Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 14, Issue 37, Pages 8641-8647Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ob01214k
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Funding
- NIH [NIGMS R01-GM079554]
- Welch Foundation [I-1868]
- UT Southwestern
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Photoexcited ketones have diradical characteristics and are functionally similar to high-spin metal-oxo species that are frequently used to catalyze C-H oxidation. First discovered by Yang in 1958, photoexcited ketones can abstract a hydrogen atom from hydrocarbons inter-or intramolecularly. Coupling with atom-transfer, group-transfer, or radical addition, the Yang reaction can be used to achieve various types of C-H functionalization. We provide in this article an overview of triplet ketone-mediated or catalyzed C-H functionalization reactions.
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