Tungsten and molybdenum based polyoxometalates for photo and electrocatalytic carbon dioxide conversion – A critical review

Two POM-based compounds containing Zn-capped Keggin anions as decent heterogeneous catalysts for sulfur oxidation and CO2 cycloaddition reactions

(2022) Yin-Hua Zhu et al.   DALTON TRANSACTIONS

Confining and Highly Dispersing Single Polyoxometalate Clusters in Covalent Organic Frameworks by Covalent Linkages for CO2 Photoreduction

(2022) Meng Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An unprecedented polyoxometalate-encapsulated organo–metallophosphate framework as a highly efficient cocatalyst for CO2 photoreduction

(2022) Ze-Yu Du et al.   Journal of Materials Chemistry A

Syngas Instead of Hydrogen Gas as a Reducing Agent─A Strategy To Improve the Selectivity and Efficiency of Organometallic Catalysts

(2022) Evgeniya Podyacheva et al.   ACS Catalysis

Two 1D Anderson-Type Polyoxometalate-Based Metal–Organic Complexes as Bifunctional Heterogeneous Catalysts for CO2 Photoreduction and Sulfur Oxidation

(2022) Jian-Bo Yang et al.   INORGANIC CHEMISTRY

Ag Nanoparticle-Modified Polyoxometalate-Based Metal–Organic Framework for Enhanced CO2 Photoreduction

(2022) Yu-Ou He et al.   INORGANIC CHEMISTRY

Origin of the Boosting Effect of Polyoxometalates in Photocatalysis: The Case of CO2 Reduction by a Rh-Containing Metal–Organic Framework

(2022) Albert Solé-Daura et al.   ACS Catalysis

Unraveling photocatalytic electron transfer mechanism in polyoxometalate-encapsulated metal-organic frameworks for high-efficient CO2 reduction reaction

(2022) Jing Du et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

Incorporation of Polyoxometalate in Sulfonic Acid‐modified MIL‐101‐Cr for Enhanced CO 2 Photoreduction Activity

(2021) Yue Wang et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Long-Lived Triplet Excited State in a Heterogeneous Modified Carbon Nitride Photocatalyst

(2021) Adam J. Rieth et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Polyoxometalate Interlayered Zinc–Metallophthalocyanine Molecular Layer Sandwich as Photocoupled Electrocatalytic CO2 Reduction Catalyst

(2021) Haozhou Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Making good use of methane to remove oxidized contaminants from wastewater

(2021) Ling-Dong Shi et al.   WATER RESEARCH

A Purely Inorganic Quasi‐Keggin Polyoxometalate for Photocatalytic Conversion of Carbon Dioxide to Carbon Monoxide

(2021) Xiao‐Mei Liu et al.   ChemPlusChem

Molecular Transition Metal Oxide Electrocatalysts for the Reversible Carbon Dioxide–Carbon Monoxide Transformation

(2021) Dima Azaiza‐Dabbah et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hexanuclear nickel-based [P4Mo11O50] with photocatalytic reduction of CO2 activity

(2021) Mingyue Li et al.   INORGANIC CHEMISTRY COMMUNICATIONS

The use of formic acid as a common solvent for electrospinning of hybrid PHB/Soy protein fibers

(2021) D. Budurova et al.   MATERIALS LETTERS

Understanding the Photocatalytic Reduction of CO2 with Heterometallic Molybdenum(V) Phosphate Polyoxometalates in Aqueous Media

(2021) Youven Benseghir et al.   ACS Catalysis

Controlled synthesis of novel Z-scheme iron phthalocyanine/porous WO3 nanocomposites as efficient photocatalysts for CO2 reduction

(2020) Bin Li et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

Heterogeneous photoredox flow chemistry for the scalable organosynthesis of fine chemicals

(2020) Can Yang et al.   Nature Communications

POM‐incorporated CoO nanowires for enhanced photocatalytic syngas production from CO2

(2020) Xun Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reduced polyoxometalates and bipyridine ruthenium complex forming a tunable photocatalytic system for high efficient CO2 reduction

(2020) Jing Du et al.   CHEMICAL ENGINEERING JOURNAL

Heterogeneous Single-Atom Photocatalysts: Fundamentals and Applications

(2020) Chao Gao et al.   CHEMICAL REVIEWS

Co-immobilization of a Rh Catalyst and a Keggin Polyoxometalate in the UiO-67 Zr-Based Metal–Organic Framework: In Depth Structural Characterization and Photocatalytic Properties for CO2 Reduction

(2020) Youven Benseghir et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A SiW11Mn-assisted indium electrocatalyst for carbon dioxide reduction into formate and acetate

(2020) Chunxiang Li et al.   Journal of CO2 Utilization

Adenine-assisted synthesis of functionalized F-Mn-MOF-74 as an efficient catalyst with enhanced catalytic activity for the cycloaddition of carbon dioxide

(2020) Chao Feng et al.   COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS

Stable and Efficient Single-Atom Zn Catalyst for CO2 Reduction to CH4

(2020) Lili Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photochemical In Situ Exfoliation of Metal–Organic Frameworks for Enhanced Visible‐Light‐Driven CO 2 Reduction

(2020) Hui‐Li Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reticular Materials for Artificial Photoreduction of CO 2

(2020) Ha L. Nguyen   Advanced Energy Materials

Stable Dioxin‐Linked Metallophthalocyanine Covalent Organic Frameworks (COFs) as Photo‐Coupled Electrocatalysts for CO 2 Reduction

(2020) Meng Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Polyoxometalate-Based Organic–Inorganic Hybrids as Heterogeneous Catalysts for Cycloaddition of CO2 with Epoxides and Oxidative Desulfurization Reactions

(2020) Yu-Qing Zhao et al.   CRYSTAL GROWTH & DESIGN

Polyoxometalates as electron and proton reservoir assist electrochemical CO2 reduction

(2020) Zhongling Lang et al.   APL Materials

Stable Hierarchical Bimetal-Organic Nanostructures as HighPerformance Electrocatalysts for the Oxygen Evolution Reaction

(2019) Wei Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Modeling the Effect of Cu Doped TiO2 with Carbon Dots on CO2 Methanation by H2O in a Photo-thermal system

(2019) Ke Wang et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

Syngas production by electrocatalytic reduction of CO2 using Ag-decorated TiO2 nanotubes

(2019) M.A. Farkhondehfal et al.   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

Solvent-Free Synthesis of ZIFs: A Route toward the Elusive Fe(II) Analogue of ZIF-8

(2019) Javier López-Cabrelles et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrophobic Polyoxometalate-Based Metal-Organic Framework for Efficient CO2 Photoconversion

(2019) Xiao-Xin Li et al.   ACS Applied Materials & Interfaces

Covalent Organic Frameworks: Chemical Approaches to Designer Structures and Built-in Functions

(2019) Donglin Jiang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dimension-Matched Zinc Phthalocyanine/BiVO4 Ultrathin Nanocomposites for CO2 Reduction as Efficient Wide-Visible-Light-Driven Photocatalysts via a Cascade Charge Transfer

(2019) Ji Bian et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From molecular metal complex to metal-organic framework: The CO2 reduction photocatalysts with clear and tunable structure

(2019) Yu-Hui Luo et al.   COORDINATION CHEMISTRY REVIEWS

Single molecule–mediated assembly of polyoxometalate single-cluster rings and their three-dimensional superstructures

(2019) Qingda Liu et al.   Science Advances

Van der Waals Integrated Hybrid POM‐Zirconia Flexible Belt‐Like Superstructures

(2019) Bilal Akram et al.   ADVANCED MATERIALS

Free-Standing CoO-POM Janus-like Ultrathin Nanosheets

(2019) Bilal Akram et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Efficient Photoreduction of Low‐Concentration CO 2 to Syngas by Using a Polyoxometalates/Ru II Composite

(2019) Hui Xu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Efficient electrochemical reduction of CO2 into formate and acetate in polyoxometalate catholyte with indium catalyst

(2019) Bingjie Zha et al.   JOURNAL OF CATALYSIS

Polyoxometalate-Promoted Electrocatalytic CO2 Reduction at Nanostructured Silver in Dimethylformamide

(2018) Si-Xuan Guo et al.   ACS Applied Materials & Interfaces

Atomically Dispersed Metal Sites in MOF-Based Materials for Electrocatalytic and Photocatalytic Energy Conversion

(2018) Zibin Liang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox performance of Na-modified Fe 2 O 3 /Al 2 O 3 with syngas as reducing agent in chemical looping combustion process

(2018) Wei-Chen Huang et al.   CHEMICAL ENGINEERING JOURNAL

Coordination of Carbon Dioxide to the Lewis Acid Site of a Zinc-Substituted Polyoxometalate and Formation of an Adduct Using a Polyoxometalate-2,4,6-Trimethylpyridine Frustrated Lewis Pair

(2018) Bo Chen et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Assessing the electrocatalytic properties of the {Cp*Rh(III)}2+ Polyoxometalate derivative [H2PW11O39{Rh(III)Cp*(OH2)}]3- towards CO2 reduction

(2018) Marcelo Girardi et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Carbon monoxide as a selective reducing agent in organic chemistry

(2018) Alexey A. Tsygankov et al.   MENDELEEV COMMUNICATIONS

A rare three-dimensional POM-based inorganic polymer bonded by CO2 with high catalytic performance for CO2 cycloaddition

(2018) Yan Xu et al.   CHEMICAL COMMUNICATIONS

Ti-Substituted Keggin-Type Polyoxotungstate as Proton and Electron Reservoir Encaged into Metal-Organic Framework for Carbon Dioxide Photoreduction

(2018) Shu-Mei Liu et al.   Advanced Materials Interfaces

Oriented electron transmission in polyoxometalate-metalloporphyrin organic framework for highly selective electroreduction of CO2

(2018) Yi-Rong Wang et al.   Nature Communications

A Molecular CO2 Reduction Catalyst Based on Giant Polyoxometalate {Mo368}

(2018) Santu Das et al.   Frontiers in Chemistry

Enhancing CO2 Electroreduction with the Metal–Oxide Interface

(2017) Dunfeng Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Climate change effects of forestry and substitution of carbon-intensive materials and fossil fuels

(2017) Leif Gustavsson et al.   RENEWABLE & SUSTAINABLE ENERGY REVIEWS

A hexanuclear cobalt metal–organic framework for efficient CO2 reduction under visible light

(2017) Jiao Zhao et al.   Journal of Materials Chemistry A

Fundamentals and Challenges of Electrochemical CO 2 Reduction Using Two-Dimensional Materials

(2017) Zhenyu Sun et al.   Chem

Photochemical Reduction of CO2 with Visible Light Using a Polyoxometalate as Photoreductant

(2016) Eynat Haviv et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enhanced proton and electron reservoir abilities of polyoxometalate grafted on graphene for high-performance hydrogen evolution

(2016) Rongji Liu et al.   Energy & Environmental Science

Efficient conversion of carbon dioxide at atmospheric pressure to 2-oxazolidinones promoted by bifunctional Cu(ii)-substituted polyoxometalate-based ionic liquids

(2016) Mei-Yan Wang et al.   GREEN CHEMISTRY

Cationic Covalent Organic Frameworks: A Simple Platform of Anionic Exchange for Porosity Tuning and Proton Conduction

(2016) Heping Ma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoreduction Mechanism of CO2 to CO Catalyzed by a Rhenium(I)–Polyoxometalate Hybrid Compound

(2016) Chenggang Ci et al.   ACS Catalysis

Electrons, Photons, Protons and Earth-Abundant Metal Complexes for Molecular Catalysis of CO2 Reduction

(2016) Hiroyuki Takeda et al.   ACS Catalysis

On the general mechanism of photocatalytic reduction of CO2

(2016) Elham Karamian et al.   Journal of CO2 Utilization

Immobilization of polyoxometalates in the Zr-based metal organic framework UiO-67

(2015) William Salomon et al.   CHEMICAL COMMUNICATIONS

Light-Driven Heterogeneous Reduction of Carbon Dioxide: Photocatalysts and Photoelectrodes

(2015) James L. White et al.   CHEMICAL REVIEWS

Recent Advances in Polyoxometalate-Catalyzed Reactions

(2015) Sa-Sa Wang et al.   CHEMICAL REVIEWS

Electrode Build-Up of Reducible Metal Composites toward Achievable Electrochemical Conversion of Carbon Dioxide

(2015) Seunghwa Lee et al.   ChemSusChem

Photocatalytic Carbon Dioxide Reduction with Rhodium-based Catalysts in Solution and Heterogenized within Metal-Organic Frameworks

(2015) Matthew B. Chambers et al.   ChemSusChem

A multi-component polyoxometalate and its catalytic performance for CO2 cycloaddition reactions

(2015) Shumin Chen et al.   DALTON TRANSACTIONS

Electro-Assisted Reduction of CO2to CO and Formaldehyde by (TOA)6[α-SiW11O39Co(_)] Polyoxometalate

(2015) Marcelo Girardi et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Highly efficient conversion of CO 2 at atmospheric pressure to cyclic carbonates with in situ -generated homogeneous catalysts from a copper-containing coordination polymer

(2015) Bo Zou et al.   JOURNAL OF CATALYSIS

Metal–Organic Polymers Containing Discrete Single-Walled Nanotube as a Heterogeneous Catalyst for the Cycloaddition of Carbon Dioxide to Epoxides

(2015) Zhen Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Old Metal Oxide Clusters in New Applications: Spontaneous Reduction of Keggin and Dawson Polyoxometalate Layers by a Metallic Electrode for Improving Efficiency in Organic Optoelectronics

(2015) Maria Vasilopoulou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Crystal Engineering of an nbo Topology Metal-Organic Framework for Chemical Fixation of CO2under Ambient Conditions

(2014) Wen-Yang Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Post-synthetic metalation of metal–organic frameworks

(2014) Jack D. Evans et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in semiconductors for photocatalytic and photoelectrochemical water splitting

(2014) Takashi Hisatomi et al.   CHEMICAL SOCIETY REVIEWS

Discovery of a Ni-Ga catalyst for carbon dioxide reduction to methanol

(2014) Felix Studt et al.   Nature Chemistry

Trends of Syngas as a Fuel in Internal Combustion Engines

(2014) Ftwi Yohaness Hagos et al.   Advances in Mechanical Engineering

Electro and photoelectrochemical reduction of carbon dioxide on multimetallic porphyrins/polyoxotungstate modified electrodes

(2013) Macarena García et al.   ELECTROCHIMICA ACTA

Status and perspectives of CO2 conversion into fuels and chemicals by catalytic, photocatalytic and electrocatalytic processes

(2013) Evgenii V. Kondratenko et al.   Energy & Environmental Science

Metal substitution in a Lindqvist polyoxometalate leads to improved photocatalytic performance

(2012) Johannes Tucher et al.   DALTON TRANSACTIONS

Formic acid as a hydrogen source – recent developments and future trends

(2012) Martin Grasemann et al.   Energy & Environmental Science

CO2 Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu2O Films

(2012) Christina W. Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand design for functional metal–organic frameworks

(2011) Filipe A. Almeida Paz et al.   CHEMICAL SOCIETY REVIEWS

Shape and Composition-Controlled Platinum Alloy Nanocrystals Using Carbon Monoxide as Reducing Agent

(2011) Jianbo Wu et al.   NANO LETTERS

Kinetic and Spectroscopic Studies of the Molybdenum-Copper CO Dehydrogenase fromOligotropha carboxidovorans

(2010) Bo Zhang et al.   JOURNAL OF BIOLOGICAL CHEMISTRY

Photoreduction of Carbon Dioxide to Carbon Monoxide with Hydrogen Catalyzed by a Rhenium(I) Phenanthroline−Polyoxometalate Hybrid Complex

(2010) Jessica Ettedgui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Practical uses of liquid methane in rocket engine applications

(2009) Todd Neill et al.   ACTA ASTRONAUTICA

Electronic Control of Spin Coupling in Keplerate-Type Polyoxomolybdates

(2009) Bogdan Botar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective sulfoxidation of aryl sulfides by coordinatively unsaturated metal centers in chromium carboxylate MIL-101

(2009) Young Kyu Hwang et al.   APPLIED CATALYSIS A-GENERAL

Direct conversion of methane to fuels and chemicals

(2009) Anders Holmen   CATALYSIS TODAY

Photochemical Reduction of Carbon Dioxide Catalyzed by a Ruthenium-Substituted Polyoxometalate

(2009) Alexander M. Khenkin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Electrocatalytic and homogeneous approaches to conversion of CO2to liquid fuels

(2008) Eric E. Benson et al.   CHEMICAL SOCIETY REVIEWS

A CO2/H2O2-tunable reaction: direct conversion of styrene into styrene carbonate catalyzed by sodium phosphotungstate/n-Bu4NBr

(2008) Jing-Lun Wang et al.   GREEN CHEMISTRY

CO2Coordination by Inorganic Polyoxoanion in Water

(2008) Guanggang Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Earth-system perspective of the global nitrogen cycle

(2008) Nicolas Gruber et al.   NATURE