期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 14, 期 37, 页码 8641-8647出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ob01214k
关键词
-
资金
- NIH [NIGMS R01-GM079554]
- Welch Foundation [I-1868]
- UT Southwestern
Photoexcited ketones have diradical characteristics and are functionally similar to high-spin metal-oxo species that are frequently used to catalyze C-H oxidation. First discovered by Yang in 1958, photoexcited ketones can abstract a hydrogen atom from hydrocarbons inter-or intramolecularly. Coupling with atom-transfer, group-transfer, or radical addition, the Yang reaction can be used to achieve various types of C-H functionalization. We provide in this article an overview of triplet ketone-mediated or catalyzed C-H functionalization reactions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据