The Applications of (Para)formaldehyde in Metal-Catalyzed Organic Synthesis

A Metal-Free Approach Toward SaturatedN-Propargyl Heterocycles via an Annulation/Decarboxylative Coupling Sequence

(2015) Huangdi Feng et al.   ADVANCED SYNTHESIS & CATALYSIS

The Retro-Hydroformylation Reaction

(2015) Shuhei Kusumoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Hydroaminocarbonylation of Alkenes with Amines: A Strategy to Overcome the Basicity Barrier Imparted by Aliphatic Amines

(2015) Guoying Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic hydrogen production from paraformaldehyde and water using an organoiridium complex

(2015) Tomoyoshi Suenobu et al.   CHEMICAL COMMUNICATIONS

Transition Metal-free Methylation of Amines with Formaldehyde as the Reductant and Methyl Source

(2015) Nikki Y. T. Man et al.   CHIMIA

Organocatalytic Enantioselective α-Hydroxymethylation of Aldehydes: Mechanistic Aspects and Optimization

(2015) Robert K. Boeckman et al.   JOURNAL OF ORGANIC CHEMISTRY

Accessible protocol for asymmetric hydroformylation of vinylarenes using formaldehyde

(2015) Tsumoru Morimoto et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Asymmetric Pauson–Khand-type reactions of 1,6-enynes using formaldehyde as a carbonyl source by cooperative dual rhodium catalysis

(2015) Takuma Furusawa et al.   TETRAHEDRON

Iron-catalyzed reduction of aromatic aldehydes with paraformaldehyde and H2O as the hydrogen source

(2015) Kishore Natte et al.   TETRAHEDRON LETTERS

Recent advances in the transition metal catalyzed carbonylation of alkynes, arenes and aryl halides using CO surrogates

(2015) Prashant Gautam et al.   Catalysis Science & Technology

Copper(i) iodide catalyzed synthesis of primary propargylic alcohols from terminal alkyne

(2015) Shrishnu Kumar Kundu et al.   RSC Advances

Palladium-Catalyzed Hydroxymethylation of Aryl- and Heteroarylboronic Acids using Aqueous Formaldehyde

(2014) Tetsuya Yamamoto et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium-Catalyzed Carbonylations of Aryl Bromides using Paraformaldehyde: Synthesis of Aldehydes and Esters

(2014) Kishore Natte et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbonylations of Alkenes with CO Surrogates

(2014) Lipeng Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Decarboxylative Cycloaddition of Vinylethylene Carbonates with Formaldehyde: Enantioselective Construction of Tertiary Vinylglycols

(2014) Ajmal Khan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Paraformaldehyde and Methanol as C1 Feedstocks in Metal-Catalyzed CC Couplings of π-Unsaturated Reactants: Beyond Hydroformylation

(2014) Brannon Sam et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium-Catalyzed Alkoxycarbonylation of Alkenes with Paraformaldehyde as a Carbon Monoxide Substitute

(2014) Qiang Liu et al.   ChemCatChem

Free Radical-mediated Hydroxymethylation Using CO and HCHO

(2014) Takuji Kawamoto et al.   CHIMIA

Ruthenium-Catalyzed Conjugate Hydrogenation of α,β-Enones by in situ Generated Dihydrogen from Paraformaldehyde and Water

(2014) Wanfang Li et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Carbonylative Synthesis of Benzoxazinones from N-(o-Bromoaryl)amides Using Paraformaldehyde as the Carbonyl Source

(2014) Wanfang Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Formylation of Amines

(2014) Ciera Gerack et al.   MOLECULES

Palladium-Catalyzed Phthalazinone Synthesis Using Paraformaldehyde as Carbon Source

(2014) Huamin Wang et al.   ORGANIC LETTERS

Carreira Alkynylations with Paraformaldehyde. A Mild and Convenient Protocol for the Hydroxymethylation of Complex Base-Sensitive Terminal Acetylenes via Alkynylzinc Triflates

(2014) Karl J Hale et al.   ORGANIC LETTERS

Selective and mild hydrogen production using water and formaldehyde

(2014) Leo E. Heim et al.   Nature Communications

One-Pot Synthesis of Allylamine Derivatives by Iodine- Catalyzed Three-Component Reaction of N-Heterocycles, Paraformaldehyde and Styrenes

(2013) Zheng-Jun Quan et al.   ADVANCED SYNTHESIS & CATALYSIS

CuI-Catalyzed Synthesis of Functionalized Terminal Allenes from 1-Alkynes

(2013) Hongwen Luo et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Ruthenium Catalyzed Reductive Coupling of Paraformaldehyde to Trifluoromethyl Allenes: CF3-Bearing All-Carbon Quaternary Centers

(2013) Brannon Sam et al.   ORGANIC LETTERS

Palladium-catalyzed hydrodehalogenation of aryl halides using paraformaldehyde as the hydride source: high-throughput screening by paper-based colorimetric iodide sensor

(2013) Ayoung Pyo et al.   TETRAHEDRON LETTERS

Rhodium catalyzed hydroformylation with formaldehyde and an external H2-source

(2013) Marcus Uhlemann et al.   TETRAHEDRON LETTERS

Regiodivergent reductive coupling of 2-substituted dienes to formaldehyde employing ruthenium or nickel catalyst: hydrohydroxymethylation via transfer hydrogenation

(2013) Alexander Köpfer et al.   Chemical Science

Allenes in Catalytic Asymmetric Synthesis and Natural Product Syntheses

(2012) Shichao Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rh(I)-Catalyzed Asymmetric Synthesis of 3-Substituted Isoindolinones through CO Gas-Free Aminocarbonylation

(2012) Masahiko Fujioka et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Vinylation of Aminals with Simple Alkenes: A New Strategy To Construct Allylamines

(2012) Yinjun Xie et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The direct catalytic asymmetric aldol reaction of α-substituted nitroacetates with aqueous formaldehyde under base-free neutral phase-transfer conditions

(2012) Seiji Shirakawa et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Direct N-Acylation of Lactams, Oxazolidinones, and Imidazolidinones with Aldehydes by Shvo’s Catalyst

(2012) Jian Zhang et al.   ORGANIC LETTERS

Molybdenum Hexacarbonyl Mediated CO Gas-Free Carbonylative Reactions

(2012) Luke Odell et al.   SYNLETT

Divergent Regioselectivity in the Synthesis of Trisubstituted Allylic Alcohols by Nickel- and Ruthenium-Catalyzed Alkyne Hydrohydroxymethylation with Formaldehyde

(2011) Cory C. Bausch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

How easy are the syntheses of allenes?

(2011) Shichao Yu et al.   CHEMICAL COMMUNICATIONS

Radical Addition of Alkyl Halides to Formaldehyde in the Presence of Cyanoborohydride as a Radical Mediator. A New Protocol for Hydroxymethylation Reaction

(2011) Takuji Kawamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

(Cyclopentadienone)iron Shvo Complexes: Synthesis and Applications to Hydrogen Transfer Reactions

(2011) Tarn C. Johnson et al.   ORGANOMETALLICS

Hydroxymethylation of α-substituted nitroacetates

(2011) Cong-Bin Ji et al.   TETRAHEDRON LETTERS

Highly Linear-Selective Hydroformylation of 1-Alkenes using Formaldehyde as a Syngas Substitute

(2010) Gouki Makado et al.   ADVANCED SYNTHESIS & CATALYSIS

Direct and efficient N-heterocyclic carbene-catalyzed hydroxymethylation of aldehydes

(2010) Nadine Kuhl et al.   CHEMICAL COMMUNICATIONS

Organocatalytic Enantioselective Hydroxymethylation of Oxindoles with Paraformaldehyde as C1 Unit

(2010) Xiong-Li Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Iridium-catalyzed formylation of amines with paraformaldehyde

(2010) Ourida Saidi et al.   TETRAHEDRON LETTERS

Direct asymmetric α-hydroxymethylation of ketones in homogeneous aqueous solvents

(2010) Monika Pasternak et al.   TETRAHEDRON LETTERS

Organocatalytic α-hydroxymethylation of cyclopentanone with aqueous formaldehyde: Easy access to chiral δ-lactones

(2009) Nobuyuki Mase et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Direct catalytic asymmetric aldol reaction of β-keto esters with formaldehyde promoted by a dinuclear Ni2-Schiff base complex

(2009) Shinsuke Mouri et al.   CHEMICAL COMMUNICATIONS

FeCl3 catalyzed diarylmethanes formations

(2009) Zhong Xian Li et al.   CHINESE CHEMICAL LETTERS

Rapid Access to 3-(Aminomethyl)isoquinoline-Fused Polycyclic Compounds by Copper-Catalyzed Four-Component Coupling, Cascade Cyclization, and Oxidation

(2009) Yusuke Ohta et al.   JOURNAL OF ORGANIC CHEMISTRY

An Efficient Synthesis of Terminal Allenes from Terminal 1-Alkynes

(2009) Jinqiang Kuang et al.   JOURNAL OF ORGANIC CHEMISTRY

Rh(I)-Catalyzed CO Gas-Free Carbonylative Cyclization Reactions of Alkynes with 2-Bromophenylboronic Acids Using Formaldehyde

(2009) Tsumoru Morimoto et al.   ORGANIC LETTERS

An Expedient Three-Component Synthesis of Tertiary Benzylamines

(2009) Erwan Le Gall et al.   SYNTHESIS-STUTTGART

An efficient organocatalyzed multicomponent synthesis of diarylmethanes via Mannich type Friedel–Crafts reaction

(2009) Atul Kumar et al.   TETRAHEDRON LETTERS

A Comparative Study of the 1-Hexene Hydroformylation Either Under Syngas Conditions or with Paraformaldehyde Catalyzed by Rhodium/Diphosphine Systems

(2008) Merlín Rosales et al.   CATALYSIS LETTERS

Facile synthesis of 3-(aminomethyl)isoquinolines by copper-catalysed domino four-component coupling and cyclisation

(2008) Yusuke Ohta et al.   CHEMICAL COMMUNICATIONS

Metal-Containing Ionic Liquids as Efficient Catalysts for Hydroxymethylation in Water

(2008) Katharina Bica et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Ruthenium Catalyzed C−C Bond Formation via Transfer Hydrogenation: Branch-Selective Reductive Coupling of Allenes to Paraformaldehyde and Higher Aldehydes

(2008) Ming-Yu Ngai et al.   ORGANIC LETTERS