Metal-free oxidative C(sp3)–H bond functionalization of alkanes and alkylation-initiated radical 1,2-aryl migration in α,α-diaryl allylic alcohols

Metal-Free Preparation of Cycloalkyl Aryl SulfidesviaDi-tert-butyl Peroxide-Promoted Oxidative C(sp3)H Bond Thiolation of Cycloalkanes

(2014) Jincan Zhao et al.   ADVANCED SYNTHESIS & CATALYSIS

Metal-free oxidative direct C(sp3)–H bond functionalization of ethers with α,α-diaryl allylic alcohols

(2014) Xue-Qiang Chu et al.   CHEMICAL COMMUNICATIONS

tert-Butyl peroxybenzoate (TBPB)-mediated 2-isocyanobiaryl insertion with 1,4-dioxane: efficient synthesis of 6-alkyl phenanthridines via C(sp3)–H/C(sp2)–H bond functionalization

(2014) Jia-Jia Cao et al.   CHEMICAL COMMUNICATIONS

Radical phosphinylation of α,α-diaryl allylic alcohols with concomitant 1,2-aryl migration

(2014) Xue-Qiang Chu et al.   CHEMICAL COMMUNICATIONS

Copper-catalysed oxidative C–H/C–H coupling between olefins and simple ethers

(2014) Dong Liu et al.   CHEMICAL COMMUNICATIONS

n-Bu4NI/TBHP-catalyzed direct amination of allylic and benzylic C(sp3)–H with anilines under metal-free conditions

(2014) Xusheng Zhang et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed tandem oxidative cyclization of cinnamamides with benzyl hydrocarbons through cross-dehydrogenative coupling

(2014) Shi-Liu Zhou et al.   CHEMICAL COMMUNICATIONS

Hypervalent Iodine-Mediated Selective Oxidative Functionalization of (Thio)chromones with Alkanes

(2014) Rishikesh Narayan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iron-Catalyzed Cross-Dehydrogenative Coupling Esterification of Unactive C(sp3)–H Bonds with Carboxylic Acids for the Synthesis of α-Acyloxy Ethers

(2014) Jincan Zhao et al.   JOURNAL OF ORGANIC CHEMISTRY

Cu-Catalyzed C(sp3)–H Bond Activation Reaction for Direct Preparation of Cycloallyl Esters from Cycloalkanes and Aromatic Aldehydes

(2014) Jincan Zhao et al.   ORGANIC LETTERS

A Free Radical Cascade Cyclization of Isocyanides with Simple Alkanes and Alcohols

(2014) Zejiang Li et al.   ORGANIC LETTERS

Metal-Free Oxidative C(sp3)–H Bond Functionalization of Alkanes and Conjugate Addition to Chromones

(2014) Jincan Zhao et al.   ORGANIC LETTERS

Copper catalyzed direct alkenylation of simple alkanes with styrenes

(2014) Yefeng Zhu et al.   Chemical Science

Copper-Catalyzed Tandem Trifluoromethylation/Semipinacol Rearrangement of Allylic Alcohols

(2013) Zhi-Min Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Oxindoles by Iron-Catalyzed Oxidative 1,2-Alkylarylation of Activated Alkenes with an Aryl C(sp2)H Bond and a C(sp3)H Bond Adjacent to a Heteroatom

(2013) Wen-Ting Wei et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Selective Oxidative Cross-Coupling of Simple Alkanes with Heteroarenes

(2013) Andrey P. Antonchick et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Functionalization of Tetrahydrofuran and 1,4-Dioxane: Nickel-Catalyzed Oxidative C(sp3)H Arylation

(2013) Dong Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Trifluoromethylation-Initiated Radical 1,2-Aryl Migration in α,α-Diaryl Allylic Alcohols

(2013) Xiaowu Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Functionalization of C(sp2)H and C(sp3)H Bonds by Using Bidentate Directing Groups

(2013) Guy Rouquet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-catalyzed decarboxylative alkenylation of cycloalkanes with arylvinyl carboxylic acids via a radical process

(2013) Jiancan Zhao et al.   Beilstein Journal of Organic Chemistry

Metal-free, highly efficient organocatalytic amination of benzylic C–H bonds

(2013) Qicai Xue et al.   CHEMICAL COMMUNICATIONS

Iron-catalyzed trifluoromethylation with concomitant C–C bond formation via 1,2-migration of an aryl group

(2013) Hiromichi Egami et al.   CHEMICAL COMMUNICATIONS

Silver-catalyzed oxidative coupling/cyclization of acrylamides with 1,3-dicarbonyl compounds

(2013) Hua Wang et al.   CHEMICAL COMMUNICATIONS

Amide bond formation via C(sp3)–H bond functionalization and CO insertion

(2013) Huizhen Liu et al.   CHEMICAL COMMUNICATIONS

Iron-catalyzed direct alkenylation of sp3(C–H) bonds via decarboxylation of cinnamic acids under ligand-free conditions

(2013) Hailong Yang et al.   GREEN CHEMISTRY

Iron-Catalyzed Allylic Arylation of Olefins via C(sp3)–H Activation under Mild Conditions

(2013) Masaki Sekine et al.   ORGANIC LETTERS

Cu-Catalyzed Cross-Dehydrogenative Coupling Reactions of (Benzo)thiazoles with Cyclic Ethers

(2013) Zengyang Xie et al.   ORGANIC LETTERS

Directing Group Assisted Copper-Catalyzed Chemoselective O-Aroylation of Phenols and Enols Using Alkylbenzenes

(2013) Saroj Kumar Rout et al.   ORGANIC LETTERS

Free-Radical Cascade Alkylarylation of Alkenes with Simple Alkanes: Highly Efficient Access to Oxindoles via Selective (sp3)C–H and (sp2)C–H Bond Functionalization

(2013) Zejiang Li et al.   ORGANIC LETTERS

Metal-Free Oxidative C(sp3)–H Bond Thiolation of Ethers with Disulfides

(2013) Sheng-rong Guo et al.   ORGANIC LETTERS

Iron-catalyzed alkenylation of cyclic ethers via decarboxylative sp3(C)–sp2(C) coupling

(2013) Jincan Zhao et al.   TETRAHEDRON LETTERS

Metal-Catalyzed Nitrogen-Atom Transfer Methods for the Oxidation of Aliphatic C–H Bonds

(2012) Jennifer L. Roizen et al.   ACCOUNTS OF CHEMICAL RESEARCH

Functionalizations of Aryl CH Bonds in 2-Arylpyridines via Sequential Borylation and Copper Catalysis

(2012) Liting Niu et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium-Catalyzed Direct ortho-Acylation through an Oxidative Coupling of Acetanilides with Toluene Derivatives

(2012) Zhangwei Yin et al.   JOURNAL OF ORGANIC CHEMISTRY

Four Tandem C–H Activations: A Sequential C–C and C–O Bond Making via a Pd-Catalyzed Cross Dehydrogenative Coupling (CDC) Approach

(2012) Srimanta Guin et al.   ORGANIC LETTERS

Tetrabutylammonium Iodide Catalyzed Synthesis of Allylic Ester with tert-Butyl Hydroperoxide as an Oxidant

(2012) Erbo Shi et al.   ORGANIC LETTERS

Copper Catalyzed Oxidative Esterification of Aldehydes with Alkylbenzenes via Cross Dehydrogenative Coupling

(2012) Saroj Kumar Rout et al.   ORGANIC LETTERS

CuI Controlled C–C and C–N Bond Formation of Heteroaromatics through C(sp3)–H Activation

(2012) Ran Xia et al.   ORGANIC LETTERS

Adding Aliphatic C-H Bond Oxidations to Synthesis

(2012) M. C. White   SCIENCE

Copper-catalyzed decarboxylative alkenylation of sp3 C–H bonds with cinnamic acids via a radical process

(2012) Zili Cui et al.   Chemical Science

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

If CH Bonds Could Talk: Selective CH Bond Oxidation

(2011) Timothy Newhouse et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

TBHP-mediated oxidative thiolation of an sp3 C–H bond adjacent to a nitrogen atom in an amide

(2011) Ri-Yuan Tang et al.   CHEMICAL COMMUNICATIONS

Bond Formations between Two Nucleophiles: Transition Metal Catalyzed Oxidative Cross-Coupling Reactions

(2011) Chao Liu et al.   CHEMICAL REVIEWS

Direct Sp3α-C–H activation and functionalization of alcohol and ether

(2011) Shu-Yu Zhang et al.   CHEMICAL SOCIETY REVIEWS

Guiding principles for site selective and stereoselective intermolecular C–H functionalization by donor/acceptor rhodium carbenes

(2011) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

Bu4NI-Catalyzed CO Bond Formation by Using a Cross-Dehydrogenative Coupling (CDC) Reaction

(2011) Long Chen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ruthenium-Catalyzed Para-Selective Oxidative Cross-Coupling of Arenes and Cycloalkanes‡

(2011) Xiangyu Guo et al.   ORGANIC LETTERS

Iron-CatalyzedN-Alkylation of Azoles via Oxidation of C−H Bond Adjacent to an Oxygen Atom

(2010) Shiguang Pan et al.   ORGANIC LETTERS

Sc(OTf)3-Catalyzed Direct Alkylation of Quinolines and Pyridines with Alkanes

(2009) Guojun Deng et al.   ORGANIC LETTERS

Cross-Dehydrogenative Coupling (CDC): Exploring C−C Bond Formations beyond Functional Group Transformations

(2008) Chao-Jun Li   ACCOUNTS OF CHEMICAL RESEARCH

Ruthenium-Catalyzed Oxidative Cross-Coupling of Chelating Arenes and Cycloalkanes

(2008) Guojun Deng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Coupling of Nitrogen Heteroaromatics and Alkanes without Transition Metals: A New Oxidative Cross-Coupling at CH/CH Bonds

(2008) Guojun Deng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed Oxidative Coupling of Benzylic C−H Bonds with 1,3-Dicarbonyl Compounds

(2008) Nadine Borduas et al.   JOURNAL OF ORGANIC CHEMISTRY