Formic acid as a hydrogen source – recent developments and future trends

CO2-“Neutral” Hydrogen Storage Based on Bicarbonates and Formates

(2011) Albert Boddien et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Charge/Discharge Device for Chemical Hydrogen Storage and Generation

(2011) Gábor Papp et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Interconversion between Formic Acid and H2/CO2 using Rhodium and Ruthenium Catalysts for CO2 Fixation and H2 Storage

(2011) Yuichiro Himeda et al.   ChemSusChem

Hydrogen Generation from Formic Acid Decomposition by Ruthenium Carbonyl Complexes. Tetraruthenium Dodecacarbonyl Tetrahydride as an Active Intermediate

(2011) Miklos Czaun et al.   ChemSusChem

Clean hydrogen generation through the electrocatalytic oxidation of formic acid in a Proton Exchange Membrane Electrolysis Cell (PEMEC)

(2011) Claude Lamy et al.   ELECTROCHIMICA ACTA

Chemical hydrogen storage: ‘material’ gravimetric capacity versus‘system’ gravimetric capacity

(2011) Umit B. Demirci et al.   Energy & Environmental Science

Production of furfural and carboxylic acids from waste aqueous hemicellulose solutions from the pulp and paper and cellulosic ethanol industries

(2011) Rong Xing et al.   Energy & Environmental Science

Selective Decomposition of Formic Acid over Immobilized Catalysts

(2011) Yan Zhao et al.   ENERGY & FUELS

Simple and recyclable ionic liquid based system for the selective decomposition of formic acid to hydrogen and carbon dioxide

(2011) M. E. M. Berger et al.   GREEN CHEMISTRY

Hydrogen production via electrolysis of aqueous formic acid solutions

(2011) W.L. Guo et al.   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

Production of CO-free H2 from formic acid. A comparative study of the catalytic behavior of Pt metals on a carbon support

(2011) F. Solymosi et al.   JOURNAL OF CATALYSIS

Decomposition and Reforming of Formic Acid on Supported Au Catalysts: Production of CO-Free H2

(2011) A. Gazsi et al.   Journal of Physical Chemistry C

Sustainable energy: a review of formic acid electrochemical fuel cells

(2011) Neil V. Rees et al.   JOURNAL OF SOLID STATE ELECTROCHEMISTRY

Synergistic Catalysis of Metal–Organic Framework-Immobilized Au–Pd Nanoparticles in Dehydrogenation of Formic Acid for Chemical Hydrogen Storage

(2011) Xiaojun Gu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Anthropogenic Chemical Carbon Cycle for a Sustainable Future

(2011) George A. Olah et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogen production from formic acid decomposition at room temperature using a Ag–Pd core–shell nanocatalyst

(2011) Karaked Tedsree et al.   Nature Nanotechnology

Efficient Dehydrogenation of Formic Acid Using an Iron Catalyst

(2011) A. Boddien et al.   SCIENCE

ortho-Metalation of Iron(0) Tribenzylphosphine Complexes: Homogeneous Catalysts for the Generation of Hydrogen from Formic Acid

(2010) Albert Boddien et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Production of CO-Free H2 by Formic Acid Decomposition over Mo2C/Carbon Catalysts

(2010) Ákos Koós et al.   CATALYSIS LETTERS

Hydrogen from formic acid decomposition over Pd and Au catalysts

(2010) Dmitri A. Bulushev et al.   CATALYSIS TODAY

Decomposition of Formic Acid Catalyzed by a Phosphine-Free Ruthenium Complex in a Task-Specific Ionic Liquid

(2010) Jackson D. Scholten et al.   ChemCatChem

Novel PdAu@Au/C Core−Shell Catalyst: Superior Activity and Selectivity in Formic Acid Decomposition for Hydrogen Generation

(2010) Yunjie Huang et al.   CHEMISTRY OF MATERIALS

A Continuous-Flow Method for the Generation of Hydrogen from Formic Acid

(2010) Artur Majewski et al.   ChemSusChem

Ruthenium-Catalyzed Hydrogenation of Bicarbonate in Water

(2010) Christopher Federsel et al.   ChemSusChem

Available hydrogen from formic acid decomposed by rare earth elements promoted Pd-Au/C catalysts at low temperature

(2010) Xiaochun Zhou et al.   ChemSusChem

Liquid-Phase Chemical Hydrogen Storage: Catalytic Hydrogen Generation under Ambient Conditions

(2010) Hai-Long Jiang  et al.   ChemSusChem

Clean, efficient electrolysis of formic acid via formation of eutectic, ionic mixtures with ammonium formate

(2010) Leigh Aldous et al.   Energy & Environmental Science

Carbon dioxide and formic acid—the couple for environmental-friendly hydrogen storage?

(2010) Stephan Enthaler et al.   Energy & Environmental Science

Rapid and highly selective conversion of biomass into value-added products in hydrothermal conditions: chemistry of acid/base-catalysed and oxidation reactions

(2010) Fangming Jin et al.   Energy & Environmental Science

Effect of water on formic acid photocatalytic decomposition on TiO2 and Pt/TiO2

(2010) Kristi L. Miller et al.   JOURNAL OF CATALYSIS

Influence of water-soluble sulfonated phosphine ligands on ruthenium catalyzed generation of hydrogen from formic acid

(2010) Weijia Gan et al.   JOURNAL OF COORDINATION CHEMISTRY

Controlling the Equilibrium of Formic Acid with Hydrogen and Carbon Dioxide Using Ionic Liquid

(2010) Yoshiro Yasaka et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Unusually Large Tunneling Effect on Highly Efficient Generation of Hydrogen and Hydrogen Isotopes in pH-Selective Decomposition of Formic Acid Catalyzed by a Heterodinuclear Iridium−Ruthenium Complex in Water

(2010) Shunichi Fukuzumi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Hydrogen Production from Formic Acid

(2010) Albert Boddien et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Generation of Hydrogen from Formic acid and its Derivatives: Useful Hydrogen Storage Materials

(2010) Björn Loges et al.   TOPICS IN CATALYSIS

A Novel Example of Molecular Hydrogen Generation from Formic Acid at Visible-Light-Responsive Photocatalyst

(2009) Seiji Kakuta et al.   ACS Applied Materials & Interfaces

Continuous Hydrogen Generation from Formic Acid: Highly Active and Stable Ruthenium Catalysts

(2009) Albert Boddien et al.   ADVANCED SYNTHESIS & CATALYSIS

Formic Acid Dehydrogenation on Au-Based Catalysts at Near-Ambient Temperatures

(2009) Manuel Ojeda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reaction of Formic Acid on Zn-Modified Pd(111)

(2009) Eseoghene Jeroro et al.   CATALYSIS LETTERS

Kinetic study of the photo-Fenton degradation of formic acid

(2009) Jorgelina Farias et al.   CATALYSIS TODAY

Opportunities and prospects in the chemical recycling of carbon dioxide to fuels

(2009) Gabriele Centi et al.   CATALYSIS TODAY

Hydrogen generation: catalytic acceleration and control by light

(2009) Björn Loges et al.   CHEMICAL COMMUNICATIONS

Low activation energy dehydrogenation of aqueous formic acid on platinum–ruthenium–bismuth oxide at near ambient temperature and pressure

(2009) Siu-Wa Ting et al.   CHEMICAL COMMUNICATIONS

Hydrogen generation from formic acid and alcohols using homogeneous catalysts

(2009) Tarn C. Johnson et al.   CHEMICAL SOCIETY REVIEWS

Selective Formic Acid Decomposition for High-Pressure Hydrogen Generation: A Mechanistic Study

(2009) Céline Fellay et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hydrogen Generation from Formic Acid Decomposition with a Ruthenium Catalyst Promoted by Functionalized Ionic Liquids

(2009) Xueli Li et al.   ChemSusChem

Organic materials for hydrogen storage applications: from physisorption on organic solids to chemisorption in organic molecules

(2009) Philippe Makowski et al.   Energy & Environmental Science

Highly efficient hydrogen evolution by decomposition of formic acid using an iridium catalyst with 4,4′-dihydroxy-2,2′-bipyridine

(2009) Yuichiro Himeda   GREEN CHEMISTRY

Selective decomposition of formic acid on molybdenum carbide: A new reaction pathway

(2009) David W. Flaherty et al.   JOURNAL OF CATALYSIS

In situ FTIR study of the kinetics of formic acid decomposition on V–Ti oxide catalyst under stationary and non-stationary conditions. Determination of kinetic constants

(2009) E.A. Ivanov et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Photolysis studies on HCOOH and HCOO− in presence of TiO2 photocatalyst as suspension in aqueous medium

(2009) G.R. Dey et al.   Journal of Natural Gas Chemistry

Influence of Aspect Ratio of TiO2 Nanorods on the Photocatalytic Decomposition of Formic Acid

(2009) Hyeong Jin Yun et al.   Journal of Physical Chemistry C

Insights into Hydrogen Generation from Formic Acid Using Ruthenium Complexes

(2009) David J. Morris et al.   ORGANOMETALLICS

Improved hydrogen generation from formic acid

(2009) Henrik Junge et al.   TETRAHEDRON LETTERS

Hydrogen storage and delivery: immobilization of a highly active homogeneous catalyst for the decomposition of formic acid to hydrogen and carbon dioxide

(2009) Weijia Gan et al.  

Controlled Generation of Hydrogen from Formic Acid Amine Adducts at Room Temperature and Application in H2/O2Fuel Cells

(2008) Björn Loges et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Viable Hydrogen-Storage System Based On Selective Formic Acid Decomposition with a Ruthenium Catalyst

(2008) Céline Fellay et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

High-quality hydrogen from the catalyzed decomposition of formic acid by Pd–Au/C and Pd–Ag/C

(2008) Xiaochun Zhou et al.   CHEMICAL COMMUNICATIONS

Carbon Dioxide-The Hydrogen-Storage Material of the Future?

(2008) Stephan Enthaler   ChemSusChem

Hydrogen Generation at Ambient Conditions: Application in Fuel Cells

(2008) Albert Boddien et al.   ChemSusChem

Efficient Catalytic Decomposition of Formic Acid for the Selective Generation of H2and H/D Exchange with a Water-Soluble Rhodium Complex in Aqueous Solution

(2008) Shunichi Fukuzumi et al.   ChemSusChem

Breakthroughs in Hydrogen Storage-Formic Acid as a Sustainable Storage Material for Hydrogen

(2008) Ferenc Joó   ChemSusChem

Photocatalytic hydrogen generation over alkaline-earth titanates in the presence of electron donors

(2008) B ZIELINSKA et al.   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

Redox Pathways for HCOOH Decomposition over CeO2 Surfaces

(2008) Sanjaya D. Senanayake et al.   Journal of Physical Chemistry C