Enantioconvergent and regioselective reductive coupling of propargylic esters with chlorogermanes by nickel catalysis

Nickel-catalyzed cross-electrophile C-Ge coupling of benzyl pivalates and chlorogermanes

(2023) Ming-Xiang You et al.   Science China-Chemistry

Ni-Catalyzed Decarboxylative Silylation of Alkynyl Carbonates: Access to Chiral Allenes via Enantiospecific Conversions

(2022) Kun Guo et al.   ORGANIC LETTERS

Nickel‐Catalyzed Reductive C(sp 2 )−Si Coupling of Chlorohydrosilanes via Si−Cl Cleavage

(2022) Zhen‐Zhen Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reductive Cross-Coupling of Unreactive Electrophiles

(2022) Xiaobo Pang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Nickel-Catalyzed, Stereospecific C–C and C–B Cross-Couplings via C–N and C–O Bond Activation

(2021) Jianyu Xu et al.   ACS Catalysis

Ruthenium‐Catalyzed Enantioselective Propargylic Phosphinylation of Propargylic Alcohols with Phosphine Oxides

(2021) Shiyao Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Insertion of Alkynyl Carbenes into Si–H Bonds: An Efficient Access to Chiral Propargylsilanes and Allenylsilanes

(2021) Liang-Liang Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel‐Catalyzed Reductive C−Ge Coupling of Aryl/Alkenyl Electrophiles with Chlorogermanes

(2021) Pei‐Feng Su et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-Catalyzed Enantiospecific Dynamic Kinetic Cross-Electrophile Vinylation of Allylic Alcohols with Vinyl Triflates

(2021) Wei-Yuan Ma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni/Chiral Sodium Carboxylate Dual Catalyzed Asymmetric O-Propargylation

(2021) Xianghong Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Multisubstituted Allenes via Nickel-Catalyzed Cross-Electrophile Coupling

(2021) Youxiang Jin et al.   ACS Catalysis

Catalyst-controlled doubly enantioconvergent coupling of racemic alkyl nucleophiles and electrophiles

(2020) Haohua Huo et al.   SCIENCE

Mechanisms of Nickel-Catalyzed Coupling Reactions and Applications in Alkene Functionalization

(2020) Justin Diccianni et al.   ACCOUNTS OF CHEMICAL RESEARCH

Pd-Catalyzed Enantioselective Syntheses of Trisubstituted Allenes via Coupling of Propargylic Benzoates with Organoboronic Acids

(2020) Huanan Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoinduction in Metallaphotoredox Catalysis

(2020) Alexander Lipp et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Enantioselective Reductive Cross-Coupling Reactions

(2020) Kelsey E. Poremba et al.   ACS Catalysis

Application of Trimethylgermanyl-Substituted Bisphosphine Ligands with Enhanced Dispersion Interactions to Copper-Catalyzed Hydroboration of Disubstituted Alkenes

(2020) Yumeng Xi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of α-Chiral Propargylic Silanes by Copper-Catalyzed 1,4-Selective Addition of Silicon Nucleophiles to Enyne-Type α,β,γ,δ-Unsaturated Acceptors

(2020) Wenbin Mao et al.   ORGANIC LETTERS

Dynamic Kinetic Cross-Electrophile Arylation of Benzyl Alcohols by Nickel Catalysis

(2020) Peng Guo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Propargylic Radical Cyanation Enabled by Dual Organophotoredox and Copper Catalysis

(2019) Fu-Dong Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Cross-Electrophile Aryl-Alkenylation of Unactivated Alkenes

(2019) Zhi-Xiong Tian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Investigation of Enantioconvergent Kumada Reactions of Racemic α-Bromoketones Catalyzed by a Nickel/Bis(oxazoline) Complex

(2019) Haolin Yin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Divergent Synthesis of CF3 -Substituted Allenyl Nitriles by Ligand-Controlled Radical 1,2- and 1,4-Addition to 1,3-Enynes

(2018) Fei Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The market of chiral drugs: Chiral switches versus de novo enantiomerically pure compounds

(2018) Andrea Calcaterra et al.   JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS

Nickel-Catalyzed Asymmetric Propargylic Amination of Propargylic Carbonates Bearing an Internal Alkyne Group

(2018) Kouichi Watanabe et al.   ORGANIC LETTERS

Catalytic enantioconvergent coupling of secondary and tertiary electrophiles with olefins

(2018) Zhaobin Wang et al.   NATURE

Quest for Novel Chemical Entities through Incorporation of Silicon in Drug Scaffolds

(2017) Remya Ramesh et al.   JOURNAL OF MEDICINAL CHEMISTRY

Transition-Metal Catalysis of Nucleophilic Substitution Reactions: A Radical Alternative to SN1 and SN2 Processes

(2017) Gregory C. Fu   ACS Central Science

Stereospecific and stereoconvergent cross-couplings between alkyl electrophiles

(2017) Erika L. Lucas et al.   Nature Reviews Chemistry

Rh-Catalyzed Stereospecific Synthesis of Allenes from Propargylic Benzoates and Arylboronic Acids

(2016) Jonathan Ruchti et al.   ORGANIC LETTERS

Dichotomous mechanistic behavior in Narasaka–Heck cyclizations: electron rich Pd-catalysts generate iminyl radicals

(2016) Nicholas J. Race et al.   Chemical Science

Enantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C–C Bonds

(2015) Alan H. Cherney et al.   CHEMICAL REVIEWS

Enantioselective Cross-Coupling of meso-Epoxides with Aryl Halides

(2015) Yang Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Enantioselective Propargylic Etherification of Propargylic Esters with Alcohols

(2015) Kazunari Nakajima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Studies Lead to Dramatically Improved Reaction Conditions for the Cu-Catalyzed Asymmetric Hydroamination of Olefins

(2015) Jeffrey S. Bandar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Cross-Coupling of Photoredox-Generated Radicals: Uncovering a General Manifold for Stereoconvergence in Nickel-Catalyzed Cross-Couplings

(2015) Osvaldo Gutierrez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Asymmetric Reductive Cross-Coupling Between Vinyl and Benzyl Electrophiles

(2014) Alan H. Cherney et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Negishi Arylations of Propargylic Bromides: A Mechanistic Investigation

(2014) Nathan D. Schley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Conquering three-carbon axial chirality of allenes

(2014) Juntao Ye et al.   Organic Chemistry Frontiers

Biological Activity of Organogermanium Compounds (A Review)

(2013) L. G. Menchikov et al.   PHARMACEUTICAL CHEMISTRY JOURNAL

Nickel-Catalyzed Enantioselective Cross-Couplings of Racemic Secondary Electrophiles That Bear an Oxygen Leaving Group

(2012) Alexander J. Oelke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Construction of 1,5-Enynes by Stereospecific Pd-Catalyzed Allyl–Propargyl Cross-Couplings

(2012) Michael J. Ardolino et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Regio- and Chemoselective Single and Double Addition of Nucleophilic Silicon to Propargylic Chlorides and Phosphates

(2012) Chinmoy K. Hazra et al.   ORGANIC LETTERS

Catalytic Asymmetric Propargylation

(2011) Chang-Hua Ding et al.   CHEMICAL REVIEWS

Nickel-Catalyzed Asymmetric Cross-Couplings of Racemic Propargylic Halides with Arylzinc Reagents

(2008) Sean W. Smith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Substitution of Propargylic Carbonates with Diboron: Selective Synthesis of Multisubstituted Allenylboronates

(2008) Hajime Ito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY