BippyPhos: A Single Ligand With Unprecedented Scope in the Buchwald-Hartwig Amination of (Hetero)aryl Chlorides

Pd2dba3/Bippyphos: A Robust Catalyst System for the Hydroxylation of Aryl Halides with Broad Substrate Scope

(2013) Christopher B. Lavery et al.   ADVANCED SYNTHESIS & CATALYSIS

Mild and Rapid Pd-Catalyzed Cross-Coupling with Hydrazine in Continuous Flow: Application to the Synthesis of Functionalized Heterocycles

(2013) Andrew DeAngelis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient palladium-catalyzed synthesis of substituted indoles employing a new (silanyloxyphenyl)phosphine ligand

(2012) Christopher B. Lavery et al.   CHEMICAL COMMUNICATIONS

Addressing Challenges in Palladium-Catalyzed Cross-Coupling Reactions Through Ligand Design

(2012) Rylan J. Lundgren et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Convenient and Practical Synthesis of Anisoles and Deuterated Anisoles by Palladium-Catalyzed Coupling Reactions of Aryl Bromides and Chlorides

(2012) Saravanan Gowrisankar et al.   CHEMISTRY-A EUROPEAN JOURNAL

[Pd(IPr*)(cinnamyl)Cl]: An Efficient Pre-catalyst for the Preparation of Tetra-ortho-substituted Biaryls by Suzuki-Miyaura Cross-Coupling

(2012) Anthony Chartoire et al.   CHEMISTRY-A EUROPEAN JOURNAL

Buchwald-Hartwig Amination of (Hetero)aryl Chlorides by Employing Mor-DalPhos under Aqueous and Solvent-Free Conditions

(2012) Bennett J. Tardiff et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Cascade Palladium- and Copper-Catalysed Aromatic Heterocycle Synthesis: The Emergence of General Precursors

(2012) Catherine J. Ball et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

The Complementary Competitors: Palladium and Copper in C–N Cross-Coupling Reactions

(2012) Irina P. Beletskaya et al.   ORGANOMETALLICS

Stoichiometric Reactivity Relevant to the Mor-DalPhos/Pd-Catalyzed Cross-Coupling of Ammonia and 1-Bromo-2-(phenylethynyl)benzene

(2012) Pamela G. Alsabeh et al.   ORGANOMETALLICS

Spiroazetidine–piperidine bromoindane as a key modular template to access a variety of compounds via C–C and C–N bond-forming reactions

(2012) Dilinie P. Fernando et al.   TETRAHEDRON LETTERS

A Single Phosphine Ligand Allows Palladium-Catalyzed Intermolecular CO Bond Formation with Secondary and Primary Alcohols

(2011) Xiaoxing Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalyzed synthesis of indoles via ammonia cross-coupling–alkyne cyclization

(2011) Pamela G. Alsabeh et al.   CHEMICAL COMMUNICATIONS

Update 1 of: Synthesis and Functionalization of Indoles Through Palladium-Catalyzed Reactions

(2011) Sandro Cacchi et al.   CHEMICAL REVIEWS

Rational and Predictable Chemoselective Synthesis of Oligoamines via Buchwald–Hartwig Amination of (Hetero)Aryl Chlorides Employing Mor-DalPhos

(2011) Bennett J. Tardiff et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed C,N-Cross Coupling Reactions of 3-Halo-2-aminopyridines

(2011) Felix Perez et al.   ORGANIC LETTERS

Mild Pd-CatalyzedN-Arylation of Methanesulfonamide and Related Nucleophiles: Avoiding Potentially Genotoxic Reagents and Byproducts

(2011) Brandon R. Rosen et al.   ORGANIC LETTERS

A New Biarylphosphine Ligand for the Pd-Catalyzed Synthesis of Diaryl Ethers under Mild Conditions

(2011) Luca Salvi et al.   ORGANIC LETTERS

Kilogram-Lab-Scale Oxindole Synthesis via Palladium-Catalyzed C–H Functionalization

(2011) E. Jason Kiser et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Indole synthesis: a review and proposed classification

(2011) Douglass F. Taber et al.   TETRAHEDRON

Application of 6,7-Indole Aryne Cycloaddition and Pd(0)-Catalyzed Suzuki–Miyaura and Buchwald–Hartwig Cross-Coupling Reactions for the Preparation of Annulated Indole Libraries

(2011) Paul D. Thornton et al.   ACS Combinatorial Science

Palladium-Catalyzed Cross-Coupling of Aryl Chlorides and Tosylates with Hydrazine

(2010) Rylan J. Lundgren et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A P,N-Ligand for Palladium-Catalyzed Ammonia Arylation: Coupling of Deactivated Aryl Chlorides, Chemoselective Arylations, and Room Temperature Reactions

(2010) Rylan J. Lundgren et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Organometallic Reactions of Ammonia

(2010) Jessica L. Klinkenberg et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct amination of aryl halides with ammonia

(2010) Yoann Aubin et al.   CHEMICAL SOCIETY REVIEWS

Advances in selective activation and application of ammonia in homogeneous catalysis

(2010) Jarl Ivar van der Vlugt   CHEMICAL SOCIETY REVIEWS

A General and Efficient Catalyst for Palladium-Catalyzed C−O Coupling Reactions of Aryl Halides with Primary Alcohols

(2010) Saravanan Gowrisankar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Multiligand Based Pd Catalyst for C−N Cross-Coupling Reactions

(2010) Brett P. Fors et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Slow Reductive Elimination from Arylpalladium Parent Amido Complexes

(2010) Jessica L. Klinkenberg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Pd-Catalyzed Amination Reactions for Heterocycle Functionalization

(2010) Jaclyn L. Henderson et al.   ORGANIC LETTERS

Pd-Catalyzed Cross-Coupling Reactions of Amides and Aryl Mesylates

(2010) Karin Dooleweerdt et al.   ORGANIC LETTERS

Synthesis of N-arylhydroxylamines by Pd-catalyzed coupling

(2010) Daniel Beaudoin et al.   TETRAHEDRON LETTERS

Palladium-catalyzed coupling of functionalized primary and secondary amines with aryl and heteroaryl halides: two ligands suffice in most cases

(2010) Debabrata Maiti et al.   Chemical Science

Dialkylbiaryl phosphines in Pd-catalyzed amination: a user's guide

(2010) David S. Surry et al.   Chemical Science

Recent Applications of Palladium-Catalyzed Coupling Reactions in the Pharmaceutical, Agrochemical, and Fine Chemical Industries

(2009) Christian Torborg et al.   ADVANCED SYNTHESIS & CATALYSIS

Expedient Synthesis of N-Fused Indoles: A CF Activation and CH Insertion Approach

(2009) Kohei Fuchibe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemoselectivity and the Curious Reactivity Preferences of Functional Groups

(2009) Nicholas A. Afagh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Highly Versatile Catalyst System for the Cross-Coupling of Aryl Chlorides and Amines

(2009) Rylan J. Lundgren et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of a TRPV1 Receptor Antagonist

(2009) Su Yu et al.   JOURNAL OF ORGANIC CHEMISTRY

Pd-Catalyzed N-Arylation of Secondary Acyclic Amides: Catalyst Development, Scope, and Computational Study

(2009) Jacqueline D. Hicks et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Coupling of Ammonia with Aryl Chlorides, Bromides, Iodides, and Sulfonates: A General Method for the Preparation of Primary Arylamines

(2009) Giang D. Vo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A General Method for the Synthesis of Unsymmetrically Substituted Ureas via Palladium-Catalyzed Amidation

(2009) Brian J. Kotecki et al.   ORGANIC LETTERS

Formation of ArF from LPdAr(F): Catalytic Conversion of Aryl Triflates to Aryl Fluorides

(2009) D. A. Watson et al.   SCIENCE

Thieme Chemistry Journal Awardees - Where Are They Now? Palladium-Catalyzed N-Arylation-Hydroamination Sequence for the Synthesis of Indoles with Sterically Demanding N-Substituents

(2009) Lutz Ackermann et al.   SYNLETT

An efficient system for the Pd-catalyzed cross-coupling of amides and aryl chlorides

(2009) Brett P. Fors et al.   TETRAHEDRON

Palladium-catalyzed sequential indole synthesis using sterically hindered amines

(2009) Lutz Ackermann et al.   TETRAHEDRON

Evolution of a Fourth Generation Catalyst for the Amination and Thioetherification of Aryl Halides

(2008) John F. Hartwig   ACCOUNTS OF CHEMICAL RESEARCH

Biaryl Phosphane Ligands in Palladium-Catalyzed Amination

(2008) David S. Surry et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Highly Active Catalyst for Pd-Catalyzed Amination Reactions: Cross-Coupling Reactions Using Aryl Mesylates and the Highly Selective Monoarylation of Primary Amines Using Aryl Chlorides

(2008) Brett P. Fors et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Development of a practical Buchwald–Hartwig amine arylation protocol using a conveniently prepared (NHC)Pd(R-allyl)Cl catalyst

(2008) Mark J. Cawley et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

[(CyPF-tBu)PdCl2]: An Air-Stable, One-Component, Highly Efficient Catalyst for Amination of Heteroaryl and Aryl Halides

(2008) Qilong Shen et al.   ORGANIC LETTERS

Water-Mediated Catalyst Preactivation: An Efficient Protocol for C−N Cross-Coupling Reactions

(2008) Brett P. Fors et al.   ORGANIC LETTERS

Palladium-Catalyzed Coupling of Hydroxylamines with Aryl Bromides, Chlorides, and Iodides

(2008) Achim Porzelle et al.   ORGANIC LETTERS

Streamlined Synthesis of the Bippyphos Family of Ligands and Cross-Coupling Applications

(2008) Gregory J. Withbroe et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Simple Indole Synthesis by One-Pot Sonogashira Coupling-NaOH-Mediated Cyclization

(2008) Roberto Sanz et al.   SYNLETT

Preparation of Fully Substituted Anilines for the Synthesis of Functionalized Indoles

(2007) Armin H. Stoll et al.   ORGANIC LETTERS