Synthesis of Chiral Tertiary Alcohols by CuI-Catalyzed Enantioselective Addition of Organomagnesium Reagents to Ketones

Asymmetric Addition of Pyridyl Aluminum Reagents to Aldehydes Catalyzed by a Titanium(IV) Catalytic System of (R)-H8-BINOLate

(2015) Lijun Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective titanium-promoted 1,2-additions of carbon nucleophiles to carbonyl compounds

(2015) Hélène Pellissier   TETRAHEDRON

Catalytic Asymmetric Alkylation of Acylsilanes

(2014) Jiawei Rong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of (R,R,R)-γ-Tocopherol through Cu-Catalyzed Asymmetric 1,2-Addition

(2014) Zhongtao Wu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Asymmetric Alkylation of Aryl Heteroaryl Ketones

(2014) Pablo Ortiz et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Catalytic Enantioselective Addition of Aryl Grignard Reagents to Ketones

(2014) Emilio Fernández-Mateos et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Aryl Bromides as Inexpensive Starting Materials in the Catalytic Enantioselective Arylation of Aryl Aldehydes: The Additive TMEDA Enhances the Enantioselectivity

(2014) Yong-Xin Yang et al.   JOURNAL OF ORGANIC CHEMISTRY

Discussion Addendum for: Applications of (2S)-(-)-3-exo-Morpholinoisoborneol [(-)MIB] in Organic Synthesis

(2014)   ORGANIC SYNTHESES

Synthesis of new derivatives of copper complexes of Josiphos family ligands for applications in asymmetric catalysis

(2014) R. Oost et al.   Catalysis Science & Technology

Catalytic Enantioselective Addition of Alkyl Grignard Reagents to Aliphatic Aldehydes

(2013) Emilio Fernández-Mateos et al.   ADVANCED SYNTHESIS & CATALYSIS

The X-ray Crystal Structure of a Cuprate-Carbonyl π-Complex

(2013) Steven H. Bertz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

One-Pot Zinc-Promoted Asymmetric Alkynylation/Brook-Type Rearrangement/Ene-Allene Cyclization: Highly Selective Formation of Three New Bonds and Two Stereocenters in Acyclic Systems

(2013) Polina Smirnov et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Addition of Nucleophilic Silicon to Aldehydes

(2013) Virginie Cirriez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hybridisation at the organic–metal interface: a surface-scientific analogue of Hückel's rule?

(2013) Hasmik Harutyunyan et al.   CHEMICAL COMMUNICATIONS

Asymmetric amplification in the catalytic enantioselective 1,2-addition of Grignard reagents to enones

(2013) Francesca Caprioli et al.   CHEMICAL COMMUNICATIONS

Catalytic Enantioselective Alkylation of Aldehydes by Using Organozinc Halide Reagents

(2013) Yuichiro Kinoshita et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Asymmetric Synthesis of Dihydrofurans and Cyclopentenols with Tertiary Stereocenters

(2013) Zhongtao Wu et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Aldehydes and Ketones Form Intermediate π Complexes with the Gilman Reagent, Me2CuLi, at Low Temperatures in Tetrahydrofuran

(2013) Steven H. Bertz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral 1,1-diaryl compounds as important pharmacophores

(2013) Dana Ameen et al.   MedChemComm

Asymmetric Copper-Catalyzed Addition of Grignard Reagents to Aryl Alkyl Ketones

(2012) Ashoka V. R. Madduri et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium and copper-catalyzed asymmetric conjugate addition of alkenyl nucleophiles

(2012) Daniel Müller et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed Asymmetric Conjugate Addition to Challenging Michael Acceptors and Synthesis of Relevant Target Molecules

(2012) Ludovic Gremaud et al.   CHIMIA

Rapid Injection NMR Reveals η3 ‘π-Allyl’ CuIII Intermediates in Addition Reactions of Organocuprate Reagents

(2012) Steven H. Bertz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Histamine-1 receptor antagonism for treatment of insomnia

(2012) Joseph P. Vande Griend et al.   JOURNAL OF THE AMERICAN PHARMACISTS ASSOCIATION

Access to chiral α-bromo and α-H-substituted tertiary allylic alcohols via copper(i) catalyzed 1,2-addition of Grignard reagents to enones

(2012) Ashoka V. R. Madduri et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhodium(I)/Diene-Catalyzed Addition Reactions of Arylborons with Ketones

(2012) Yuan-Xi Liao et al.   ORGANIC LETTERS

Synthesis and Application of 2,6-Bis(trifluoromethyl)-4-pyridyl Phosphanes: The Most Electron-Poor Aryl Phosphanes with Moderate Bulkiness

(2011) Toshinobu Korenaga et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper(i) catalyzed asymmetric 1,2-addition of Grignard reagents to α-methyl substituted α,β-unsaturated ketones

(2011) Ashoka V. R. Madduri et al.   CHEMICAL COMMUNICATIONS

Mechanisms of Nucleophilic Organocopper(I) Reactions

(2011) Naohiko Yoshikai et al.   CHEMICAL REVIEWS

Catalytic Enantioselective Allylation of Carbonyl Compounds and Imines

(2011) Miguel Yus et al.   CHEMICAL REVIEWS

Highly Enantioselective Synthesis of Tertiary Boronic Esters and their Stereospecific Conversion to other Functional Groups and Quaternary Stereocentres

(2011) Helen K. Scott et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Enantioselective Addition of MeMgBr and Other Grignard Reagents to Aldehydes

(2011) Emilio Fernández-Mateos et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

A General Copper–BINAP-Catalyzed Asymmetric Propargylation of Ketones with Propargyl Boronates

(2011) Keith R. Fandrick et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Addition of Arylboronic Acids to Isatins usingC2-Symmetric CationicN-Heterocyclic Carbenes (NHCs) Pd2+Diaqua Complexes as Catalysts

(2011) Zhen Liu et al.   ORGANIC LETTERS

Asymmetric Addition of Diorganozinc Reagents to Aldehydes and Ketones

(2011) Caitlin M. Binder et al.   ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL

Catalytic Enantioselective Alkylation and Arylation of Aldehydes by Using Grignard Reagents

(2010) Yusuke Muramatsu et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Catalytic enantioselective synthesis of sterically demanding alcohols using di(2°-alkyl)zinc prepared by the refined Charette's method

(2010) Manabu Hatano et al.   CHEMICAL COMMUNICATIONS

Zinc(ii)-catalyzed Grignard additions to ketones with RMgBr and RMgI

(2010) Manabu Hatano et al.   CHEMICAL COMMUNICATIONS

Serendipity strikes again—efficient preparation of lithium tetramethylcuprate(iii) via rapid injection NMR

(2010) Erika R. Bartholomew et al.   CHEMICAL COMMUNICATIONS

Organocuprate(iii) chemistry: synthesis and reactivity of amido, cyano, phosphido and thiolato ate complexes of copper(iii)

(2010) Steven H. Bertz et al.   CHEMICAL COMMUNICATIONS

Metal-catalyzed asymmetric conjugate addition reaction: formation of quaternary stereocenters

(2010) Christine Hawner et al.   CHEMICAL COMMUNICATIONS

Zinc(II)-Catalyzed Addition of Grignard Reagents to Ketones

(2010) Manabu Hatano et al.   JOURNAL OF ORGANIC CHEMISTRY

CuH-Catalyzed Enantioselective 1,2-Reductions of α,β-Unsaturated Ketones

(2010) Ralph Moser et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Aerobic Oxidative Functionalization of an Arene C−H Bond: Evidence for an Aryl-Copper(III) Intermediate

(2010) Amanda E. King et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Brønsted Acid Catalyzed Asymmetric Reduction of Ketones and Acyl Silanes Using Chiralanti-Pentane-2,4-diol

(2010) Jun-ichi Matsuo et al.   ORGANIC LETTERS

Nonlinear Effects in Asymmetric Catalysis

(2009) Tummanapalli Satyanarayana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances in enantioselective copper-catalyzed 1,4-addition

(2009) Thomas Jerphagnon et al.   CHEMICAL SOCIETY REVIEWS

Mechanistic Study of Copper-Catalyzed Aerobic Oxidative Coupling of Arylboronic Esters and Methanol: Insights into an Organometallic Oxidase Reaction

(2009) Amanda E. King et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantio- and Diastereoselective Tandem Zn-Promoted Brook Rearrangement/Ene−Allene Carbocyclization Reaction

(2009) Rozalia Unger et al.   ORGANIC LETTERS

Asymmetric addition of achiral organomagnesium reagents or organolithiums to achiral aldehydes or ketones: a review

(2009) Matthew R. Luderer et al.   TETRAHEDRON-ASYMMETRY

A New Aspect of Magnesium Bromide‐Promoted Enantioselective Aryl Additions of Triaryl(tetrahydrofuran)aluminum to Ketones Catalyzed by a Titanium(IV) Catalyst oftrans‐1,2‐Bis(hydroxycamphorsulfonylamino)cyclohexane

(2008) Chien‐An Chen et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Hydrogenation of Aromatic, Aliphatic, and α,β-Unsaturated Acyl Silanes Catalyzed by Tol-binap/Pica Ruthenium(II) Complexes: Practical Synthesis of Optically Active α-Hydroxysilanes

(2008) Noriyoshi Arai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Alkylation of Aldehydes with Grignard Reagents

(2008) Yusuke Muramatsu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Neutral organocopper(iii) complexes

(2008) Erika R. Bartholomew et al.   CHEMICAL COMMUNICATIONS

Catalytic enantioselective organozinc addition toward optically active tertiary alcohol synthesis

(2008) Manabu Hatano et al.   CHEMICAL RECORD

Catalytic Asymmetric Conjugate Addition and Allylic Alkylation with Grignard Reagents

(2008) Syuzanna R. Harutyunyan et al.   CHEMICAL REVIEWS

Asymmetric Synthesis of Tertiary Alcohols and α-Tertiary Amines via Cu-Catalyzed C−C Bond Formation to Ketones and Ketimines

(2008) Masakatsu Shibasaki et al.   CHEMICAL REVIEWS

Enantioselective Copper-Catalyzed Conjugate Addition and Allylic Substitution Reactions

(2008) A. Alexakis et al.   CHEMICAL REVIEWS

Catalytic Asymmetric Aryl Transfer Reactions to Aldehydes with Grignard Reagents as the Aryl Source

(2008) Yusuke Muramatsu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Theoretical Insights into Enantioselective Catalysis: The Mechanism of the Kharasch-Sosnovsky Reaction

(2008) José Antonio Mayoral et al.   CHEMISTRY-A EUROPEAN JOURNAL

Preparation of σ- and π-Allylcopper(III) Intermediates in SN2 and SN2′ Reactions of Organocuprate(I) Reagents with Allylic Substrates

(2008) Erika R. Bartholomew et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantiodivergent conversion of chiral secondary alcohols into tertiary alcohols

(2008) Jake L. Stymiest et al.   NATURE