Ultrasound assisted dispersive solid phase microextraction using polystyrene-polyoleic acid graft copolymer for determination of Sb(III) in various bottled beverages by HGAAS

A new polyoleic acid-polystyrene (PoleS) block/graft copolymer was synthesized and applied as adsorbent for ultrasound assisted dispersive solid phase microextraction (UA-DSPME) of Sb(III) in different bottled beverages and analysis using hydride generation atomic absorption spectrometry (HGAAS). Adsorption capacity of the PoleS was 150 mg g- 1. Several sample preparation parameters such as sorbent amount, solvent type, pH, sample volume and shaking time were optimized (based on central composite design (CCD) approach) and evaluated in respect to the recovery of Sb(III). The method revealed a high tolerance limit of matrix ions presence. Under optimized conditions, linearity range, the limit of detection, the limit of quantitation, extraction recovery, enhancement factor, preconcentration factor were 5-800 ng L-1, 1.5 ng L-1, 5.0 ng L-1, 96%, 82, 90, respectively. Accuracy of the UA-DSPME method was confirmed based on different certified reference materials and standard addition method. Factorial design was utilized to estimate the influences of variables of recovery of Sb (III).

Automated summary

A new PoleS block/graft copolymer was synthesized and used as an adsorbent for UA-DSPME of Sb(III) in bottled beverages. The method showed good recovery and high tolerance limit of matrix ions presence. Under optimized conditions, the method exhibited a wide linearity range, low limits of detection and quantitation, high extraction recovery, and satisfactory preconcentration factor and enhancement factor. The influences of variable on the recovery of Sb(III) were estimated using factorial design.