Synthesis of tetra-substituted 5-trifluoromethylpyrazoles via sequential halogenation/palladium-catalyzed C–C and C–N cross-coupling

Recent Progress on Pyrazole Scaffold-Based Antimycobacterial Agents

(2015) Rangappa S. Keri et al.   ARCHIV DER PHARMAZIE

Palladium-Catalyzed Amination of Unprotected Five-Membered Heterocyclic Bromides

(2014) Mingjuan Su et al.   ORGANIC LETTERS

BippyPhos: A Single Ligand With Unprecedented Scope in the Buchwald-Hartwig Amination of (Hetero)aryl Chlorides

(2013) Sarah M. Crawford et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mild and Highly Selective Palladium-Catalyzed Monoarylation of Ammonia Enabled by the Use of Bulky Biarylphosphine Ligands and Palladacycle Precatalysts

(2013) Chi Wai Cheung et al.   ORGANIC LETTERS

A Bulky Biaryl Phosphine Ligand Allows for Palladium-Catalyzed Amidation of Five-Membered Heterocycles as Electrophiles

(2012) Mingjuan Su et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild and General Conditions for Negishi Cross-Coupling Enabled by the Use of Palladacycle Precatalysts

(2012) Yang Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A General and Regioselective Synthesis of 5-Trifluoromethyl-pyrazoles

(2012) Robert S. Foster et al.   ORGANIC LETTERS

New one-pot, efficient, and regioselective method for the synthesis of 3-Trifluoromethyl-1H-1-phenylpyrazoles and alkyl 3-carboxylate analogs

(2012) Helio G. Bonacorso et al.   TETRAHEDRON LETTERS

Rational and Predictable Chemoselective Synthesis of Oligoamines via Buchwald–Hartwig Amination of (Hetero)Aryl Chlorides Employing Mor-DalPhos

(2011) Bennett J. Tardiff et al.   JOURNAL OF ORGANIC CHEMISTRY

A Medicinal Chemist’s Guide to Molecular Interactions

(2010) Caterina Bissantz et al.   JOURNAL OF MEDICINAL CHEMISTRY

Trifluoromethyl-substituted pyridyl- and pyrazolylboronic acids and esters: synthesis and Suzuki–Miyaura cross-coupling reactions

(2009) Kate M. Clapham et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Highly Reactive, General and Long-Lived Catalysts for Palladium-Catalyzed Amination of Heteroaryl and Aryl Chlorides, Bromides, and Iodides: Scope and Structure–Activity Relationships

(2008) Qilong Shen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Streamlined Synthesis of the Bippyphos Family of Ligands and Cross-Coupling Applications

(2008) Gregory J. Withbroe et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT