab Initio Molecular Orbital Methods: Implications for Amidic Resonance along the C–N Rotational Pathway

(2015) Roman Szostak et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-catalyzed acylative cross-coupling of amides with diarylborinic acids and sodium tetraarylborates

(2015) Xijing Li et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Graphene-Catalyzed Direct Friedel–Crafts Alkylation Reactions: Mechanism, Selectivity, and Synthetic Utility

(2015) Feng Hu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Conversion of amides to esters by the nickel-catalysed activation of amide C–N bonds

(2015) Liana Hie et al.   NATURE

Nickel-catalysed Suzuki–Miyaura coupling of amides

(2015) Nicholas A. Weires et al.   Nature Chemistry

Rhodium-catalysed asymmetric allylic arylation of racemic halides with arylboronic acids

(2015) Mireia Sidera et al.   Nature Chemistry

Aminoketyl Radicals in Organic Synthesis: Stereoselective Cyclization of Five- and Six-Membered Cyclic Imides to 2-Azabicycles Using SmI2–H2O

(2015) Shicheng Shi et al.   ORGANIC LETTERS

Sterically Controlled Pd-Catalyzed Chemoselective Ketone Synthesis via N–C Cleavage in Twisted Amides

(2015) Guangrong Meng et al.   ORGANIC LETTERS

Amino acid chlorides: a journey from instability and racemization toward broader utility in organic synthesis including peptides and their mimetics

(2015) Girish Prabhu et al.   TETRAHEDRON

Palladium-Catalyzed Decarbonylative Dehydration of Fatty Acids for the Production of Linear Alpha Olefins

(2014) Yiyang Liu et al.   ADVANCED SYNTHESIS & CATALYSIS

Chemoselective Boronic Ester Synthesis by Controlled Speciation

(2014) James W. B. Fyfe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Direct CH Functionalization of Benzoquinone

(2014) Sarah E. Walker et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct C sp2H and C sp3H Arylation Enabled by Heterogeneous Palladium Catalysts

(2014) Laurent Djakovitch et al.   ChemCatChem

Catalytic amide formation from non-activated carboxylic acids and amines

(2014) Helena Lundberg et al.   CHEMICAL SOCIETY REVIEWS

Metal-catalyzed activation of ethers via C–O bond cleavage: a new strategy for molecular diversity

(2014) Josep Cornella et al.   CHEMICAL SOCIETY REVIEWS

Mechanism of SmI2/Amine/H2O-Promoted Chemoselective Reductions of Carboxylic Acid Derivatives (Esters, Acids, and Amides) to Alcohols

(2014) Michal Szostak et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly Chemoselective Reduction of Amides (Primary, Secondary, Tertiary) to Alcohols using SmI2/Amine/H2O under Mild Conditions

(2014) Michal Szostak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereospecific Pd-Catalyzed Cross-Coupling Reactions of Secondary Alkylboron Nucleophiles and Aryl Chlorides

(2014) Ling Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Reductive and Borylative Cleavage of Aromatic Carbon–Nitrogen Bonds in N-Aryl Amides and Carbamates

(2014) Mamoru Tobisu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantiospecific sp2–sp3 coupling of secondary and tertiary boronic esters

(2014) Amadeu Bonet et al.   Nature Chemistry

Ten Years of Adventures with Pd/C Catalysts: From Reductive Processes to Coupling Reactions

(2014) François-Xavier Felpin   SYNLETT

Mild Palladium-Catalyzed Oxidative Directortho-CH Acylation of Anilides under Aqueous Conditions

(2013) Fruzsina Szabó et al.   ADVANCED SYNTHESIS & CATALYSIS

Transmetalation in the Suzuki-Miyaura Coupling: The Fork in the Trail

(2013) Alastair J. J. Lennox et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Reduction of Barbituric Acids Using SmI2/H2O: Synthesis, Reactivity, and Structural Analysis of Tetrahedral Adducts

(2013) Michal Szostak et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Uncovering the Importance of Proton Donors in TmI2-Promoted Electron Transfer: Facile CN Bond Cleavage in Unactivated Amides

(2013) Michal Szostak et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structural analysis and reactivity of unusual tetrahedral intermediates enabled by SmI2-mediated reduction of barbituric acids: vinylogous N-acyliminium additions to α-hydroxy-N-acyl-carbamides

(2013) Michal Szostak et al.   CHEMICAL COMMUNICATIONS

Chemistry of Bridged Lactams and Related Heterocycles

(2013) Michal Szostak et al.   CHEMICAL REVIEWS

Transition-metal-catalyzed Suzuki–Miyaura cross-coupling reactions: a remarkable advance from palladium to nickel catalysts

(2013) Fu-She Han   CHEMICAL SOCIETY REVIEWS

Selection of boron reagents for Suzuki–Miyaura coupling

(2013) Alastair J. J. Lennox et al.   CHEMICAL SOCIETY REVIEWS

Mechanism of Palladium-Catalyzed Suzuki-Miyaura Reactions: Multiple and Antagonistic Roles of Anionic “Bases” and Their Countercations

(2013) Christian Amatore et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Cross-Coupling Reaction of Organoboron Compounds with Carboxylic Derivatives

(2013) Jun Yang et al.   CHINESE JOURNAL OF ORGANIC CHEMISTRY

Suzuki-Miyaura Cross-Coupling in Acylation Reactions, Scope and Recent Developments

(2013) Marco Blangetti et al.   MOLECULES

Controlling Site Selectivity in Palladium-Catalyzed C–H Bond Functionalization

(2012) Sharon R. Neufeldt et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic Selective Synthesis

(2012) Jessada Mahatthananchai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A New Twist on Amide Solvolysis

(2012) Jeffrey Aubé   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Cross-Coupling: A Historical Contextual Perspective to the 2010 Nobel Prize

(2012) Carin C. C. Johansson Seechurn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Boroalkyl Group Migration Provides a Versatile Entry into α-Aminoboronic Acid Derivatives

(2012) Zhi He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carboxylates as sources of carbon nucleophiles and electrophiles: comparison of decarboxylative and decarbonylative pathways

(2012) Wojciech I. Dzik et al.   Chemical Science

Switching Pathways: Room-Temperature Neutral Solvolysis and Substitution of Amides

(2011) Marc Hutchby et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of diaryl ketones via a phosphine-free Fukuyama reaction

(2011) Kamala Kunchithapatham et al.   CHEMICAL COMMUNICATIONS

Transmetalation of Unsaturated Carbon Nucleophiles from Boron-Containing Species to the Mid to Late d-Block Metals of Relevance to Catalytic C−X Coupling Reactions (X = C, F, N, O, Pb, S, Se, Te)

(2011) David V. Partyka   CHEMICAL REVIEWS

The asymmetric Heck and related reactions

(2011) Dennis Mc Cartney et al.   CHEMICAL SOCIETY REVIEWS

The Medicinal Chemist’s Toolbox: An Analysis of Reactions Used in the Pursuit of Drug Candidates

(2011) Stephen D. Roughley et al.   JOURNAL OF MEDICINAL CHEMISTRY

Mobilizing Cu(I) for Carbon−Carbon Bond Forming Catalysis in the Presence of Thiolate. Chemical Mimicking of Metallothioneins

(2011) Zhihui Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A computational study of phosphine ligand effects in Suzuki–Miyaura coupling☆

(2010) Jesús Jover et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

A New Palladium Precatalyst Allows for the Fast Suzuki−Miyaura Coupling Reactions of Unstable Polyfluorophenyl and 2-Heteroaryl Boronic Acids

(2010) Tom Kinzel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Medium-bridged lactams: a new class of non-planar amides

(2010) Michal Szostak et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A Copper-Catalyzed, pH-Neutral Construction of High-Enantiopurity Peptidyl Ketones from PeptidicS-Acylthiosalicylamides in Air at Room Temperature

(2009) Lanny S. Liebeskind et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemoselectivity and the Curious Reactivity Preferences of Functional Groups

(2009) Nicholas A. Afagh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Carbonylation Reactions of Aryl Halides and Related Compounds

(2009) Anne Brennführer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox Economy in Organic Synthesis

(2009) Noah Z. Burns et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-free carbon–carbon bond-forming reductive coupling between boronic acids and tosylhydrazones

(2009) José Barluenga et al.   Nature Chemistry

Palladium-Catalyzed Suzuki−Miyaura Cross-Coupling Reactions Employing Dialkylbiaryl Phosphine Ligands

(2008) Ruben Martin et al.   ACCOUNTS OF CHEMICAL RESEARCH

The Liebeskind-Srogl CC Cross-Coupling Reaction

(2008) Hana Prokopcová et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carboxylic Acids as Substrates in Homogeneous Catalysis

(2008) Lukas J. Gooßen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Suzuki–Miyaura Cross-Coupling Reactions of Alkylboronic Acid Derivatives or Alkyltrifluoroborates with Aryl, Alkenyl or Alkyl Halides and Triflates

(2008) Henri Doucet   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Room Temperature and Phosphine Free Palladium Catalyzed Direct C-2 Arylation of Indoles

(2008) Nathalie Lebrasseur et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbon–heteroatom bond formation catalysed by organometallic complexes

(2008) John F. Hartwig   NATURE

A mechanistic study on modern palladium catalyst precursors as new gateways to Pd(0) in cationic Heck reactions

(2008) Andreas Svennebring et al.   TETRAHEDRON

More than Bystanders: The Effect of Olefins on Transition-Metal-Catalyzed Cross-Coupling Reactions

(2007) Jeffrey B. Johnson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Online Mechanistic Investigations of Catalyzed Reactions by Electrospray Ionization Mass Spectrometry: A Tool to Intercept Transient Species in Solution

(2007) Leonardo S. Santos   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY