σ-Insertive Mechanism versus Concerted Non-insertive Mechanism in the Intramolecular Hydroamination of Aminoalkenes Catalyzed by Phenoxyamine Magnesium Complexes: A Synthetic and Computational Study

Well-Defined Four-Coordinate Iron(II) Complexes For Intramolecular Hydroamination of Primary Aliphatic Alkenylamines

(2014) Elise Bernoud et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cyclohydroamination of Aminoalkenes Catalyzed by Disilazide Alkaline-Earth Metal Complexes: Reactivity Patterns and Deactivation Pathways

(2013) Bo Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Heteroleptic Alkyl and Amide Iminoanilide Alkaline Earth and Divalent Rare Earth Complexes for the Catalysis of Hydrophosphination and (Cyclo)Hydroamination Reactions

(2013) Bo Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Enantioselective Zirconium-Catalyzed Cyclization of Aminoalkenes

(2013) Kuntal Manna et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

2-Aminopyridinate Titanium Complexes for the Catalytic Hydroamination of Primary Aminoalkenes

(2013) Eugene Chong et al.   ORGANOMETALLICS

C1-Symmetric Rare-Earth-Metal Aminodiolate Complexes for Intra- and Intermolecular Asymmetric Hydroamination of Alkenes

(2013) Alexander L. Reznichenko et al.   ORGANOMETALLICS

When Bigger Is Better: Intermolecular Hydrofunctionalizations of Activated Alkenes Catalyzed by Heteroleptic Alkaline Earth Complexes

(2012) Bo Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Calcium amido-bisoxazoline complexes in asymmetric hydroamination/cyclisation catalysis

(2012) Tracy D. Nixon et al.   CHEMICAL COMMUNICATIONS

Heteroleptic Silylamido Phenolate Complexes of Calcium and the Larger Alkaline Earth Metals: β-Agostic Ae⋅⋅⋅SiH Stabilization and Activity in the Ring-Opening Polymerization ofL-Lactide

(2012) Bo Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chiral Benzamidinate Ligands in Rare-Earth-Metal Coordination Chemistry

(2012) Paul Benndorf et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanistic elucidation of the yttrium(iii)-catalysed intramolecular aminoalkene hydroamination: DFT favours a stepwise σ-insertive mechanism

(2012) Sven Tobisch   DALTON TRANSACTIONS

Intramolecular Aminoalkene Hydroamination Mediated by a Tethered Bis(ureate)zirconium Complex: Computational Perusal of Various Pathways for Aminoalkene Activation

(2012) Sven Tobisch   INORGANIC CHEMISTRY

Iridium-Catalyzed Intermolecular Hydroamination of Unactivated Aliphatic Alkenes with Amides and Sulfonamides

(2012) Christo S. Sevov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diamido-Ether Actinide Complexes as Catalysts for the Intramolecular Hydroamination of Aminoalkenes

(2012) Cassandra E. Hayes et al.   ORGANOMETALLICS

Intermolecular Rhodium-Catalysed Hydroamination of Non-Activated Olefins: Effect of Olefin, Amine, Phosphine and Phosphonium Salt

(2012) Mireia Rodriguez-Zubiri et al.   ChemPlusChem

Assembling Zirconium and Calcium Moieties through an Oxygen Center for an Intramolecular Hydroamination Reaction: A Single System for Double Activation

(2011) Arup Mukherjee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Chiral Phenoxyamine Magnesium Catalyst for the Enantioselective Hydroamination/Cyclization of Aminoalkenes and Intermolecular Hydroamination of Vinyl Arenes

(2011) Xiaoming Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral calcium catalysts for asymmetric hydroamination/cyclisation

(2011) James S. Wixey et al.   CHEMICAL COMMUNICATIONS

Does a Concerted Non-Insertive Mechanism Prevail over a σ-Insertive Mechanism in Catalytic Cyclohydroamination by Magnesium Tris(oxazolinyl)phenylborate Compounds? A Computational Study

(2011) Sven Tobisch   CHEMISTRY-A EUROPEAN JOURNAL

Modular ligand variation in calcium bisimidazoline complexes: effects on ligand redistribution and hydroamination catalysis

(2011) James S. Wixey et al.   DALTON TRANSACTIONS

Synthesis and catalytic activity of group 5 metal amides with chiral biaryldiamine-based ligands

(2011) Furen Zhang et al.   DALTON TRANSACTIONS

Easy Routes towards Chiral Lithium Binaphthylamido Catalysts for the Asymmetric Hydroamination of Amino-1,3-dienes and Aminoalkenes

(2011) Julia Deschamp et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Effect of the damping function in dispersion corrected density functional theory

(2011) Stefan Grimme et al.   JOURNAL OF COMPUTATIONAL CHEMISTRY

Catalytic, Enantioselective Intramolecular Hydroamination of Primary Amines Tethered to Di- and Trisubstituted Alkenes

(2011) Yulia Chapurina et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium Phosphine−π-Arene Intermediates in the Hydroamination of Alkenes

(2011) Zhijian Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Elucidation of Intramolecular Aminoalkene Hydroamination Catalyzed by a Tethered Bis(ureate) Complex: Evidence for Proton-Assisted C–N Bond Formation at Zirconium

(2011) David C. Leitch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Heavier Alkaline Earth Catalysts for the Intermolecular Hydroamination of Vinylarenes, Dienes, and Alkynes

(2011) Christine Brinkmann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cyclopentadienylphosphazene (CpPN) Complexes of Rare-Earth Metals: Synthesis, Structural Characterization, and Hydroamination Catalysis

(2011) Noa K. Hangaly et al.   ORGANOMETALLICS

Cation Charge Density and Precatalyst Selection in Group 2-Catalyzed Aminoalkene Hydroamination

(2011) Merle Arrowsmith et al.   ORGANOMETALLICS

Suppression of Schlenk Equilibration and Heavier Alkaline Earth Alkyl Catalysis: A Dearomatization Strategy

(2011) Merle Arrowsmith et al.   ORGANOMETALLICS

2,5-Bis{N-(2,6-diisopropylphenyl)iminomethyl}pyrrolyl Complexes of the Heavy Alkaline Earth Metals: Synthesis, Structures, and Hydroamination Catalysis

(2011) Jelena Jenter et al.   ORGANOMETALLICS

Group 5 Metal Binaphtholate Complexes for Catalytic Asymmetric Hydroaminoalkylation and Hydroamination/Cyclization

(2011) Alexander L. Reznichenko et al.   ORGANOMETALLICS

Concerted C–N/C–H Bond Formation in Highly Enantioselective Yttrium(III)-Catalyzed Hydroamination

(2011) Kuntal Manna et al.   ACS Catalysis

Alkaline Earth Metal Catalysts for Asymmetric Reactions

(2010) Shu̅  Kobayashi et al.   ACCOUNTS OF CHEMICAL RESEARCH

Asymmetric Intermolecular Hydroamination of Unactivated Alkenes with Simple Amines

(2010) Alexander L. Reznichenko et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium- and Iridium-Catalyzed Hydroamination of Alkenes

(2010) Kevin D. Hesp et al.   ChemCatChem

Enantioselective Intramolecular Hydroamination of Secondary Amines Catalyzed by Easily Accessible Ate and Neutral Rare-Earth Complexes

(2010) Clémence Queffelec et al.   ChemCatChem

From Limestone to Catalysis: Application of Calcium Compounds as Homogeneous Catalysts

(2010) Sjoerd Harder   CHEMICAL REVIEWS

Mechanistic Investigation of Organolanthanide-Mediated Hydroamination of Conjugated Aminodienes: A Comprehensive Computational Assessment of Various Routes for Diene Activation

(2010) Sven Tobisch   CHEMISTRY-A EUROPEAN JOURNAL

Discrete, Base-Free, Cationic Alkaline-Earth Complexes - Access and Catalytic Activity in the Polymerization of Lactide

(2010) Yann Sarazin et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis, Characterization, and Catalytic Studies of (Aryloxido)magnesium Complexes

(2010) Jolanta Ejfler et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu

(2010) Stefan Grimme et al.   JOURNAL OF CHEMICAL PHYSICS

Bis(phosphinimino)methanide borohydride complexes of neodymium and scandium

(2010) Jelena Jenter et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Linked bis(β-diketiminato) yttrium and lanthanum complexes as catalysts in asymmetric hydroamination/cyclization of aminoalkenes (AHA)

(2010) Daniela V. Vitanova et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Optically active, bulky tris(oxazolinyl)borato magnesium and calcium compounds for asymmetric hydroamination/cyclization

(2010) Steven R. Neal et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Asymmetric hydroamination/cyclization catalyzed by group 4 metal complexes with chiral biaryl-based ligands

(2010) Guofu Zi   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Intramolecular enantioselective hydroamination catalyzed by rare earth binaphthylamides

(2010) Jérôme Hannedouche et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Concerted C−N and C−H Bond Formation in a Magnesium-Catalyzed Hydroamination

(2010) James F. Dunne et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular Hydroamination of Unbiased and Functionalized Primary Aminoalkenes Catalyzed by a Rhodium Aminophosphine Complex

(2010) Lisa D. Julian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Catalytic Cyclohydroamination by Zirconium Salicyloxazoline Complexes

(2010) Laura E. N. Allan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular Aminoalkene Hydroamination Catalyzed by Magnesium Complexes Containing Multidentate Phenoxyamine Ligands

(2010) Xiaoming Zhang et al.   ORGANOMETALLICS

Inter- and Intramolecular Hydroamination with a Uranium Dialkyl Precursor

(2010) Erin M. Broderick et al.   ORGANOMETALLICS

Heterofunctionalization catalysis with organometallic complexes of calcium, strontium and barium

(2010) A. G. M. Barrett et al.   PROCEEDINGS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES

Catalytic synthesis of amines and N-containing heterocycles: Amidate complexes for selective C–N and C–C bond-forming reactions

(2010) Patrick Eisenberger et al.   PURE AND APPLIED CHEMISTRY

Diethylzinc: A Simple and Efficient Catalyst for the Swift Hydroamination at Room Temperature

(2009) Jens-Wolfgang Pissarek et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium-Catalyzed Asymmetric Intramolecular Hydroamination of Unactivated Alkenes

(2009) Xiaoqiang Shen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Kinetic Resolution of Aminoalkenes by Asymmetric Hydroamination: A Mechanistic Study

(2009) Alexander L. Reznichenko et al.   CHEMISTRY-A EUROPEAN JOURNAL

Versatile catalytic systems based on complexes of zinc, magnesium and calcium supported by a bulky bis(morpholinomethyl)phenoxy ligand for the large-scale immortal ring-opening polymerisation of cyclic esters

(2009) Valentin Poirier et al.   DALTON TRANSACTIONS

Asymmetric hydroamination/cyclization catalyzed by organolanthanide complexes with chiral biaryl-based ligands

(2009) Guofu Zi   DALTON TRANSACTIONS

Heavier Group 2 Metals and Intermolecular Hydroamination: A Computational and Synthetic Assessment

(2009) Anthony G. M. Barrett et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular Hydroamination of Aminoalkenes by Calcium and Magnesium Complexes: A Synthetic and Mechanistic Study

(2009) Mark R. Crimmin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intermolecular Hydroamination of Ethylene and 1-Alkenes with Cyclic Ureas Catalyzed by Achiral and Chiral Gold(I) Complexes

(2009) Zhibin Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

[Ir(COD)Cl]2as a Catalyst Precursor for the Intramolecular Hydroamination of Unactivated Alkenes with Primary Amines and Secondary Alkyl- or Arylamines: A Combined Catalytic, Mechanistic, and Computational Investigation

(2009) Kevin D. Hesp et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bis- and Mono(amidate) Complexes of Yttrium: Synthesis, Characterization, and Use as Precatalysts for the Hydroamination of Aminoalkenes

(2009) Louisa J. E. Stanlake et al.   ORGANOMETALLICS

Monoalkyllanthanide Complexes with New β-Diketiminato Derivative Dianionic Ligands

(2009) Erli Lu et al.   ORGANOMETALLICS

Phenylene-Bridged Binuclear Organolanthanide Complexes as Catalysts for Intramolecular and Intermolecular Hydroamination

(2009) Holming F. Yuen et al.   ORGANOMETALLICS

Bis(imidazolin-2-ylidene-1-yl)borate Complexes of the Heavier Alkaline Earths: Synthesis and Studies of Catalytic Hydroamination

(2009) Merle Arrowsmith et al.   ORGANOMETALLICS

Tris(imidazolin-2-ylidene-1-yl)borate Complexes of the Heavier Alkaline Earths: Synthesis and Structural Studies

(2009) Merle Arrowsmith et al.   ORGANOMETALLICS

The Grignard Reagents

(2009) Dietmar Seyferth   ORGANOMETALLICS

C2-Symmetric Zirconium Bis(Amidate) Complexes with Enhanced Reactivity in Aminoalkene Hydroamination

(2009) Alexander L. Reznichenko et al.   ORGANOMETALLICS

Intramolecular hydroamination/cyclization of aminoalkenes catalyzed by diamidobinaphthyl magnesium- and zinc-complexes

(2009) Patricia Horrillo-Martínez et al.   TETRAHEDRON LETTERS

Hydroamination: Direct Addition of Amines to Alkenes and Alkynes

(2008) Thomas E. Müller et al.   CHEMICAL REVIEWS

Mechanism of the Intramolecular Hydroamination of Alkenes Catalyzed by Neutral Indenyltitanium Complexes: A DFT Study

(2008) Carsten Müller et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rare Earth and Alkaline Earth Metal Complexes with Me2Si-Bridged Cyclopentadienyl-Imidazolin-2-Imine Ligands and Their Use as Constrained-Geometry Hydroamination Catalysts

(2008) Tarun K. Panda et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Neutral Group-IV Metal Catalysts for the Intramolecular Hydroamination of Alkenes

(2008) Carsten Müller et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Triazenide Complexes of the Heavier Alkaline Earths: Synthesis, Characterization, And Suitability for Hydroamination Catalysis

(2008) Anthony G. M. Barrett et al.   INORGANIC CHEMISTRY

Preparation, Characterization, and Catalytic Studies of Magnesium Complexes Supported by NNO-Tridentate Schiff-Base Ligands

(2008) Wen-Chou Hung et al.   INORGANIC CHEMISTRY

Mild, Rhodium-Catalyzed Intramolecular Hydroamination of Unactivated Terminal and Internal Alkenes with Primary and Secondary Amines

(2008) Zhijian Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Zinc and enolato-magnesium complexes based on bi-, tri- and tetradentate aminophenolate ligands

(2008) Zhanjiang Zheng et al.   NEW JOURNAL OF CHEMISTRY

Air- and Water-Stable Catalysts for Hydroamination/Cyclization. Synthesis and Application of CCC−NHC Pincer Complexes of Rh and Ir

(2008) Eike B. Bauer et al.   ORGANIC LETTERS

Group-4 Dipyrrolylmethane Complexes in Intramolecular Olefin Hydroamination

(2008) Supriyo Majumder et al.   ORGANOMETALLICS

Sterically Hindered Mono(phosphines) as Supporting Ligands for the Platinum-Catalyzed Hydroamination of Amino Alkenes

(2008) Christopher F. Bender et al.   ORGANOMETALLICS

Chiral Amido Alkyl Rare Earth Complexes: A New Family of Asymmetric Intramolecular Hydroamination Catalysts

(2008) Isabelle Aillaud et al.   ORGANOMETALLICS

Aminotroponiminate Complexes of the Heavy Alkaline Earth and the Divalent Lanthanide Metals as Catalysts for the Hydroamination/Cyclization Reaction

(2008) Simmi Datta et al.   ORGANOMETALLICS

Recent advances in organothorium and organouranium catalysis

(2007) Tamer Andrea et al.   CHEMICAL SOCIETY REVIEWS

Highly efficient, base-catalysed, intramolecular hydroamination of non-activated olefins

(2007) Coralie Quinet et al.   TETRAHEDRON